• Title/Summary/Keyword: Polycarbonate

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A Study on the Preparation of Polycarbonate/Polypyrrole Conducting Composite and Their Electrical Properties (Polycarbonate/Polypyrrole 전도성 복합체의 제조와 전기적 성질에 관한 연구)

  • Kim, Yong-Ju;Kim, Nam-In;Lee, Wan-Jin
    • Applied Chemistry for Engineering
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    • v.10 no.6
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    • pp.923-928
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    • 1999
  • Polycarbonate(PC)/polypyrrole(PPy) conducting composites were prepared by precipitation polymerization. $FeCl_3$, pyrrole and chloroform were used as oxidant, monomer, and solvent, respectively. The electrical conductivity was increased with increasing the amount of PPy, while the mechanical property was decreased. When the PPy content was 25 wt %, the electrical conductivity of the composites was increased up to 0.23 S/cm. The electrical conductivity, the stability of conductivity in air and mechanical properties of the composites of different PPy content were investigated and the morphology of the composite films was observed.

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Growth and Yield of Tomato and Cucumber Plants in Polycarbonate or Glass Greenhouses

  • Kwon, Joon Kook;Khoshimkhujaev, Bekhzod;Lee, Jae Han;Yu, In Ho;Park, Kyoung Sub;Choi, Hyo Gil
    • Horticultural Science & Technology
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    • v.35 no.1
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    • pp.79-87
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    • 2017
  • We examined the effect of two greenhouse covering materials (glass or solid polycarbonate sheets) on the light environment and growth of tomato and cucumber plants. Spectral analysis showed that polycarbonate sheets entirely blocked radiation in both the UV - B (300 - 320 nm) and UV - A (320 - 400 nm) ranges, whereas glass transmitted UV - A and was only opaque to UV - B. The transmittance of photosynthetically active radiation (400 - 700 nm) and near infrared radiation (700 - 1100 nm) was higher in polycarbonate than glass. Air and soil temperatures were not significantly different between greenhouses covered with either material. The growth of cucumber plants was slightly affected by covering materials, whereas no significant changes in growth parameters were observed for tomato plants. The color parameters of tomato fruits were affected by the cover material, whereas cucumber fruits showed similar coloration in both glass and polycarbonate greenhouses.

Preparation of Polycarbonate/Polyaniline Conducting Composite and Their Electrical Properties (Polycarbonate/Polyaniline 전도성 복합체의 제조 및 전기적 성질)

  • Lee, Wan-Jin;Kim, Yong-Ju
    • Applied Chemistry for Engineering
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    • v.10 no.2
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    • pp.287-292
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    • 1999
  • The conducting composites were prepared by solution blending of polyaniline (PANI) as a conducting polymer and polycarbonate (PC) as a matrix in chloroform. Also the composites film was prepared by solution casting method. The PANI was protonated with alkylbenzenesulfonic acids, such as camphorsulfonic acid (CSA) or dodecylbenzenesulfonic acid (DBSA). The electrical conductivity of composites prepared by solution casting was enhanced compared with that of compression molding. The electrical conductivity, tensile strength and morphology were observed as a function of the amount of protonating agent as well as PANI complex content. In general, as the PANI complex content was increased, the electrical conductivity increased. In the case of the composite film containing 25 wt % of PANI complex doped with DBSA, the electrical conductivity exhibited 3.18 S/cm.

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A Study on Polycarbonate Microfabrication Using a Pneumatic Hot Press (공압 핫프레스를 이용한 마이크로 폴리카보네이트 성형에 관한 연구)

  • Yeo, Changyeong;Park, Taehyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.4
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    • pp.106-112
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    • 2021
  • Thermoplastic microfluidic devices are used in BioMEMS for medical and biotechnology applications, such as gene extraction, DNA analysis, and virus detection. In this research, a simple fabrication protocol with a commercially available pneumatic hot press is proposed and demonstrated for polycarbonate microfluidic devices. Microfluidic channels with a width of 200 ㎛ and a height of 10 ㎛ were designed and machined onto a brass plate as a mold insert using a CNC milling machine. The resulting microfluidic channels on the mold insert were assessed and found to have an actual width of 198 ㎛ and a height of 10 ± 0.25 ㎛. The microfluidic channels were replicated on a polycarbonate sheet using the proposed replication technique at 146℃ for 20 minutes under a constant load of 2400 kgf. The devices were then naturally cooled to 100℃ while maintaining the same pressure. It was found that the microchannels were successfully replicated in the polycarbonate, with a width of 198 ㎛ and a height of 10.07 ㎛. The proposed replication technique thus offers the rapid mass production of high-quality microfluidic devices at a low cost with a process that, unlike conventional photolithography systems, does not require expensive equipment.

