• Title/Summary/Keyword: Polycarbonate Film

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A study on the molding of dome shaped plastic parts embedded with electronic circuits (전자회로 일체형 돔 형상의 플라스틱 부품 성형에 관한 연구)

  • Seong, Gyeom-Son;Lee, Ho-Sang
    • Design & Manufacturing
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    • v.14 no.1
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    • pp.15-21
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    • 2020
  • Smart systems in different application areas such as automotive, medical and consumer electronics require a novel manufacturing method of electronic, optical and mechanical functions into products. Traditional methods including mechanical assembly, bonding of plastic and electronic circuit cause the problems in large size of products and complicated manufacturing processes. In this study, thermoforming and film insert molding were applied to fabricate a dome shaped plastic part embedded with electronic circuits. The deformation of patterns printed on PET film was predicted by thermoforming simulation using T-SIM, and the results were compared with those by experiment. In order to decrease spring-back after thermoforming, the Taguchi method of design of experiment was used. Through ANOVA analysis, it was found that mold temperature was the most dominant parameter for spring-back. By using flow analysis, gate design was performed to decrease injection pressure. During film insert molding, the wash-out of ink printed on film occurred for Polycarbonate. When the resin was changed to PMMA, the wash-out disappeared due to low melt temperature.

Hybrid Passivation for a Flexible Organic Light Emitting Diode (다층 구조의 Hybrid flexible 박막 기술 연구)

  • Lee, Whee-Won;Kim, Young-Hwan;Seo, Dae-Shik;Kim, Yong-Hoon;Moon, Dae-Gyu;Han, Jeong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.269-270
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    • 2005
  • A hybrid passivation method using parylene and silicon dioxide combination layer for a flexible organic light emitting diode (FOLED) was applied on a polycarbonate substrate. A parylene coating by vapor polymerization method is a highly effective passivation process for the FOLED, and it applies all top surface and the edges of the FOLED device. In order to minimize the permeation of moisture and oxygen from the top surface of the device, an additional layer of silicon dioxide was deposited over the parylene coated layer. It was found that the water vapor transmittance rate (WVTR) of parylene (15 m-in-thickness) / SiO2 (0.3$\mu$m-in-thickness) combination layers deposited on polycarbonate film was decreased under the value of 10-3 g/m2day. The FOLED with the hybrid passivation showed remarkably longer lifetime characteristics in the ambient conditions than the non-passivated FOLED. The lifetime of the passivated FOLED was 400 hours and it was more than ten times over the lifetime of the convectional non-passivated FOLED.

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Effect of Electron Irradiation Energy on the Properties of GZO/SiO2 Thin Films on Polycarbonate (PC 기판위에 증착된 SiO2/GZO박막의 전자빔 조사에너지에 따른 특성 변화)

  • Heo, Sung-Bo;Park, Min-Jae;Jung, Uoo-Chang;Kim, Dae-Il;Cha, Byung-Chul
    • Journal of the Korean institute of surface engineering
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    • v.47 no.6
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    • pp.341-346
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    • 2014
  • Ga-doped ZnO (GZO) single layer and $SiO_2/GZO$ bi-layered films were deposited on Polycarbonate(PC) substrate by radio frequency magnetron sputtering. Influence of the structural, electrical, and optical properties of the films was considered. We have considered the influence of electron irradiation energy of 450 and 900 eV on the stuctural, electrical and optical properties of $SiO_2/GZO$ thin films. The optical transmittance in a visible wave length region increased with the electron irradiation energy. The electrical resistivity of the films were dependent on the electron's irradiation energy. The $SiO_2/GZO$ films irradiated at 900 eV were showen the lowest resistivity of $7.8{\times}10^{-3}{\Omega}cm$. The film which was irradiated by electron at 900 eV shows 84.3% optical transmittance and also shows lower than contact angle of $58^{\circ}$ in this study.

Chemical Fixation of Polyelectrolyte Multilayers on Polymer Substrates

  • Tuong, Son Duy;Lee, Hee-Kyung;Kim, Hong-Doo
    • Macromolecular Research
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    • v.16 no.4
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    • pp.373-378
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    • 2008
  • A simple chemical fixation method for the fabrication of layer-by-layer (LbL) polyelectrolyte multilayer (PEM) has been developed to create a large area, highly uniform film for various applications. PEM of weak poly-electrolytes, i.e., polyallylamine hydrogen chloride (PAH) and poly(acrylic acid)(PAA), was assembled on polymer substrates such as poly(methyl methacrylate)(PMMA) and polycarbonate (PC). In the case of a weak polyelectrolyte, the fabricated thin film thickness of the polyelectrolyte multilayers was strongly dependent on the pH of the processing solution, which enabled the film thickness or optical properties to be controlled. On the other hand, the environmental stability for device application was poor. In this study, we utilized the chemical fixation method using glutaraldehyde (GA)-amine reaction in order to stabilize the polyelectrolyte multilayers. By simple treatment of GA on the PEM film, the inherent morphology was fixed and the adhesion and mechanical strength were improved. Both surface tension and FT-IR measurements supported the chemical cross-linking reaction. The surface property of the polyelectrolyte films was altered and converted from hydrophilic to hydrophobic by chemical modification. The possible application to antireflection coating on PMMA and PC was demonstrated.

