• Title/Summary/Keyword: Polycarbonate

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Hybrid Passivation for a Flexible Organic Light Emitting Diode (다층 구조의 Hybrid flexible 박막 기술 연구)

  • Lee, Whee-Won;Kim, Young-Hwan;Seo, Dae-Shik;Kim, Yong-Hoon;Moon, Dae-Gyu;Han, Jeong-In
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.269-270
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    • 2005
  • A hybrid passivation method using parylene and silicon dioxide combination layer for a flexible organic light emitting diode (FOLED) was applied on a polycarbonate substrate. A parylene coating by vapor polymerization method is a highly effective passivation process for the FOLED, and it applies all top surface and the edges of the FOLED device. In order to minimize the permeation of moisture and oxygen from the top surface of the device, an additional layer of silicon dioxide was deposited over the parylene coated layer. It was found that the water vapor transmittance rate (WVTR) of parylene (15 m-in-thickness) / SiO2 (0.3$\mu$m-in-thickness) combination layers deposited on polycarbonate film was decreased under the value of 10-3 g/m2day. The FOLED with the hybrid passivation showed remarkably longer lifetime characteristics in the ambient conditions than the non-passivated FOLED. The lifetime of the passivated FOLED was 400 hours and it was more than ten times over the lifetime of the convectional non-passivated FOLED.

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Program Development for Extracting the Numerical Data of Aspherical Surface for the Core Manufacturing of Ophthalmic Lens (안경렌즈 코아 가공을 위한 비구면 형상 도출 프로그램 개발)

  • Lee, Dong-Hee
    • Journal of Korean Ophthalmic Optics Society
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    • v.12 no.4
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    • pp.87-90
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    • 2007
  • To manufacture the lens mold used in producing polycarbonate (PC) lenses, the core manufacturing is needed and this core manufacturing is generally performed by diamond turning machine (DTM) or computer numerical control (CNC) lathe. The numerical data about the lens core feature is necessarily needed for operating of these devices. Therefore, we developed the program which calculate the numerical data about the lens core feature. The program was composed to be able to input aspherical coefficients of lens feature, display the graph of lens feature, and save the numerical data file.

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Control of morphology and interfacial tension of PC/SAN blends with compatibilizer

  • Kim, J.H.;Kim, M.J.;Kim, C.K.;Lee, J.W.
    • Korea-Australia Rheology Journal
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    • v.13 no.3
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    • pp.125-130
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    • 2001
  • Block copolymers of PC-b-PMMA (polycarbonate-b-polymethylmethacrylate) and PC -b-SAN (polycarbonate-b-(styrene-c-acrylonitrile)), were examined as compatibilizers for blonds of PC with SAN copolymer. The average diameter of the dispersed particles was measured with an image analyser, and the interfacial properties of the blonds were analysed with an imbedded fiber retraction (IFR) technique. The average diameter of dispersed particles and interfacial tension of the PC/SAN blends reached a minimum value when the SAN copolymer contained about 24 wt% AN. Interfacial tension and particle size were further reduced by adding compatibilizer to the PC/SAN blends. PC-b-PMMA was more effective than PC-b-SAN as a compatibilizer in reducing the average diameter of the dispersed particles and interfacial tension of PC/SAN blend. A direct proportionality between the particle diameter and interfacial tension was also observed. The interfacial properties of the PC/SAN blends were optimized by adding a block copolymer and using an SAN copolymer that had minimum interaction energy with PC.