Effect of NCO Index on the Particle Size of Polycarbonate Diol-based Polyurethane Dispersion

  • Kim, Dong-Eun;Kang, Seung-Oh;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.20-25
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    • 2020
  • The effect of the isocyanate index (NCO index) on the particle size and particle size distribution of a waterborne polyurethane dispersion (WPUD) with polycarbonate-diol was determined. The WPUDs were prepared using a conventional acetone process with polycarbonate-polyol (Mn = 2028), 4,4'-methylenebis(cyclohexyl isocyanate) (H12MDI), 2,2-bis(hydroxymethyl) propionic acid (DMPA), and dibutyltin dilaurate catalyst. At NCO index values below 1.5, the number average particle diameter of the WPUDs significantly increased with the NCO index, whereas the particle diameter slightly varied at higher NCO indexes. The dependency of the WPUD viscosity on the NCO index exhibited similar behavior to that of the particle size. The relative values of the full width at half maximum of the WPUD particle distribution curves at various NCO indexes were not influenced by the NCO index.

Dynamic Stress Intensity Factors and Dynamic Crack Propagation Velocities in Polycarbonate WL-RDCB Specimen (WL-RDCB 시편의 동적 균열전파속도와 동적 응력확대계수)

  • 정석주;한민구
    • Journal of the Korean Society of Safety
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    • v.11 no.3
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    • pp.3-9
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    • 1996
  • Dynamic fracture characteristics of Polycarbonate WL-RDCB specimen were investigated. The dynamic crack propagation velocities in these specimens were measured by using both high speed camera system and silver paint grid method developed and justified in the INHA Fracture Mechanics Laboratory. The measured crack propagation velocities were fed into the INSAMCR code(a dynamic finite element code which has been developed in the INBA Fracture Mechanics Laboratory) to extract the dynamic stress intensity factors. It has been confirmed that both dynamic crack arrest toughness and the static crack arrest toughness depend on both the geometry and the dynamic crack propagation velocity of specimens. The maximum dynamic crack propagation velocity of Polycarbonate WL-RDCB specimen was found to be dependent on the material property, geometry and the type of loading. The dynamic cracks in these Polycarbonate WL-RDCB specimens seemed to propagate in a successive manner, involving distinguished 'propagation-arrest-propagation-arrest' steps on the microsecond time scale. It was also found that the relat-ionship between dynamic stress intensity factor and dynamic crack propagation velocities might be represented by the typical '$\Gamma$'shape.

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Deposition of hard coatings on polycarbonate substrate by high frequency ion beam

  • Kim, Sung-Ryong;Song, Jun-Seob;Choi, Young-Joon;Kim, Jong-Hun
    • Journal of Korean Vacuum Science & Technology
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    • v.2 no.2
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    • pp.101-106
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    • 1998
  • The poor wear and scratch properties of polycarbonate have limited its application in many fields. In order to improve the wear and scratch properties of polycarbonate we have deposited diamond like carbon (DLC) coatings. The diamond like carbon coatings were made using a high frequency ion beam gun by introducing H2 and CH4 gases. The coatings were characterized with Raman spectroscopy, scanning electron microscope, ellipsometer, microscratch tester and hazemeter. Polymeric hard coating was applied onto the polycarbonate substrate before depositing a DLC coating to investigate the effect of interlayer on the system's failure mode.

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The Effect of Injection Molding Temperature on the Morphology of Polycarbonate/ABS blends (Polycarbonate/ABS 블렌드에서 사출온도에 따른 모폴로지 변화에 관한 연구)

  • Son, Young-Gon
    • Elastomers and Composites
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    • v.39 no.4
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    • pp.324-329
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    • 2004
  • The phase morphology, degree of craze and impact property in Polycarbonate (PC)/Acrylonitrile-Butadiene- styrene (ABS) blend containing the phosphate based flame retardant were studied in terms of injection molding temperatures. As the injection molding temperature increases, significant amount of coalescences and crazes were observed and impact strength decreased. It was also observed that the addition of compatibilizer into the blends suppresses the coalescence and craze.

Influence of natural and accelerated weathering of polycarbonate (폴리카보네이트 소재의 자연폭로와 실내촉진 내후성 영향)

  • Moon, Jung-mi;Jang, Ho-Jin;Kim, Chang-Hwan
    • Journal of the Korean institute of surface engineering
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    • v.55 no.6
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    • pp.383-389
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    • 2022
  • Natural(outdoor) and accelerated(artificial) weathering tests were performed to investigate their influence on polycarbonate. The polycarbonate materials were prepared of various formulations divided into three batches, with existing, development materials1, development materials2, containing mixture of UV additives. Weathering tests were carried out as outdoor weathering(Seosan, South Korea) and accelerated weathering(xenon-arc), and the results analysis were evaluated based on yellow-index(YI), scanning electron microscope(SEM/EDS), energy dispersive x-ray spectroscopy(XRD), and gel permeation chromatography(GPC). Among the three materials, processing method development materials1 with UV stabilizer was excellent in weathering. This study can provide basic data for standardization of development and performance evaluation on livestock barn roof.