Application of Polycarbonate Diol Prepared with Carbon Dioxide in the Field of Waterborne Polyurethane (이산화탄소를 이용하여 제조된 폴리카보네이트 디올의 수분산 폴리우레탄에 응용)

  • Lim, Jae-Woo;Oh, Hyoung-Jin;Kim, Young-Jo;Jeong, Kwang-Eun;Yim, Jin-Heong;Ko, Young-Soo
    • Polymer(Korea)
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    • v.34 no.6
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    • pp.507-510
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    • 2010
  • Poly(cyclohexane carbonate) diol was synthesized by the alternating copolymerization of cyclohexene oxide and $CO_2$ over Cr based transition metal catalysts. The prepared PCCD was applied as a precursor for the preparation of waterborne polyurethane (PUD) in order to investigate an application field of carbon dioxide-based polycarbonate. The scratch resistance and thermal properties of PUDs, which was prepared with two kinds of polymeric diols (PCD and PCCD) were investigated. The scratch resistance and thermal decomposition temperature of PUD film prepared with PCCD is worse than those prepared with PCD, poly(hexamethylene carbonate) glycol. While, glass transition temperature of PUD film prepared with PCCD was higher than that prepared with PCD. It might be due to the rigid cyclohexane structure in the PCCD.

Electro-optical properties of organic thin film EL device using PPV (PPV를 이용한 유기 박막 EL 소자의 전기-광학적특성)

  • Kim, Min-Soo;Park, Lee-Soon;Park, Se-Kwang
    • Journal of Sensor Science and Technology
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    • v.7 no.2
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    • pp.97-102
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    • 1998
  • Organic thin film EL devices using PPV(poly (p-phenylenevinylene)) as emitter were fabricated on various conditions and structures, their electro-optical properties were estimated. Fabricated EL devices had structures of single layer(ITO(indium tin oxide)/PPV/Mg), double layer(ITO/PVK(poly(N-vinylcarbazole))/PPV/Mg and ITO/PPV/Polymer matrix + PBD/Mg) and three layer (ITO/PVK/PPV/PS(polystyrene)+PBD(butyl-2-(4-bipheny])-5-(4-tert-butylphenyl-1,3,4-oxadiazole))/Mg), their electro-optical characteristics were compared with each other. In structure of double layer (ITO/PPV /Polymer matrix + PBD/Mg), the used polymer-matrices were PMMA(poly(methyl methacrylate), PC(polycarbonate), PS and MCH(side chain liquid crystalline homopolymer). When PS as a hole transport layer was used, the luminance characteristics on concentration of PBD was obtained. In results, current-voltage-luminance curves of fabricated devices had characteristics of tunneling effect and the device showed a stable light emitting.

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Analysis of the Polymer Properties and Sound Characteristics of Interlayer Films for Laminated Glass (접합유리용 고분자 필름의 물성 및 음향학적 특성 분석)

  • Ko, Sangwon;Hong, Jiyoung;Sunwoo, Yerim;Kim, Young Jun
    • Journal of the Korean Society for Railway
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    • v.19 no.1
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    • pp.1-10
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    • 2016
  • To improve the sound insulation performance of laminated glass in high speed trains, it is beneficial to study the relationship between the characteristics of interlayer films and the acoustical performance. In addition to those of conventional PVB (polyvinyl butyral), the dynamic mechanical properties of PVB derivatives and PC (polycarbonate), which are candidates for interlayer films, were analyzed. We assumed that PVB-HEMU, which has a glass transition temperature ($T_g$) around room temperature and a large tan ${\delta}$ (loss tangent) value, can be made to damp efficiently. The damping capability was tested utilizing sound transmission loss measurement and simulation under the identical structure of laminated glass in high speed trains. We also built a database for analysis of relations between interlayer film characteristics and acoustical performance; this was followed by the determination of sound transmission loss using the intensity technique and FEA.

Membrane Filtration Characteristics of Oil/Water Emulsions (오일/물 에멀젼의 분리막 투과 특성)

  • Kim, Jong-Pyo;Lim, Jin-Soo;Ryu, Jong-Hoon;Kim, Jae Jin;Chung, Kun Yong;Chun, Myung-Suk;Min, Byoung-Ryul
    • Clean Technology
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    • v.5 no.2
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    • pp.69-78
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    • 1999
  • Separation characteristics of cutting oil-in-water emulsions were studied experimentally by using various kinds of flat-type microfiltration and ultrafiltration membranes. For ultrafiltration membranes the permeation behavior of cutting oil emulsions obeys the film model, whereas a significant deviation from the model was observed for ASYPOR microfiltration membranes. The experimental data obtained for all the membranes showed that the effect of operating pressure on the permeation flux of oil-in-water emulsions is not very significant. At low transmembrane pressures the permeation flux decreased gradually with increasing filtration time, whereas the permeation flux at high transmembrane pressures decreased steeply for early filtration time. However, every flux eventually reached a constant value that depends only on the applied transmembrane pressure. For the hydrophobic polycarbonate microfiltration membrane the permeation flux increased with the filtration time. The critical permeation pressures were also determined from the data obtained from unstirred cell experiments.

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