• Journal of Electrochemical Science and Technology
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• v.14 no.3
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• pp.283-292
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• 2023

Currently, spray coating has attracted interest in the mass production of anode catalyst layers for proton exchange membrane water electrolysis (PEMWE). The solvent in the spray ink is a critical factor for the catalyst dispersion in ink, the microstructure of the catalyst layer, and the PEMWE performance. Herein, various pure organic solvents were examined as a substitute for conventional isopropanol-deionized water (IPA-DIW) mixture for ink solvent. Among the polar solvents that exhibited better IrO₂ dispersion over nonpolar solvents, 2-butanol (2-BuOH) was selected as a suitable candidate. The PEMWE single cells were fabricated using 2-BuOH at various ionomer contents, spray nozzle types, and drying temperatures, and their performance was compared to the cells fabricated using a conventional IPA-DIW mixture. The PEMWE single cells with 2-BuOH solvent showed good performances comparable to the conventional IPA-DIW mixture case and highly durable performances under accelerated degradation tests.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.143.2-143.2
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• 2010

Therefore, with this development assignment we'd like to develop the hybrid system combining 800W DMFC (Direct Methanol Fuel Cell) and 1.6kW of Lithium secondary battery pack which can be applied to the most common small cart. a scooter, to secure the development capability of hundreds of Watts DMFC, the high-capacity Lithium secondary battery pack, the technology of BMS (Battery Management System) and the development technology of hybrid system. DMFC, in fact, has lower energy efficiency than PEMFC (Polymer Electrolyte Membrane Fuel Cell); however, it has several advantages in terms of fuel storage and use. It is pretty easy to be stored and used without any additional colling and heating devices because of its insensitive liquid methanol to temperature. In conclusion, DMFC system is the most suitable device for small mobile vehicles.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2589-2593
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• 2008

In a fuel cell vehicle using polymer electrolyte membrane fuel cell(PEMFC), hydrogen is over-supplied to gain higher stack efficiency. So it is needed considering fuel efficiency to re-circulate hydrogen which is not reacted in stack. And to re-circulate hydrogen, a blower or an ejector is used. Ejector re-circulation system has several merits compared with blower system, for example no parasite energy, simple structure and no lubrication system. But the secondary flow of an ejector in fuel cell vehicle, has high humidity because of crossover problem in stack. Therefore in this paper, ejector is designed by 1-D modeling and CFD with the primary and secondary flow of hydrogen. And the ejector which has the primary and secondary flow of air, is designed to have the same Reynolds number and Mach number at the nozzle exit as the hydrogen ejector's. And this air ejector is tested while the humidity of the secondary flow is varied.

• Membrane Journal
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• v.27 no.1
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• pp.53-59
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• 2017

In this study, the composite membranes prepared by sulfonated graphene oxide (sGO) and Nafion were developed as proton exchange membranes (PEMs) for polymer electrolyte membrane fuel cells (PEMFCs). The sGO/Nafion composite membranes were prepared by mixing Nafion solution with the sGO dispersed in a binary solvent system to improve dispersity of sGO. The composite membranes were investigated in terms of ionic conductivity, ion exchange capacity (IEC), FT-IR, TGA and SEM, etc. As a result, the binary solvent system, i.e., ortho-dichlorobenzene (ODB) and N,N-dimethylacetamide (DMAc), were used to obtain high dispersion of sGO particles in Nafion solution, and the ionic conductivity of the sGO/Nafion composite membrane showed $0.06Scm^{-1}$ similar to other research results at lower water uptake, 11 wt%.

