• Title/Summary/Keyword: Polyamide-12

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Preparation of graphene oxide incorporated polyamide thin-film composite membranes for PPCPs removal

  • Wang, Xiaoping;Li, Nana;Zhao, Yu;Xia, Shengji
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.211-220
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    • 2018
  • Incorporating nano-materials in thin-film composite (TFC) membranes has been considered to be an approach to achieve higher membrane performance in various water treatment processes. This study investigated the rejection efficiency of three target compounds, i.e., reserpine, norfloxacin and tetracycline hydrochloride, by TFC membranes with different graphene oxide proportions. Graphene oxide (GO) was incorporated into the polyamide active layer of a TFC membrane via an interfacial polymerization (IP) reaction. The TFC membranes were characterized with FTIR, FE-SEM, AFM; in addition, the water contact angle measurements as well as the permeation and separation performance were evaluated. The prepared GO-TFC membranes exhibited a much higher flux ($3.11{\pm}0.04L/m2{\cdot}h{\cdot}bar$) than the pristine TFC membranes ($2.12{\pm}0.05L/m2{\cdot}h{\cdot}bar$) without sacrificing their foulant rejection abilities. At the same time, the GO-modified membrane appeared to be less sensitive to pH changes than the pure TFC membrane. A significant improvement in the anti-fouling property of the membrane was observed, which was ascribed to the favorable change in the membrane's hydrophilicity, surface morphology and surface charge through the addition of an appropriate amount of GO. This study predominantly improved the understanding of the different PA/GO membranes and outlined improved industrial applications of such membranes in the future.

Improved performance of polyamide nanofiltration membranes by incorporating reduced glutathione during interfacial polymerization

  • Jiao, Zhiwei;Zhou, Linjie;Wu, Mengyuan;Gao, Kang;Su, Yanlei;Jiang, Zhongyi
    • Korean Journal of Chemical Engineering
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    • v.35 no.12
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    • pp.2487-2495
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    • 2018
  • Inspired by the specific amino acid sequence Asn-Pro-Ala (NPA) of water channel aquaporins (AQPs), we fabricated polyamide (PA) nanofiltration (NF) membranes by introducing reduced glutathione (GSH) in interfacial polymerization (IP) method. Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectrometry (XPS), scanning electron microscope (SEM), atomic force microscopy (AFM), zeta potential and static water contact angle measurement were employed to characterize the chemical composition, morphology, electronegativity and hydrophilicity of the NF membranes. The water flux of GSH/PIP-TMC NF membrane reached $32.00L\;m^{-2}h^{-1}$ at 0.2 MPa, which was approximately twice than that of pristine PIP-TMC NF membrane when the ratio of GHS to piperazidine (PIP) was 40% during IP process. More water channels were built as GSH was embedded into PA layer. The fabricated NF membranes also took on potent rejection for dyes and $Na_2SO_4$. This study presents a simple and facile method to simulate water channels-based biological materials which may find potential application in water treatment.

Spring Back on the Compound Bending of the Plastic Fuel Tube for Automobile (자동차용 플라스틱 연료튜브의 복합 벤딩에 대한 스프링백)

  • Moon, C.Y.;Park, J.S.;Jeong, Y.D.
    • Journal of Power System Engineering
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    • v.7 no.2
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    • pp.51-55
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    • 2003
  • Recently the requirements for light weight and high performance of the automobile have increased. Especially, the plastic fuel tube makers have made their efforts to dove]op the various plastic fuel tube module with not only dimensional accuracy but also cost competitiveness. The experiment is performed to investigate spring backs for PA12 plastic fuel tubes in case of compound bending. In the experiment, steam bending process is adopted as bending method. In this study, the results we obtained are used to design the bending fixtures and the compound bending system.

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Development of New Polymer Powders for the Industrial SFF system by using SLS Process (SLS 공정을 이용한 산업용 SFF 시스템용 신소재 고분자분말 개발)

  • Bang, Young-Kil;Choi, Ki-Seop;Park, Chang-Hyun;Kim, Hyung-Il;Lim, Byung-Seok;Kim, Dong-Soo
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.1404-1409
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    • 2007
  • Polymers for laser sintering were needed in order to fabricate the articles with the three-dimensional duplication equipment of SLS (selective laser sintering) process. The thermal properties, particle size, distribution, and shape of polymer powder had a close relation with the processibility of laser sintering. In this study, we prepared new polymer powders with uniform size and higher bulk density by wet process. Wet process consists of several finely-controlled steps such as dissolution, nucleation, propagation and crystallization. Several additives were added to improve the thermal, rheological, and flow properties.

