• 제목/요약/키워드: Polydimethylsiloxane

검색결과 373건 처리시간 0.019초

Nano Clay와 Polydimethylsiloxane을 포함하는 Poly(N-isopropylacrylamide) 공중합체의 합성과 팽윤거동 (Synthesis and Swelling Characteristics of Poly(N-isopropylacrylamide) Containing Polydimethylsiloxane and Nano Clay)

  • 노휘철;이찬우;박상윤;윤구식
    • 폴리머
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    • 제34권2호
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    • pp.166-171
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    • 2010
  • Polydimethylsiloxane(PDMS) macroinitiator를 이용하여 N-isopropylacrylamide(NIPAAm)와 [3- (methacryloylamino)propyl]trimethyl ammonium montmorillonite(MAPTAC-MMT)를 중합하여 주사슬에 PDMS 블록을 가지며 nano clay(montmorillonite)를 가진 PNIPAAm 중합체를 합성하여 FT-IR과 XRD를 이용하여 확인하고 DSC를 이용하여 열적 성질을 조사하였으며 중합체의 온도에 따른 수팽윤도를 구하였다. DSC 측정 결과 poly(NIPAAm-b-PDMS) 속의 PNIPAAm과 PDMS는 분리된 상으로 존재했으며, 소수성인 PDMS의 함량이 증가함에 따라 수팽윤도는 감소하였으나 LCST 값은 큰 변화가 없었다. 또한, PNIPAAm의 유리전이온도 ($T_g$)는 분리된 상으로 인해 큰 변화가 없었다. 또한, 나노입자의 첨가는 전반적으로 수팽윤도에는 영향을 주지 않았으나 중합체의 $T_g$의 값은 감소하였다.

Acrylate기를 갖는 Polydimethylsiloxane계 코팅 액의 제조와 그 특성 (Preparation and Properties of Coating Materials of Polydimethylsiloxane with Acrylate Groups)

  • 박승우;강호종;강두환
    • 폴리머
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    • 제38권2호
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    • pp.138-143
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    • 2014
  • ${\alpha},{\omega}$-Hydroxypropyl기를 갖는 polydimethylsiloxane을 합성하고 이를 hexamethylenediisocyanate(HDI)의 고리화 반응으로 제조된 HDI trimer와 반응시켜 말단에 이소시아네이트 기를 갖는 PDMS 변성 urethane(PSU)을 제조하였다. 이소시아네이트기를 갖는 PSU와 2-hydroxyethylmethacrylate를 urethane 반응으로 acrylate기를 갖는 PDMS 변성 urethane base 수지(PSUA)를 제조하였으며, 이를 FTIR, NMR로 구조를 확인하여 분석하였다. 제조한 base 수지에 아크릴계 경화제, 광 개시제, 용매들을 혼합하여 코팅 액을 제조하였으며 이를 PET 필름에 도포하고 자외선으로 조사하여 고경도의 유연성을 갖는 코팅 막을 얻었다. 얻어진 코팅 막의 광 투과도는 89.7%, 연필경도는 3H, 접촉각은 $88^{\circ}$였다.

Polyorganosiloxane 변성 말레화 EPDM/EPDM 방진고무의 제조와 그 특성 (Preparation and Properties of Polyorganosiloxane Modified Maleated EPDM/EPDM Rubber Vibration Isolator)

  • 강두환;김소미
    • 공업화학
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    • 제21권5호
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    • pp.581-585
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    • 2010
  • 산업폐기물 중의 하나인 무기 금속화합물, Alnico를 1,3,5-trimethylcyclotrisilazane으로 표면 처리하여 충전제로 하고 EPDM에 maleic anhydride (MA)를 용융 중합법으로 그라프트시켜 제조한 말레화 EPDM과 ${\alpha},{\omega}$-bis(3-aminopropyl)polydimethylsiloxane을 공중합시켜 제조한 말레화 EPDM-polydimethylsiloxane공중합체(MEPDM-PDMS)와 EPDM 및 표면처리된 Alnico를 compounding하여 composite rubber를 제조하였다. EPDM/Alnico/MEPDM-PDMS 방진고무는 MEPDMPDMS와 EPDM을 중량비로 1 : 10으로 하고 또한 충전제의 함량을 EPDM에 대하여 25, 50 phrs로 그리고 개시제로 dicumyl peroxide (DCP)를 첨가하여 compounding시킨 다음 유압 고온 프레스로 가교시켜 제조하였다. 제조한 composite rubber의 열적특성을 측정한 결과 MEPDM-PDMS를 첨가하여 제조한 시료의 Tg가 EPDM만으로 제조한 고무보다 약간 낮은 $-33^{\circ}C$ 부근으로 나타났고 DMA의 측정결과 손실계수 tan ${\delta}$는 MEPDM-PDMS을 혼합한 경우가 더 크게 나타나는 것으로 보아 방진 특성이 우수함을 확인하였다.