• Journal of the Korean Electrochemical Society
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• v.19 no.2
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• pp.39-44
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• 2016

Oxygen reduction reaction in the fuel cell (ORR) plays a dominant role in the overall reaction. In addition, the low compatibility between the membrane and the binder consisted of different materials, greatly reduces the efficiency of the fuel cell performance. In view of these two problems, geometrically modified copolymers with 9.9_Bis (4-hydroxyphenyl) were synthesized via condensation reaction instead of conventional biphenol and were adopted as hydrocarbon ionomer binders. By utilizing these binders, two kinds of MEAs using fluorinated Nafion membrane and hydrocarbon based membrane were manufactured in order to electrochemical performance evaluation. With current-voltage curves, there was no significant difference in the 0.6 V when two types of membrane were applied. Also, tafel slope became considerably lower as compared to the Nafion membrane. Thus, it is determined that the new hydrocarbon binder is expected to contribute the improvement in performance of fuel cells.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1409-1411
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• 1996

Direct Methanol Fuel Cell(DMFC) using Pt-Ru electrocatlayst and Nafion menbrane can provide high performance if operating conditions are well designed. In this study, operating temperature, pressure, and fuel flow rate were changed to obtain optimum operating conditions of DHFC single cell. Performance of DMFC were increased by the increase of operating temperature. The concentration of fuel methanol was 2.0M $CH_{3}OH$ and pressure difference of cathode and anode was 2 atm were showed maximum performance of DMFC single cell with showing the current density of 160 $mA/cm^2$ at 0.2V cell voltage.

• Proceedings of the KIPE Conference
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• 2018.07a
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• pp.356-357
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• 2018

Fuel-cell powered Railway Vehicle Propulsion Systems (RVPSs) are highly desirable due to environment friendly characteristics, and high efficiency of fuel cell (FC). Among various types, the faster start-up and optimality to frequent starts and stops of Polymer electrolyte membrane fuel cell (PEMFC) makes it well suited for propulsion systems. A comprehensive model of PEMFC with reflection of multi-physics behavior required to identify and validate its performance in real RVPSs. Thus this paper will model and simulate the PEMFC unit cell model: a detailed reflection of governing laws and account of dynamic conditions.

• Proceedings of the KIPE Conference
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• 2005.07a
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• pp.357-359
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• 2005

In this paper, a new SEPIC-Flyback converter with a single transformer has been proposed, which is suitable for a fuel cell based power generation system. The proposed converter is superposition of sepic and flyback converter mode. It has outstanding high boosting output voltage, component utilization and high efficiency characteristics under the inherently severe low output voltage of the fuel cell generator. The proposed converter for a full cell generator is described and verified by simulation and experimental result that make used of the Polymer Electrolyte Membrane Fuel Cell(PEMFC) Generator.

• Journal of the Korean Electrochemical Society
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• v.16 no.1
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• pp.52-58
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• 2013

In order to overcome the cost issue for commercialization of polymer electrolyte membrane fuel cell (PEMFC), this research was conducted for replacing platinum cathode catalyst with non-precious metal catalyst. The non-precious metal catalyst (Co-PANI-C) was synthesized by the simple reduction method with polyaniline (PANI), carbon black, and cobalt precursor without any heat treatment. Characterization of new Co-PANI-C composite catalysts was done by the measurement of X-ray diffraction (XRD) and thermogravimetric analysis (TGA) for structure analysis and performed by rotating disk electrode (RDE) and rotating ring disk electrode (RRDE) for electrochemical analysis. As a result, Co-PANI-C catalyst showed 60 mV lower on-set potential for oxygen reduction reaction (ORR) than Pt/C catalyst, but the overall reduction current of Co-PANI-C catalysts by ORR was still smaller than that of Pt/C. In addition, the ORR behavior of Co-PANI-C catalysts depending on the rotation speed of electrode and the stability of Co-PANI-C catalyst under potential cycling and the performance of fuel cell conditions are also discussed.

• Journal of the Korean institute of surface engineering
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• v.48 no.5
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• pp.199-204
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• 2015

Recently, fuel cell is a good alternative for energy source. Separator is a important component for fuel cell. In this study, The surface of separator was modified for corrosion resistance and electric conductivity. Reduced graphene oxide (rGO) was made by Staudenmaier's method. Nickel, phosphorus and rGO were coated on 6061 aluminum alloy as a separator of proton exchange membrane fuel cell by composite electroless plating. Scanning electron microscope, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy were used to examine the morphology of Ni-P-rGO. Surface images were shown that the rGO was dispersed on the surface of Ni-P electroless plating, and nickel was combined with the un-reduced oxygen functional group of rGO.