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Study on the Textile Structural Design using SLS 3D Printing Technology -Focused on Design of Flexible Woven Fabric Structure- (SLS 방식의 3D 프린팅 기술을 활용한 직물구조적인 디자인설계 연구 -유연성 있는 직조구조 직물설계를 중심으로-)

  • Song, HaYoung
    • Journal of Fashion Business
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    • v.23 no.3
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    • pp.67-84
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    • 2019
  • Since the early 2000s, various fashion design products that use 3D printing technology have constantly been introduced to the fashion industry. However, given the nature of 3D printing technology, the flexible characteristics of material of textile fabrics is yet to be achieved. The aim of this study is to develop the optimal design conditions for production of flexible and elastic 3D printing fabric structure based on plain weave, which is the basic structure in fabric weaving using SLS 3D printing technology. As a the result this study aims to utilize appropriate design conditions as basic data for future study of flexible fashion product design such as textile material. Weaving structural design using 3D printing is based on the basic plain weave, and the warp & weft thickness of 4mm, 3mm, 2mm, 1.5mm, 1mm, and 0.7mm as expressed in Rhino 6.0 CAD software program for making a 3D model of size $1800mm{\times}180mm$ each. The completed 3D digital design work was then applied to the EOS SLS Machine through Maker ware, a program for 3D printer output, using polyamide 12 material which has a rigid durability strength, and the final results obtained through bending flexibility tests. In conclusion, when designing the fabric structure design in 3D printing using SLS method through application of polyamide 12 material, the thickness of 1 mm presented the optimal condition in order to design a durable digital textile structure with flexibility and elasticity of the 3D printing result.

Filtration Characteristics of Magnetic Fibrous Polymeric Filter Elements for Industrial Lub-systems (산업용 자성폴리머 필터소재의 여과특성 연구)

  • 안병길;최웅수;이용훈;정용진;권오관
    • Tribology and Lubricants
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    • v.12 no.3
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    • pp.39-47
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    • 1996
  • The magnetic fibrous polymeric oil filter elements for industrial lub-systems were obtained by pneumoextrusion processing prepared from thermoplastic pqlymer (polyamide) containing a magnetic particulate filler (Ba ferrite), and treated subsequently in a magnetic fields. Using the standard laboratory oil filtration test rig, metallic particle quantifier and image analyser system, the dependence of filtration charateristics of the magnetic filter media on the parameters of porosity and magnetic properties was investigated. The pressure drops and efficiencies of lubricating filter elements were measured on the packing density and magnetised filler content of filter element. Also, the industrial lub-systems such as lubricant filters for gear test rig and electric discharge processing machine were used for testing the flitrational characteristics of tl, c magnetised filter elements. The magnetic fibrous polymeric filter material was shown to possess a highly filtration efficiency in filtering the fine ferrous particles with increasing the magnetic force of filter element. Therefore, it is expected that the magnetic fibrous polymeric filter material should be used for effective oil filrers on the industrial lub-systems.

Flow and Engineering Properties of Fiber Reinforced Hwangtoh Mortars

  • Mun, Ju-Hyun;Yang, Keun-Hyeok;Hwang, Hye-Zoo
    • Journal of the Korea Institute of Building Construction
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    • v.12 no.3
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    • pp.332-339
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    • 2012
  • In this study, six mortar mixes were tested in order to examine the significance and limitations of hydrophilic fiber in terms of its capacity to enhance the tensile resistance of Hwangtoh mortar. Lyocell, polyamide and polyvinyl alcohol (PVA) fibers were selected for the main test parameters. The tensile capacity of mortars tested was evaluated based on the splitting tensile strength and the modulus of fracture, while their ductility was examined using the toughness indices specified in ASTM. Test results showed that the addition of lyocell and PVA fibers had little influence on the flow of the Hwangtoh mortars. To enhance the tensile capacity and toughness index of Hwangtoh mortar, it is proposed that fiber spacing above 0.0003 is required, regardless of the type of fiber.

Preparation and Softening Effect of Fatty Polyamide Type Nonionic Durable Softer (지방산 폴리아미드계 비이온성 내구유연제의 제조와 유연효과에 관한 연구)

  • Ko, Jae-Yong;Jeon, Young-Je;Hong, Eui-Suk;Park, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.65-73
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    • 1995
  • 1, 3-Di(dodecanoyl)-2, 7-dioxy-6, 8-di(2-hydroxyethyl)-1, 3, 6, 8-tetraazacyclodecane(DDDT) and pentaerythritol monostearate(PMS) were synthesized as a main component for softner. O/W type softner(DPSA) was prepared by blending DDDT and PMS with polyoxyethylene(10) castor oil, polyoxyethylene(20) oleyl ether, and polyoxyethylene(10) monolaurate. After treatment of DPSA to all cotton fabrics, the physical properties such as tear strength, crease recovery, and flexing abrasion resistance were measured. As a result of the measurement, DPSA was proved to be durable softner with good softness.