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Dynamic Viscoelasticity and Optical Properties of Poly(carbonate-g-styrene) Copolymers in the Glass Transition Zone (Poly(carbonate-g-styrene)공중합체의 유리정이 영역에서의 동적 점탄성과 광학특성)

  • 황의정
    • The Korean Journal of Rheology
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    • v.9 no.4
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    • pp.163-173
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    • 1997
  • Polystyrene/polycarbonate 조성이 약 50/50인 3종류의 Poly(carbonate-g-styrene) 공중합체의 동적 탄성율, E*($\omega$)와 동적 스트레인-광학계수 O*($\omega$)을 유리전이 영역부근의 여러온도에서 동시에 측정하여 연구하였다. 두 개의 공중합체는 각각의 스티렌 그라프트쇄 에 5, 10 wt%의 MAH를 함유하고 있다. 이들 공중합체의 E*($\omega$)와 O*($\omega$)완화거동과 그라 프트 공중합체의 상용성과 연관하여 비교 고찰하였다. 공중합체들의 E*($\omega$)는 전형적인 무 정형 고분자의 유리전이 완하거동을 보였으며 정성적인 차이를 발견할수 없었다. 그러나 고 강도의 단일 tan$\delta$분산의 저주파수 영역에 미세분산을 나타내, 공중합체는 2상으로 분리되 어 있음이 추정되엇다. 폴리스티렌 그라프트체에 무수 말레인산 함유량이 증가함에 따라, 저 주파수 영역의 미세피크가 $\alpha$주분산에 병합되어 성분 고분자간의 상호 형동성이 증가함을 알수 있었다. 3공중합체의 유사한 기계적 특성과는 달리, 광학적 완화 스펙트럼 O*($\omega$)는 정 성적으로 명확한 차이를 보여 공중합체들의 광학완화 거동이 명확히 다름을 나타냈다. 기계 적 특성보다는 광학적 특성이 공중합체내의 성분 고분자의 미세한 완하 거동에 훨씬 민감한 응답을나타냈다. 이러한 특성적인 공중합체의 O*($\omega$)차이를 공중합체의 조성단일 고분자 PS, PC의 O*($\omega$)의 가성성을 가정하여 모사하였다 모사에서 구한 광학적 부분 기여 파라메 터를 사용하여 공중합체의 상용성을 고찰하였다.

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Direct Determination of Uric Acid in Human Serum Samples Using Polypyrrole Nanoelectrode Ensembles

  • Yang, Guangming;Tan, Lin;Shi, Ya;Wang, Suiping;Lu, Xuxiao;Bai, Huiping;Yang, Yunhui
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.454-458
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    • 2009
  • Polypyrrole (PPy) nanotubes have been synthesized by chemical oxidative polymerization of pyrrole within the pores of polycarbonate membrane using the technology of diffusion of solutes. The nanotubes array prepared by the proposed method can be considered as nanoelectrode ensembles (NEEs). An amperometric uric acid sensor based on PPy NEEs has been developed and used for determination of uric acid in human serum samples. The electrode can direct response to uric acid at potential of 0.60V vs. SCE with wide linear range of $1.52{\times}10^{-6}\;to\;1.54{\times}10^{-3}\;M.\;The\;detection\;limit\;is \;3.02{\times}10^{-7}$ M. This sensor has been used to determine uric acid in real serum samples. PPy NEEs is thought of as a good application in the foreground.

Development of LED Lamp which using Transparent Plastic Substrates (플라스틱 기판을 이용한 LED 투명 광원 구현)

  • Hong, Dae-Woon;Lee, Song-Jae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.5
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    • pp.1-7
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    • 2010
  • LEDs, compared to conventional light sources, have many advantages and their applications are rapidly expanding, especially in areas such as back-lights for LCD. In this paper, we propose a new LED lamp structure suitable for applications requiring a low power. In the proposed LED lamp structures, LED chips are mounted on a transparent polycarbonate plate, and thus photons are transmitted through the both sides of the plate. The copper layer deposited on the polycarbonate plate is patterned to form circuit patten and the chip mount pad, on which LED chips are mounted. We speculate that our proposed LED lamp structures may be used as a type of plate light source.

