Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Control of Molecular Weight, Stereochemistry and Higher Order Structure of Siloxane-containing Polymers and Their Functional Design

  • Yusuke Kawakami (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST)) ;
  • Yuning Li (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST) ;
  • Yang Liu (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST) ;
  • Makoto Seino (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST) ;
  • Chitsakon Pakjamsai (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST) ;
  • Motoi Oishi (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST) ;
  • Cho, Yeong-Bee (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST) ;
  • Ichiro Imae (Graduate School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST))
  • Published : 2004.04.01
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Abstract

We describe the precision synthesis schemes of siloxane-containing polymers, i.e., the control of their molecular weight, stereoregularity, and higher-order structures. First, we found a new catalytic dehydrocoupling reaction of water with bis(dimethylsilyl)benzene to give poly(phenylene-disiloxane). Together with this reaction, we applied hetero-condensations to the synthesis of thermally stable poly(arylene-siloxane)s. The dehydrocoupling reaction was applied to the synthesis of syndiotactic poly(methylphenylsiloxane) and poly(silsesquioxane)s, which we also prepared by hydrolysis and deaminative condensation reactions. We discuss the tendency for loop formation to occur in the synthesis of poly(silsesquioxane) by hydrolysis, and provide comments on the design of functionality of the polymers produced. By taking advantage of the low energy barrier to rotation in the silicon-oxygen bond, we designed selective oxygen-permeable membrane materials and liquid crystalline materials. The low surface free energy of siloxane-containing systems allows surface modification of a blend film and the design of holographic grating materials.

Keywords

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