• 폴리머
• /
• 제32권4호
• /
• pp.353-358
• /
• 2008

EPDM에 maleic anhydride를 그래프트시켜 말레화 EPDM(MEPDM)을 제조하고 여기에 양 말단에 hydroxyl기를 갖는 $\alpha$,$\omega$-poly(dimethylsiloxane)(PDMS)을 반응시켜 MEPDM-g-PDMS 공중합체를 제조하였다. MEPDM-g-PDMS와 HDFE 및 4-ethoxybenzoic acid로 표면처리된 MWCNT를 internal mixer에 가하고 $180^{\circ}C$에서 컴파운딩하여 MEPDM-g-PDMS/HDPE/CNT 복합체를 제조하였다. 복합체에서 CNT의 모폴로지를 전자현미경으로 측정한 결과 표면처리된 CNT를 사용한 경우가 분산이 균일하게 이루어졌으며 입자의 응집현상도 감소되는 것으로 나타났다. 온도변화에 따른 전기저항은 용융온도부근에서 전기저항이 급격히 증가하였으며 EtO-CNT의 함량을 15%로 하여 제조한 복합체의 경우가 PTC intensity가 2.3으로 가장 우수한 PTC 특성을 나타내었다.

• 한국안광학회지
• /
• 제11권1호
• /
• pp.49-53
• /
• 2006

Diisocynate를 HEMA(2-hydroxyethylmethacrylate)와 DBTDL(Dibutylitin dilaurate) 촉매 하에서 반응시킨 후 다시 고 산소 투과성 특성을 가지는 bis(hydroxyalkyl)terminated poly(dimethylsiloxane)를 반응시켜 Acrylate-PDMS(Polydimethylsiloxane)-Urethane Prepolymer를 합성하였다. HEMA(2-hydroxyethyl-methacrylate)는 중합 가능한 prepolymer를 만들기 위해서 사용하였으며, Urethane의 도입은 탄성이 좋고 산소투과성을 높이기 위해 사용하였다. 이들의 반응은 FT-IR로 확인하였으며, 이 고분자 재료는 고 산소투과성 하이드로 젤 렌즈의 원료로 사용될 것이다.

• 폴리머
• /
• 제30권3호
• /
• pp.224-229
• /
• 2006

3-Aminopropyldimethylethoxysilane (AS)과 methyliodide를 이용하여 4차 암모늄 실란을 제조하고 7,7,8,8-tetracyanoquinodimethane (TCNQ)과 methyliodide 및 요오드화 리튬을 이용하여 $Li^+TCNQ^-$를 제조하였다. 제조한 4차 암모늄 실란에 $Li^+TCNQ^-$를 가하여 4차 암모늄 실란-TCNQ adduct(ST)를 제조하고 이를 말단에 OH기를 갖는 poly(dimethylsiloxane) (PDMS)과 축합반응시켜 poly(dimethylsiloxane)-ST adduct(PST)를 제조하였다. PST 변성 말레화 폴리에틸렌(PST-g-MPE)은 말레화 폴리에틸렌과 PST를 internal mixer(Rheomix 600P)를 사용하여 용융중합으로 제조하였으며 여기에 카본블랙 (CB)의 함량을 변화시켜 PST-g-MPE/CB 및 MPE/CB 복합체를 제조하였다. 제조한 복합체의 열적 특성을 측정한 결과 유사한 열분해 온도를 나타내었다. PST-g-MPE/CB 복합체의 인장강도는 카본블랙의 함량 증가에 따라 $200\sim308MPa$로 증가하였으며 모폴로지를 측정한 결과 MPE/CB 복합체보다 PST-g-MPE/CB 복합체의 경우에서 카본블랙의 분산이 보다 더 잘 이루어졌음을 확인하였다.

• 폴리머
• /
• 제32권2호
• /
• pp.95-102
• /
• 2008

The $\alpha$,$omega$-diacrylate poly(dimethylsiloxane) (DA-PDMS) containing vinyl ester of versatic acid/vinyl acetate (Veova-10/VAc) was prepared by emulsion copolymerization of (DA-PDMS), Veova-10 (with VAc), and auxiliary agents at $85^{\circ}C$ in the presence of ammonium peroxodisulfate (APS) as an initiator. Sodium dodecyl sulfate (SDS) and nonylphenol ethylene oxide-40 units (NP-40) were used as anionic and nonionic emulsifiers, respectively. The resulting copolymers were characterized by using Fourier transform infrared spectroscopy (FT-IR). Thermal properties of the copolymers were studied by using thermogravimetric analysis(TGA) and differential scanning calorimetry (DSC). The morphology of copolymers was also investigated by scanning electron microscopy (SEM) and then the effects of variables such as temperature, agitation speed, surfactant kinds, molecular weights, initiator, and DA-PDMS concentrations on the properties of the silicone-containing Veova-10/VAc emulsions were examined. The calculation of monomer conversion versus time histories indicates that by increasing the DA-PDMS concentration the polymerization rate and the number of polymer particles decrease, respectively.