Polydimethylsiloxane 가공 Polypropylene막에서의 기체투과 및 혈액적합성 (Gas Permeability and Blood Compatibility in Polydimethylsiloxane Polypropylene Combined Membrane)

  • 김기범;이삼철;정경락
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1998년도 추계학술대회
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    • pp.233-234
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    • 1998
  • The purpose of this paper is the evaluation of a permeability and blood compatibility for silicone/polypropylene combined membrane. Despite the overall good performances of polypropylene membrane, its long-lasting usage for artificial lung has been limited by serum leakage. In order to overcome this problem, we have newly fabricated polydimethylsiloxane(silicone)/polypropylene combined membrane(SPCM). SPCM has been proved to be serum leakage free in hours experimental. It has shown good long-lasting gas transfer and durability features.

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압전 구동 방식의 Polydimethylsiloxane(PDMS) 마이크로 펌프 (Piezoelectric-Actuated Polydimethylsiloxane(PDMS) Micropump with Diffusers)

  • 김진호;김영호;김용상
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제52권10호
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    • pp.487-491
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    • 2003
  • The low-cost, simple structured micropump which is actuated by piezoelectric-discs, is fabricated with polydimethylsiloxane (PDMS) and the performances of the micropump, such as pump rate and backpressure, are characterized. The PDMS micropump with diffusers instead of passive check valves as a flow-rectifying element was fabricated. The deflection of glass diaphragm measured by atomic force microscope (AFM) is about 0.4$\mu\textrm{m}$ when applying a 150V square wave voltage at 300Hz across a 300${\mu}\ell$ thick piezoelectric disc. While the square wave driving voltage is applied to the piezoelectric disc of the actuator, the flow rate is measured by fluid displacement variation of the outlet tube. The flow rate of micropump increases with enhancing the applied voltage due to the increase of diaphragm deflection. The flow rate and the backpressure of the micropump with diffusers are about 32.9${\mu}\ell$/min and 173Pa respectively for the above mentioned deflection conditions.

열공압 방식의 Polydimethylsiloxane 마이크로 밸브의 제작 및 특성 (Fabrication and Characteristics of Thermopneumatic-Actuated Polydimethylsiloxane Microvalve)

  • 김진호;조주현;한경희;김영호;김한수;김용상
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권4호
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    • pp.231-236
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    • 2004
  • A normally open thermopneumaticc-actuated microvalve has been fabricated and their properties are investigated. The advantages of the proposed microvalve are of the low cost fabrication process and the transparent optical property using polydimethylsiloxane (PDMS) and indium tin oxide (ITO) glass. The fabricated microvalves with in-channel configuration are easily integrated with other microfluidic devices on the same substrate. The fabrication process of thermopneumatic-actuated microvalvesusing PDMS is very simple and its performance is very suitable for a disposable lab-on-a-chip. The PDMS membrane deflection increases and the flow rates of the microchannel with microvalvels decrease as the applied power to the ITO heater increases. The powers at flow-off are dependent on the membrane thickness and the applied inlet pressure but are independent of the channel width of microvalves. The flow rate is well controlled by the switching function of ITO heater and the closing/opening times are around 20 sec and 25 sec, respectively.

