Browse > Article

Application of Polycarbonate Diol Prepared with Carbon Dioxide in the Field of Waterborne Polyurethane  

Lim, Jae-Woo (Division of Advanced Materials Engineering, Kongju National University)
Oh, Hyoung-Jin (Department of Chemical Engineering, Kongju National University)
Kim, Young-Jo (Department of Chemistry, Chungbuk National University)
Jeong, Kwang-Eun (Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology)
Yim, Jin-Heong (Division of Advanced Materials Engineering, Kongju National University)
Ko, Young-Soo (Department of Chemical Engineering, Kongju National University)
Publication Information
Polymer(Korea) / v.34, no.6, 2010 , pp. 507-510 More about this Journal
Abstract
Poly(cyclohexane carbonate) diol was synthesized by the alternating copolymerization of cyclohexene oxide and $CO_2$ over Cr based transition metal catalysts. The prepared PCCD was applied as a precursor for the preparation of waterborne polyurethane (PUD) in order to investigate an application field of carbon dioxide-based polycarbonate. The scratch resistance and thermal properties of PUDs, which was prepared with two kinds of polymeric diols (PCD and PCCD) were investigated. The scratch resistance and thermal decomposition temperature of PUD film prepared with PCCD is worse than those prepared with PCD, poly(hexamethylene carbonate) glycol. While, glass transition temperature of PUD film prepared with PCCD was higher than that prepared with PCD. It might be due to the rigid cyclohexane structure in the PCCD.
Keywords
polyurethane; poly(hexamethylene carbonate) glycol; poly(caprolactone) glycol; carbon dioxide;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By Web Of Science : 1  (Related Records In Web of Science)
Times Cited By SCOPUS : 0
연도 인용수 순위
1 C. Koning, J. Wildeson, R. Parton, B. Plum, P. Steeman, and D. J. Darensbourg, Polymer, 42, 3995 (2001).   DOI   ScienceOn
2 K.-L. Noble, Prog. Org. Coat., 32, 131 (1997).   DOI   ScienceOn
3 B. Li, G.-P. Wu, W.-M. Ren, Y.-M. Wang, D.-Y. Rao, and X.-B. Lu, J. Polym. Sci. Part A: Polym. Chem., 46, 6102 (2008).   DOI   ScienceOn
4 D. Dieterich, W. Keberle, and H. Witt, Angew. Chem., 82, 53 (1970).   DOI
5 H. Sugimoto and S. Inoue, J. Polym. Sci. Part A: Polym. Chem., 42, 5561 (2004).   DOI   ScienceOn
6 B. K. Kim and J. C. Lee, J. Polym. Sci. Part A: Polym. Chem., 34, 1095 (1996).   DOI
7 G. Jimenez, S. Asai, A. Shishido, and M. Sumita, Eur. Polym. J., 36, 2039 (2000).   DOI   ScienceOn
8 L.-H. Bao, Y.-J. Lan, and S.-F. Zhang, J. Polym. Res., 13, 507 (2006).   DOI   ScienceOn
9 M. Melchiors, M. Sonntag, C. Kobusch, and E. Jurgens, Prog. Org. Coat., 40, 99 (2000).   DOI   ScienceOn
10 C. H. Cho, H. D. Seo, B. H. Min, H. K. Cho, S. T. Noh, H. G. Choi. Y. H. Cho, and J. H. Kim, J. Korean Ind. Eng. Chem., 13, 825 (2002).
11 G. W. Coates and D. R. Moore, Angew. Chem. Int. Ed., 43, 6618 (2004).   DOI   ScienceOn
12 D. E. Fiori, Prog. Org. Coat., 32, 65 (1997).   DOI   ScienceOn
13 Z. W. Wicks, Jr., D. A. Wicks, and J. W. Rosthauser, Prog. Org. Coat., 44, 161 (2002)   DOI   ScienceOn
14 Y. Hwang, M. Ree, and H. Kim, Catal. Today, 115, 288 (2006).   DOI   ScienceOn
15 S. Inoue, H. Koinuma, and T. Tsuruta, Makromol. Chem., 130, 210 (1969).   DOI