Dependance of thickness on the properties of B doped ZnO:Al (AZOB) thin film on polycarbonate (PC) substrate at room temperature (PC 기판에 저온 증착한 AZOB 박막의 두께에 따른 특성 변화)

  • Yu, Hyun-Kyu;Lee, Kyu-Il;Lee, Jong-Hwan;Kang, Hyun-Il;Lee, Tae-Yong;Oh, Su-Young;Song, Joon-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.138-138
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    • 2008
  • In this study, effect of thickness on structural, electrical and optical properties of B doped ZnO:Al (AZOB) films was investigated. AZOB films were deposited on PC substrates by DC magnetron sputtering. The thickness range of films were from 300 nm to 800 nm to identified as increasing thickness, stress between substrate and AZOB film. The. average transmittance of the films was over 80 % until 500 nm. Then a resistivity of $1.58\times10^{-3}\Omega$-cm was obtained. We presented that a AZOB film of 500 nm was optimization to obtain a high transmittance and conductivity.

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Preparation of Photochromic Coating Films Containing Spiropyran by Sol-Gel Method (Sol-Gel법에 의해 Spiropyran을 함유한 광 변색 코팅 막의 제조)

  • Jeong, Sang Hyeok;Cho, Kyung In;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.112-117
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    • 2008
  • Organic-inorganic hybrid solutions were prepared via sol-gel method using glycidoxypropyl trimethoxysilane (GPTMS) and methyl triethoxysilane (MTES) as starting precursors at a molar ratio of 1:1. The photochromic coating solutions were prepared by mixing the solutions of photochromic dye (spiropyran) dissolved in ethylacetate (EA) with the organic-inorganic hybrid solutions. Photochromic films were prepared on polycarbonate substrate by spin coating and cured for 2 h at $100^{\circ}C$. The resulting films exhibited a reversible color change upon irradiation with UV light. The photochromic properties of the films showed that the color-fading speed increases with increasing the EA content in the coating solutions.

Effect of Addition of Pentaerythritol Triacrylate on the Properties of Waterborne Polyurethane (수분산 폴리우레탄의 물성에 미치는 Pentaerythritol Triacrylate의 첨가 효과)

  • Shin, Yong Tak;Hong, Min Gi;Choi, Jin Joo;Lee, Won Ki;Yoo, Byung Won;Lee, Myung Goo;Song, Ki Chang
    • Korean Chemical Engineering Research
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    • v.49 no.4
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    • pp.411-416
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    • 2011
  • NCO terminated polyurethane prepolymers were synthesized from isophorone diisocyanate(IPDI), polycarbonate diol(PCD) and dimethylol propionic acid(DMPA). Subsequently, acrylic terminated prepolymers were prepared by capping the NCO groups of polyurethane prepolymers with different moles of pentaerythritol triacrylate (0~0.024 moles) as a acrylate monomer. The average particle size of the acrylic terminated polyurethane solutions was increased with increasing PETA contents. Also, the prepared coating films showed better abrasion resistance and pencil hardness than pure waterborne polyurethane.

Dynamic Fracture Behavior of Some Polymeric Materials (고분자재료의 동적 파괴거동에 관한 연구)

  • 이억섭;한정우;한문식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.7
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    • pp.1630-1641
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    • 1995
  • The dynamic stress intensity factors (DSIF ; $K_{I}$$^{dyn}$) were studied in some polymeric materials using caustics method with a high speed camera system. Also crack tip propagation speed was measured by dynamic crack propagation velocity measuring device. To calculate DSIF a finite element analysis program-INha Stress Analysis Moving CRack(INSAMCR) was utilized. Dynamic fracture characteristics were investigated to verify a relationship between DSIF and crack tip propagation speed and acceleration in PMMA, Homalite-100 and Polycarbonate. The relationship between dynamic stress intensity factor and crack tip velocity revealed typical shapes. Measured crack tip acceleration data envelope converges to the zero level with increasing DSIF. Equivalently crack tip velocities show a wide spread range at low values of DSIF, but become a constant with a higher DSIF. $1.2MPa{\sqrt{m}}$, $1.4MPa{\sqrt{m}}$ and $1.3 MPa{\sqrt{m}}$ were obtained as $K_{I}$$^{dyn}$ values to arrest the dynamic crack for PMMA, Homalite-100 and Polycarbonate, respectively. INSAMCR was run to verify experimental results in PMMA and shows good agreementment.