열공압 방식의 polydimethylsiloxane 마이크로 펌프의 제작 및 특성 (Fabrication and Characteristics of Thermopneumatic-Actuated Polydimethylsiloxane Micropump)

  • 김진호;문민철;김주호;김영호;김한수;한경희;김용상
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권6호
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    • pp.342-346
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    • 2004
  • A thermopneumatic-actuated polydimethylsiloxane (PDMS) micropump has been fabricated and their properties are characterized. The diffusers are used as a flow-rectifying element instead of passive check valves. The advantages of the proposed microvalve are of the low cost fabrication process and the transparent optical property using PDMS and indium tin oxide (ITO) glass. We presented the PDMS micropump that is easily integrated with the in-channel PDMS microvalves on the same substrate. The flowrate of the micropump increases linearly as the applied pulse voltage to the ITO heater increases. The fabricated ITO heater resistance is 6.54k$\Omega$. The peak of the flow rate is observed at the duty ratio of 10% for the applied pulse voltage of 55V at 6Hz and the maximum flow rate of 78nl/min is measured.

마이크로 펌프와 밸브가 집적된 polydimethylsiloxane microfluidic system (A new polydimethylsiloxane microfluidic system integrated with micropump and microvalve)

  • 유종철;문민철;김주호;강치중;김용상
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2374-2376
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    • 2005
  • 본 연구에서 제안한 microfluidic system은 열공압 방식으로 구동되고 indium tin oxide (ITO) 및 polydimethylsiloxane(PDMS)로 제작하여 공정이 간단하고 비용이 저렴하여 일회용으로 사용이 가능하며 투명한 장점을 갖는다. 또한 마이크로 펌프는 인-채널 구조의 마이크로 밸브와 동일한 공정으로 제작하였다. 제안된 마이크로 펌프는 인-채널 구조의 마이크로 밸브와 같은 기판 위에 쉽게 집적하여 제작할 수 있다. 마이크로 펌프의 pumping rate는 인가 펄스 전압의 주파수와 duty비를 변화시켜 최적화하였다. Duty 비가 1%이고 주파수가 2 Hz일 때 최대 pumping rate를 보였으며 이때 pumping rate는 26.18nl/min이였다. 마이크로 밸브는 ITO 히터에 전력을 인가함으로서 유량의 on/off 제어가 잘 됨을 확인할 수 있었고 유체를 closing하기 위해 필요한 전력은 100mW이다.

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Hydrophobic modification of PVDF hollow fiber membranes using polydimethylsiloxane for VMD process

  • Cui, Zhaoliang;Tong, Daqing;Li, Xue;Wang, Xiaozu;Wang, Zhaohui
    • Membrane and Water Treatment
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    • 제10권4호
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    • pp.251-257
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    • 2019
  • Fabricating hydrophobic porous membrane is important for exploring the applications of membrane distillation (MD). In the present paper, poly(vinylidene fluoride) (PVDF) hollow fiber membrane was modified by coating polydimethylsiloxane (PDMS) on its surface. The effects of PDMS concentration, cross-linking temperature and cross-linking time on the performance of the composite membranes in a vacuum membrane distillation (VMD) process were investigated. It was found that the hydrophobicity and the VMD performance of the PVDF hollow fiber membrane were obviously improved by coating PDMS. The optimal PDMS concentration, cross-linking temperature and cross-linking time were 0.5 wt%, $80^{\circ}C$, and 9 hr, respectively.

PDMS(Polydimethylsiloxane)의 열경화조건에 따른 크랙 이용 센서 감도 최적화 (Optimization of Crack Based Sensor Sensitivity According to Thermal Curing Conditions of PDMS (Polydimethylsiloxane))

  • 황인주;윤상석;최용환
    • 열처리공학회지
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    • 제36권4호
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    • pp.237-241
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    • 2023
  • Recently, research on flexible sensors for personal health management has been gaining attention. In this study, we fabricated a crack-based flexible sensor in thin film form to measure the pulse on the wrist. We evaluated the characteristics of the sensor based on the curing conditions of the PDMS (Polydimethylsiloxane) film to optimize the sensor's gauge factor. The modulus of PDMS varies depending on the curing conditions. In this case, the modulus of PDMS has a significant influence on crack formation, leading to changes in the sensitivity of the sensor. This study examined the changes in the gauge factor associated with these variations.