• Title/Summary/Keyword: Polymer Resin

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Improvement in Long-Term Stability and Photovoltaic Performance of UV Cured Resin Polymer Gel Electrolyte for Dye-Sensitized Solar Cell

  • Park, Geun Woo;Hwang, Chul Gyun;Jung, Jae Won;Jung, Young Mee
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4093-4097
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    • 2012
  • We introduced a new UV-cured resin polymer gel as an electrolyte for dye-sensitized solar cells (DSSCs) that is cured with UV irradiation to form a thin film of UV-cured resin polymer gel in the cells. The gel film was characterized and its potential for use as an electrolyte in DSSCs was investigated. This new UV-cured resin polymer gel was successfully applied as a gel polymer electrolyte in DSSCs overcoming the problems associated with the liquid electrolytes in typical DSSCs. The effect of ${\gamma}$-butylrolactone (GBL) on the long-term stability and photovoltaic performance in DSSCs using this UV-cured resin polymer gel electrolyte was also investigated. The results of the energy conversion efficiency, ionic conductivity and Raman spectra of the UV-cured resin polymer gel electrolyte with the addition of 6 wt % GBL to the UV-cured resin polymer electrolyte showed good long-term stability and photovoltaic performance for the DSSCs with the UV-cured polymer gel electrolyte.

A Study on the Properties of Polymer Mortar Using Waste Expanded Polystyrene as a Shrinkage-Reducing Agent (수축저감제로서 발포 폴리스티렌 폐기물을 이용한 폴리머 모르터의 기초적 성질에 관한 연구)

  • 최낙운;김완기;조영국;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10a
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    • pp.362-367
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    • 1998
  • The purpose of this study is to examine the influences of polystyrene content and St/UP on the setting shrinkage and strengths of polymer mortar with waste expanded polystyrene resin as a shrinkage-reducing agent, and to recommend the optimum binder formulations for product of low-shrinkage polymer mortar. In this paper, polymer mortar is prepared with waste expanded polystyrene content and St/UP, and tested for setting shrinkage, flexural and compressive strengths. From the test results, irrespective of increasing of waste expanded polystyrene resin, the strengths reduction of polymer mortar with waste expanded polystyrene(EPS) resin is not recognized. And the setting shrinkage is reduced with EPS resin content. The waste expanded polystyrene resin as a shrinkage-reducing agent can be used in the same manner as commercial polystyrene resin. In this study, we can obtain the optimum mix proportions of polymer mortar using EPS resin.

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Effects of Resin Quantity on the Strength Properties of Polyester Resin Concrete (폴리에스터 레진콘크리트에서 수지 사용량에 따른 강도특성)

  • 황광률;소형석;소승영;박홍신;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.235-239
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    • 1994
  • Polymer mortars are mainly used as protective coatings in concrete, reinforced concrete, and more rarely, steel, while polymer concretes represent a new type of structural material capable of withstanding highly corrosive environments. The mechanical properties, chemical stability, and some other useful properties are the reasons research, design, and production organizations. However polymer mortars and polymer concretes have been introduced only recently, and many of their properties are still imperfectly known. And, the main technique in producing polymer concrete is to minimize void volume in the aggregate mass so as to reduce the quantity of the relatively impressive polymer necessary for binding the aggregate. In this study, compressive strength and flexural strength of unsaturated polyester resin concrete are related to quantity of resin and solid volume of aggregate. It was founded that the more solid volume of aggregate increase, the less using quantity of resin decrease with out reducing mechnical properties. When solid volume ratio of aggregate is 70.6%, using quantity of resin is minimized to 10wt.%.

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A Study on the Thermal Insulation Property of Concrete Composites using Light-weight Aggregate (경량골재를 사용한 콘크리트 복합체의 단열성능에 관한 연구)

  • So, Seung-Yeong
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.3
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    • pp.93-100
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    • 2004
  • In recent years, it has widely been studied on the light-weight composites for the purpose of the large space and thermal insulation of building structures. The purpose of this study is to evaluate the properties of light-weight composites made by binders as cement, resin and polymer cement slurry. The concrete composites are prepared with various conditions such as polymer-cement ratio, void-filling ratio, type of resin, filler content and light-weight aggregate content, tested for thermal conductivity. From the test results, the thermal conductivity of concrete composites with the binder of cement tends to decrease with increasing polymer-cement ratio, and to increase with increasing void-filling ratio. The thermal conductivity of concrete composites with the binder of resin are markedly affected by the light-weight aggregate content, type of resin and filler content. The composites made by polymer-modified concrete and polymer cement slurry have a good thermal insulation property. From the this study, we can recommend the proper mix proportions for thermal insulation Panel or concrete. Expecially. the thermal conductivity of concrete composites made by polyurethane resin is almost the same as that of the conventional expanded polystyrene resin.

Effects of Fillers on Mixing and Mechanical Properties of Polymer Concrete (충진재가 폴리머 콘크리트의 배합과 역학적 성질에 미치는 영향)

  • 연규석;김광우;김기성;김관호
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.35 no.2
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    • pp.81-91
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    • 1993
  • This study was performed to evalute effects of fillers on the mixing characteristics and mechanical properties of polymer concrete. Two types of unsaturated polyester polymer and two types of epoxy resin were used as binder material, and the portland cement, a fly ash and heavy calcium carbonate were used as filler. Following conclusions were drawn from the research results. 1. Working life of polymer concrete was not affected by filler types, but affected significantly by polymer types and quantities of hardener and catalysts. 2. Without concerning polymer types, use of heavy calcuim carbonate as filler was the best in improving workability.3. The highest strength was achieved by heavy calcium carbonate in using unsaturated polyester resin and by fly ash in using epoxy resin type.4. Elastic modulus was in the range of 2.05X 10-5~2.6X 10-5gf/cm$^2$, which was approximatly 60% of that of cement concrete. Heavy calcium carbonate with unsaturated polyester resin and fly ash with epoxy resin showed relatively higher elastic modulus.

