• 제목/요약/키워드: Polymer core

검색결과 374건 처리시간 0.024초

레이더 흡수특성이 있는 저적외선 방출 복합섬유의 제조 및 특성 연구 (Preparation and Characterization of Low Infrared Emissivity Bicomponent Fibers with Radar Absorbing Property)

  • Yu Bin;Qi Lu
    • 폴리머
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    • 제30권2호
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    • pp.124-128
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    • 2006
  • Heavy weight of the camouflage materials was always the main problem. To solve it, the low infrared emissivity fibers with the radar absorbing property (LIFR) were prepared. The low infrared emissivity fibers (LIF) were firstly melt-spun by co-extrusion of polypropylene (PP) and PP/various fillers master-batches using general conjugate spinning. The infrared emissivity of LW with AA and ZnO was decreased respectively compared with that of pure polypropylene fibers. The infrared emissivity of LIF with 15 wt% Al and 2 wt% ZnO in the sheath-part can reach 0.58. To improve LIF radar absorbing property, LIFR was prepared by filling the 50 wt% ferrite and bronze in the core-part of LIF. The radar absorbing efficacy of LIFR was good and the infrared emissivity was low. For the characterization, fiber electron intensity instrument and differential scanning calorimetry (DSC) were used for the analysis of mechanical properties, thermal and crystallization behavior of the spun-fibers. Scanning electron microscopy (SEM) was carried out to observe the particle distribution of the bicomponent fibers.

삼중 결합 링 공진기 필터의 설계 및 제작 (Design and Fabrication of Triple-coupler Ring Resonator Filter)

  • 이영식;정영철
    • 한국광학회지
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    • 제22권1호
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    • pp.40-45
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    • 2011
  • 동일한 주회 길이의 통상적인 DCRR (Double-coupler Ring Resonator) 에 비하여 두 배의 FSR (Free Spectral Range) 성능을 나타낼 수 있는 TCRR (Triple-coupler Ring Resonator: 삼중 결합 링 공진기) 필터의 설계 및 제작에 대하여 논의하였다. 열-광학 특성이 우수하고, 코어-클래딩 굴절률 차가 큰 폴리머 물질을 이용하여 작은 반경의 곡선도파로가 가능한 매립형 도파구조의 컴팩트한 TCRR 필터를 설계 및 제작하였다. 파장가변 레이저와 광섬유 배열 블록을 이용하여 TCRR 필터의 Through 및 Drop 포트 출력 특성을 측정한 결과, DCRR 필터의 두 배인 4.4 nm의 FSR을 확인하였고, 이는 전달행렬 방법을 이용하여 해석한 결과와 거의 동일하였다.

Eudragit $RS^{\circledR}$를 이용한 지속 방출형 아스피린 마이크로캅셀의 제조 및 평가 (Preparation and Evaluation of Sustained Release Aspirin Microcapsules Using Eudragit $RS^{\circledR}$ Polymer)

  • 전인구;신동원
    • 약학회지
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    • 제32권1호
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    • pp.26-39
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    • 1988
  • Eudragit $RS^{\circledR}$ polymer was used as a wall material for the microencapsulation of aspirin by a phase separation method from chloroform-cyclohexane system with 5% polyisobutylene (PIB) in cyclohexane, and microcapsules obtained were evaluated by particle size analysis, scanning electron microscopy (SEM), drug release and drug stability test. With PIB as a coacervation inducing agent, smooth and tight microcapsules with less aggregation were obtained. Below 1 : 0.3 core-wall ratio, it was possible to coat individual particle. Variation of production conditions showed that increasing the proportion of wall material, particle size and wall thickness of microcapsules and the concentration of paraffin wax in cyclohexane as a sealant sustained drug release rates effectively. SEM confirmed that larger microcapsules after drug release did not rupture into smaller particles but contained a few small pores on the surface. Aspirin release from Eudragit $RS^{\circledR}$ coated microcapsules was independent of the pH of medium, and the mechanism of drug release from non-sealed and sealed microcapsules appeared to fit Higuchi matrix model kinetics. Aspirin in the mixture of aspirin microcapsules and sodium bicarbonate was by far more stable than that in the mixture of pure aspirin and sodium bicarbonate.