• 폴리머
• /
• 제34권2호
• /
• pp.154-158
• /
• 2010

$\alpha$,$\omega$-Dichlorohexamethyltrisiloxane의 aniline과 고리 반응으로부터 N-phenylcyclotrisiloxazane($D_3^{NPh}$)을 합성하고 이를 hexamethylcyclotrisiloxane$D_3$과 이온 공중합시켜 poly(dimethylsiloxane-co-N-phenylsiloxazane)공중합체(PDMS-NPSOX)를 제조하였다. 이를 chloroethyl methacryalte에 도입하여 PDMS-NPSOX unit가 도입된 아크릴 단량체를 제조하였으며, 이를 MMA 및 n-butyl acrylate와 공중합시켜 PDMS-NPSOX가 도입된 삼원 아크릴 공중합체를 제조하고, 그 특성을 조사하였다. 단량체 조성은 생성 공중합체의 $T_g$가 25 $^{\circ}C$가 되도록 선택하여 공중합시켰다. 공중합체에서 PDMS만 도입된 경우 $T_g$가 20 $^{\circ}C$인데 비하여 PDMS-NPSOX unit이 도입됨에 따라 25 $^{\circ}C$로 증가되었으며 접착력도 1.76 N/cm에서 2.23 N/cm로 증가되었다.

• Macromolecular Research
• /
• 제11권2호
• /
• pp.128-131
• /
• 2003

Triblock copolymers of poly(dimethylsiloxane) (PDMS) middle block and degradable polyester end blocks were synthesized by the ring open polymerization initialed by alcohol groups of PDMS. Surface composition of the triblock copolymers is measured by angle-dependent electron spectroscopy for chemical analysis. The PDMS blocks are segregated in the topmost surface region and constituted up to 90 mol% of the surface, even though the overall bulk PDMS concentrations of the block copolymers is 6% or less. This result suggests that the bulk property of degradable polyesters is essentially unchanged due to the high surface segregation of PDMS.

• 센서학회지
• /
• 제27권6호
• /
• pp.392-396
• /
• 2018

Structural color has many advantages over pigment based color. In recent years, researches are being conducted to apply these advantages to applications such as wearable devices. In this study, strain sensor, a kind of wearable device, was developed using structural color. The use of structural color has the advantage of not using energy and complex measuring equipment to measure strain rate. Wrinkle structure was fabricated on the surface of Poly-dimethylsiloxane (PDMS) and used it as a sensor which color changes according to the applied strain. In addition, a transmittance-changing sensor was developed and fabricated by synthesizing additional glass nanoparticles. Furthermore, a strain sensor was developed that is largely transparent at the target strain and opaque otherwise.

• 한국막학회:학술대회논문집
• /
• 한국막학회 1997년도 추계 총회 및 학술발표회
• /
• pp.124-126
• /
• 1997

1. 서론 : 투과증발이란 비다공성 고분자막을 이용하여 수착, 확산, 및 증발기구를 통해 액체혼합물을 분리하는 기술이다. 따라서 투과증발의 분리효율은 고분자막의 종류 및 형태의 다양성뿐만 아니라 여러 단계의 기구 특성에 의해 결정된다. 일반저긍로 투과증발막의 성능은 분리하고자 하는 물질에 대한 선택도와 투과도로서 나타날 수 있다. (중략) 본 연구에서는 Poly(dimethylsiloxane)과 세라믹 지지체의 복합막을 이용하여 IPA(Isopropanol)/물 계에서의 여러 조업변수에 따른 IPA의 분리특성을 연구하였다.

• 한국응용과학기술학회지
• /
• 제25권2호
• /
• pp.115-122
• /
• 2008

The hydrosilylation is an addition reaction of Si-H bond to unsaturated double bonds, which provides a convenient mechanism to synthesize poly(dimethylsiloxane-co-methylsiloxane)copolymer having siloxy units in polymer backbone. In this study, Poly(dimethylsiloxane-co-methylsiloxane) copolymer was synthesized through the polymerization reaction of cyclopentasiloxane with poly(methyl-hydrogen) siloxane. Silicone-hydrogen functional group of the poly(dimethylsiloxane-co-methylsiloxane) copolymer was substituted to the alkyl groups by hydrosilylation. And their structure was analyzed with FT-IR, H-NMR and GPC instruments, respectively. Surface tension of the synthetic compounds is increased from 22dyne/cm to 25dyne/cm according to increase additional EO moles. The cmc which was evaluated by surface tension was ranged $10^{-5}$ to $10^{-4}mol/L$ and it was decreased according to increase of dimethyl siloxyl content. HLB number of these surfactants was evaluated 9.5 to 11.5 range. These silicone surfactants is applied to self-emulsifier defoamer and personal care products as surface tension depressant, emulsifier, foam control agent.

• 한국염색가공학회지
• /
• 제20권1호
• /
• pp.8-15
• /
• 2008

We presented the modified decal-transfer lithography (DTL) and light stamping lithography (LSL) as new powerful methods to generate patterns of poly(dimethylsiloxane) (PDMS) on the substrate. The microstructures of PDMS fabricated by covalent binding between PDMS and substrate had played as barrier to locally control wettability. The transfer mechanism of PDMS is cohesive mechanical failure (CMF) in DTL method. In the LSL method, the features of patterned PDMS are physically torn and transferred onto a substrate via UV-induced surface reaction that results in bonding between PDMS and substrate. Additionally we have exploited to generate the patterning of rhodamine B and quantum dots (QDs), which was accomplished by hydrophobic interaction between dyes and PDMS micropatterns. The topological analysis of micropatterning of PDMS were performed by atomic force microscopy (AFM), and the patterning of rhodamine B and quantum dots was clearly shown by optical and fluorescence microscope. Furthermore, it could be applied to surface guided flow patterns in microfluidic device because of control of surface wettability. The advantages of these methods are simple process, rapid transfer of PDMS, modulation of surface wettability, and control of various pattern size and shape. It may be applied to the fabrication of chemical sensor, display units, and microfluidic devices.