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Quinone-Diamine Adduct as a High Performance Resin for Coatings (퀴논-디아민 부가물계 고성능 도료용 수지)

  • Lee, Chi-Giu
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.1
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    • pp.1-10
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    • 1996
  • We have prepared diamine-benzoquinone polymer which was known to excellent water proofing, high adhesion strength and good anti-corrosive effect, and have investigate with the possibility of application as a high performance resin for coatings. First of all, the reactivity of diamine-benzoquinone has been described an example of polymer reaction with research trend. The polymer reaction was divided into the polymerization with several diamine-benzoquinone and urethane group. The synthetic resin was shown a high solubility. In case of polymer containing urethane, water absorption content, water proofing and mechanical properties were controlled with the content, water proofing and mechanical properties were controlled with the content of quinone. It was shown that an use of choice was a possible result for various coatings. Diamine-quinone polymer can be used as a new resin for coatings. In addition, the polymer containing a functional group was shown a useful applicability as a high performance resin.

Type and Characteristics of Polymer-based Luting Materials (레진시멘트의 종류와 특성)

  • Kim, Ah-Jin;Bae, Ji-Myung
    • The Journal of the Korean dental association
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    • v.53 no.3
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    • pp.178-186
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    • 2015
  • Dental polymer-based luting materials are classified into esthetic resin cement, adhesive resin cement and self-adhesive resin cement. Due to the different component of each type of resin cement, the preconditioning method of tooth surface and the steps are different from each type of resin cement. The pre-treatment of adherend (ceramic, resin and metal) surface also varies with the type of resin cement and the manufacturer. In this study, the characteristics of each type of resin cement, mechanical properties, indication and advantages were investigated. Through these, clinical tips on using resin cements were suggested.

A Study on the Strength and Durability of Polymer-Modified Mortars using Eco-friendly UM resin (친환경 UM수지를 사용한 폴리머 시멘트 모르타르의 강도 및 내구성에 관한 연구)

  • Kwon, Min-Ho;Kim, Jin-Sup;Park, Su-Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.2
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    • pp.943-948
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    • 2013
  • In this study, the characteristics of polymer-modified mortar which include UM resin, eco-friendly resin, was studied for improving the durability of concrete. UM and cement mortar were mixed with a certain percentage. Eco-friendly UM resin polymer-modified mortar was evaluated by compressive strength, splitting tensile strength, flexural strength, water absorption and chemical resistance experiments. The characteristics of eco-friendly UM resin polymer-modified mortar were evaluated by experiments. Performance of compressive strength and splitting tensile strength were decreasing. On the other hand, performance of flexural strength, water absorption and chemical resistance were increasing. Eco-friendly UM resin polymer-modified mortar reinforced concrete durability performance is excellent.

Transverse Flow and Process Modeling on the Polymer Composite with 3-Dimensionally Stitched Woven Fabric

  • Lee, Geon-Woong;Lee, Sang-Soo;Park, Min;Kim, Junkyung;Soonho Lim
    • Macromolecular Research
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    • v.10 no.4
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    • pp.194-203
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    • 2002
  • In resin infusion process(RIP), the fiber and the resin are in contact with each other for an impregnation step and often results in flow-induced defects such as poor fiber wetting and void formation. Resin flow characteristics in transverse direction and process modeling for woven fabric were studied, and the process modeling was applied to the manufacturing of hybrid composite materials. This study also considered the compressibility of woven fabrics in a series of compression force, and it was fitted well to an elastic model equation. Void formation was varied with the processing conditions in the stage of manufacturing composites using RIP. It was concluded from this study that proper combination of pressure build-up and dynamic heating condition makes important factor for flow-induced composite processing.

A study on the dielectric breakdown properties of two and three interpenetrating polymer network epoxy composites (2,3 성분 상호침입망목 에폭시 복합재료의 절연 파괴 특성에 관한 연구)

  • 김명호;김경환;손인환;이덕진;장경욱;김재환
    • Electrical & Electronic Materials
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    • v.9 no.4
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    • pp.364-371
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    • 1996
  • In this study, in order to investigate the applicability of IPN structure to epoxy resin which has been widely used as electrical and electronic insulating materials, DC dielectric breakdown properties and morphology were compared and analyzed according to variation of network structure, using the single network structure specimen formed of epoxy resin alone, interpenetrating polymer network specimen formed of epoxy resin/methacrylic acid resin, and interpenetrating polymer network specimen formed of epoxy resin/methacrylic acid resin/polyurethane resin. As results of the measunnent of DC dielectric breakdown strength at 50[.deg. C] and 130[>$^{\circ}C$], IPN specimen formed of epoxn, resin 100[phr] and methacrylic acid resin 35[phr] was the most excellent, and which corresponded to the SEM phenomena. The effect of IPN was more remarkable at high temperature region than at low temperature region. It is supposed that the defect of epoxy resin, dielectric breakdown strength is lowered remarkably at high temperature region, be complemented according to introducing IPN method.

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