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Synthesis and Mesomorphic Properties of Banana-Shaped Mesogens with All-Ester Linking Group

  • Choi, E-Joon;Cui, Xin;Zin, Wang-Choel;Ohk, Chang-Woo;Lim, Tong-Kun;Lee, Ji-Hoon;Kim, Young-Chul;Paek, Sang-Hyon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2007년도 7th International Meeting on Information Display 제7권1호
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    • pp.197-199
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    • 2007
  • Four banana-shaped compounds have beene synthesized introducing ester linking group into mesogenic unit, varying the central core with 1,6-, 1,7-, 2,3-, and 2,7-naphthylene units, and introducing the dodecyloxy group as the terminal flexible unit. All obtained compounds except one with 1,7-naphthylene unit were reversibly thermotropically liquid crystalline. The compound with 1,7-naphthylene unit could not form the mesophase due to its asymmetrical and sharp substitution angle. The compounds with 1,6- and 2,3-naphthylene units showed an antiferroelectric switchable smectic phase, which has been designated B2 phase. Interestingly, the compound with the 2,3-naphthylene unit showed the two mesophases of B2 and nematic phase.

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클릭 화학에 의한 폴리(벤질에테르)덴드리머의 효율적인 합성 (Synthesis of Poly(benzyl ether) Dendrimers by Click Chemistry)

  • 이재욱;이언엽;한승철;김지현;진성호
    • 폴리머
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    • 제33권1호
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    • pp.67-71
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    • 2009
  • 프레체형태 덴드리머의 합성을 위한 연결 방법이 알카인기와 아지드기 사이의 클릭 화학을 이용하여 개발되었다. 덴드리머의 핵으로 작용할 수 있는 단위체인 4,4'-(3,5-비스(아지도프로필옥시)벤질옥시)비스페닐이 알카인덴드론과 클릭 반응을 통해 덴드리머의 구축을 위해 사용되었다. 즉, 구리촉매 존재하에서 다중(아지드)화합물과 말단 알킨기를 가지는 폴리(벤질에테르)덴드론 사이치 클릭 반응을 통해 덴드리머의 합성 전략이 완성되었다.

Buckling and vibration of porous sandwich microactuator-microsensor with three-phase carbon nanotubes/fiber/polymer piezoelectric polymeric nanocomposite face sheets

  • Arani, Ali Ghorbanpour;Navi, Borhan Rousta;Mohammadimehr, Mehdi
    • Steel and Composite Structures
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    • 제41권6호
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    • pp.805-820
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    • 2021
  • In this research, the buckling and free vibration of three-phase carbon nanotubes/ fiber/ polymer piezoelectric nanocomposite face sheet sandwich microbeam with microsensor and micro-actuator surrounded in elastic foundation based on modified couple stress theory (MCST) is investigated. Three types of porous materials are considered for sandwich core. Higher order (Reddy) and sinusoidal shear deformation beam theories are employed for the displacement fields. Sinusoidal surface stress effects are extracted for sinusoidal shear deformation beam theory. The equations of motion are derived by Hamilton's principle and then the natural frequency and critical buckling load are obtained by Navier's type solution. The determined results are in good agreement with other literatures. The detailed numerical investigation for various parameters is performed for this microsensor-microactuator. The results reveal that the microsensor-microactuator enhanced by increasing of Skempton coefficient, carbon nanotubes diameter length to thickness ratio, small scale factor, elastic foundation, surface stress constants and reduction in porous coefficient, micro-actuator voltage and CNT weight fraction. The valuable results can be expedient for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.

Buckling performance of pultruded glass fiber reinforced polymer profiles infilled with waste steel fiber reinforced concrete under axial compression

  • Emrah, Madenci;Sabry, Fayed;Walid, Mansour;Yasin Onuralp, Ozkilic
    • Steel and Composite Structures
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    • 제45권5호
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    • pp.653-663
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    • 2022
  • This study reports the results of a series of tests of pultruded glass fiber reinforced polymer (P-GFRP) box section composite profile columns, geometrically similar with/without concrete core, containing 0-1-2-3% steel fiber, with different lengths. The recycled steel wires were obtained from waste tyres. The effects of steel fiber ratio on the collapse and size effect of concrete filled P-GFRP columns under axial pressure were investigated experimentally and analytically. A total of 36 columns were tested under compression. The presence of pultruded profile and steel wire ratio were selected as the primary variable. The capacity of pultruded profiles with infilled concrete are averagely 9.3 times higher than the capacity of concrete without pultruded profile. The capacity of pultruded profiles with infilled concrete are averagely 34% higher than that of the pultruded profiles without infilled concrete. The effects of steel wire ratio are more pronounced in slender columns which exhibit buckling behavior. Moreover, the proposed analytical approach to calculate the capacity of P-GFRP columns successfully predicted the experimental findings in terms of both pure axial and buckling capacity.

Numerical modelling of circular reinforced concrete columns confined with GFRP spirals using fracture-plastic model

  • Muhammad Saad Ifrahim;Abdul Jabbar Sangi;Shuaib H. Ahmad
    • Computers and Concrete
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    • 제31권6호
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    • pp.527-536
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    • 2023
  • Fiber Reinforced Polymer (FRP) bar has emerged as a viable and sustainable replacement to steel in reinforced concrete (RC) under severe corrosive environment. The behavior of concrete columns reinforced with FRP bars, spirals, and hoops is an ongoing area of research. In this study, 3D nonlinear numerical modelling of circular concrete columns reinforced with Glass Fiber Reinforced Polymer (GFRP) bars and transversely confined with GFRP spirals were conducted using fracture-plastic model. The numerical models and experimental results are found to be in good agreement. The effectiveness of confinement was accessed through von-mises stresses, and it was found that the stresses in the concrete's core are higher with a 30 mm pitch (46 MPa) compared to a 60 mm pitch (36 MPa). The validated models are used to conduct parametric studies. In terms of axial load carrying capacity and member ductility, the effect of concrete strength, spiral pitch, and longitudinal reinforcement ratio are thoroughly investigated. The confinement effect and member ductility of a GFRP RC column increases as the spiral pitch decreases. It is also found that the confinement effect and member ductility decreased with increase in strength of concrete.

Axial behavior of square CFST encased seawater sea-sand concrete filled PVC/GFRP tube columns

  • Rong Su;Xian Li;Ziwei Li
    • Steel and Composite Structures
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    • 제47권6호
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    • pp.781-794
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    • 2023
  • In order to directly apply seawater and sea sand in construction without desalination, a type of square concrete-filled steel tube (CFST) encased with prefabricated seawater sea-sand concrete filled Polyvinyl Chloride (PVC)/Glass Fiber Reinforced Polymer (GFRP) tube column was proposed. Twenty short columns were tested under uniaxial loads, and the test parameters included inner tube types, seawater sea-sand concrete replacement ratios, concrete strength, the wrapping area of Carbon Fiber Reinforced Polymer (CFRP) strips and the thickness of GFRP tube. The effects of the parameters on failure modes, loading capacity, ductility and strain responses were discussed. All the tested specimens failed with serious buckling of the steel tubes and fracture of the inner tubes. The specimens had good residual bearing capacity corresponding to 64% to 88.9% of the peak capacity. The inner GFRP tubes and PVC tubes wrapped by CFRP strips provided stronger confinement to the core concrete, and were good choices for the proposed columns. Moreover, an analytical model for the composite column with different inner tube types was proposed.

셀룰로오스 종이 상에 Oxime 도입된 polypyrrole 층을 제조한 신경작용제 선택적 화학저항 센서 (Nerve-Agent Selective Chemiresistors Fabricated by Oxime Decorated Polypyrrole Layer on Cellulose Paper)

  • 전창훈;하태환
    • 한국군사과학기술학회지
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    • 제27권4호
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    • pp.528-534
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    • 2024
  • In continuous research of detecting highly toxic chemical warfare agents to ensure preparedness for the future battlefield, flexible and wearable sensor platforms with high sensitivity are still demanding. Herein we demonstrate a facile fabrication of polypyrrole-based chemiresistors on cellulose paper for the detection of nerve gas simulants. In order to optimize electrical properties of sensor platform, conducting polymer made of polypyrrole were first synthesized on flexible cellulose paper and interdigitated electrodes were formed thereon. Following confirmation of polypyrrole and/or oxime moiety through FT-IR analyses, electrical characteristics were measured in the various ratio of monomers between simple pyrrole and oxime-modified one. Typically for the optimized chemiresistor(2:8 molar ratio of simple pyrrole and oxime-modified one), eleven species of chemical warfare agents were examined and enhanced conductivity(104~105 order) was observed for three simulants(diethyl cyanophosphonate, diisopropyl fluorophosphonate and diethyl chlorophosphonate), which was mainly attributed to intermolecular hydrogen bonding, while no significant responses was recorded against sixteen common volatile organic chemicals.