• 한국표면공학회지
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• 제49권1호
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• pp.26-31
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• 2016

In this paper, the characteristics of a cavitation-erosion damage behavior on the STS 304 and hot-dip aluminized STS 304 under cavitation environment in sea water solution was investigated. The electrochemical experiments were carried out by potential measurement, anodic/cathodic polarization test, Tafel analysis, and also galvanostatic experiment in current density variables for the samples. The apparatus of cavitation-electrochemical experiment was manufactured in compliance with modified ASTM G-32 standard, with the conditions of sea water temperature of $25^{\circ}C$ and the measurement, amplitude of $30{\mu}m$. The damage behavior was analyzed by an observation of surface mophologies and a measurement of damage depth by a scanning electron microscope(SEM) and a 3D microscope, respectively, after electrochemical test. After polarization experiment under cavitation environment, much higher damage depths for the hot-dip aluminized STS 304 were observed comparing to the untreated STS 304. In addition, higher corrosion current density in hot-dip aluminized STS 304 presented than that of untreated STS 304 as a result of Tafel analysis.

• 한국지구물리탐사학회:학술대회논문집
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• 한국지구물리탐사학회 2008년도 공동학술대회
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• pp.179-184
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• 2008

충적층 구성 물질 중 포화된 실트 혹은 점토층은 상대적으로 낮은 전기비저항 값을 나타낸다. 낮은 전기비저항 값은 이 지층을 투수성이 높은 대수층으로 오인하는 문제를 발생시킨다. 이러한 문제를 극복하고 충적층 내 포화된 실트 혹은 점토층과 모래 혹은 자갈 대수층을 구분하기 위해 전기비저항 조사와 함께 유도분극 조사를 활용하는 방안을 검토하였다. 본 연구에서는 우선, 실내 실험을 통해 충적층 구성 물질별 전기비저항(resistivity)과 충전성(chargeability)을 조사하였고, 비분극 전극을 활용한 현장 수직 전기비저항/유도분극 조사를 수행하였다. 실내 실험을 통해 모래/점토 혼합층에서 점토함량이 증가함에 따라 비저항은 낮아지고, 충전성은 높아짐을 확인하였다. 이러한 실험 결과를 바탕으로 강변여과 현장에서 전기비저항/유도분극 조사를 수행하였다. 자료의 정량적 해석을 통해, 낮은 비저항과 낮은 충전성을 갖는 지층이 상대적으로 투수성이 우수하고 지하수 산출성이 높은 충적 대수층에 해당되는 것으로 최종 해석하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표회 논문집(I)
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• pp.211-216
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• 1998

Recently the shortage of good aggregate has encouraged the use of sea sand in construction field, and the corrosion damage of the reinforced steel in concrete structures has been increased due to chlorides from sea sand and deicing salt. Therefore, a number of researchs are proceeding to prevent the corrosion of the reinforced steel in concrete, especially in marine environments. This study focused on the effect of corrosion inhibitors to evaluate protection characteristics for mortar specimens containing clorides. Corrosion behaviors have been investigated by half-cell potential measurement, linear polarization method, AC impedance method, and cyclic polarization test after immersing in sea water for 7 years. A possitive effect of a corrosion inhibitor has been obtained.

• 한국재료학회지
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• 제15권8호
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• pp.528-535
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• 2005

It is inclined to increase that use of hazardous substances such as lead(Pb), mercury (Hg), cadmium(Cd) etc. are prohibited in the electronics according to environmental friendly policies of an advanced nation for protecting environment of earth. As this reasons, many researches for ensuring the reliability were proceeding in Pb free soldering process. n the flux remains on the PCB(printed circuit board) in the soldering process or the electronics exposed to corrosive environment, it becomes the reasons of breakdown or malfunction of the electronics caused by corrosion. Therefore in this studies we researched the polarization and Tafel properties of Sn40Pb and SnCu system solders based on the electrochemical theory. The experimental polarization curves were measured in distilled ionized water and 1 mole $3.5 wt\%$ NaCl electrolyte of $40^{\circ}C$, pH 7.5. Ag/AgCl and graphite were utilized by reference and counter electrodes, respectively. To observe the electrochemical reaction, polarization test was conducted from -250mV to +250mV. From the polarization curves composed of anodic and cathodic curves, we obtained Tafel slop, reversible electrode potential(Ecorr) and exchange current density((cow). In these results, we compared the corrosion rate of SnPb and SnCu solders.

• Corrosion Science and Technology
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• 제13권1호
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• pp.15-19
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• 2014

Recently, anti-fouling paints which does not include the poison components such as tin(Sn), copper(Cu) have been increasingly developed in order to inhibit the environmental contamination of the sea water. Moreover, the wear ratios of these anti-fouling paints are very important problem to prolong their life time in economical point of view. In this study, five types of anti-fouling paints as self polishing type were investigated on the relationship between their polarization characteristics and wear ratios. It was verified that there was apparently a good relationship between the wear ratio and polarization characteristics, for example, the wear ratio increased with increasing the impedance ratio, and increased or decreased with the corrosion potential shifting in the negative or positive direction respectively. In addition, the wear ratio decreased with decreasing the corrosion current density. Consequently, it is suggested that we can qualitatively expect the wear ratio by only measuring the polarization characteristics. Therefore, before the examination of the wear ratio was actually carried out in the field, the evaluation of polarization property in the laboratory may give a available reference data for their developments.

• Journal of the Optical Society of Korea
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• 제18권5호
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• pp.598-604
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• 2014

A polarization fluorescence correlation spectroscopy system based on a confocal microscope was built to study the rotational and translational diffusion of CdSe/CdS quantum rods (Q-rods), with the same and different polarization states between the polarizer and the analyzer (i.e. the XXX and XYY states). The rotational diffusion amplitude showed the dependences on polarization of $0.75{\pm}0.05$ in the XXX state and $0.26{\pm}0.03$ in the XYY state, when the translational diffusion amplitude was 1. The diffusion coefficients of the Q-rods were found based on their translational and rotational diffusion times in the two polarization states, in solutions with viscosity ranging from 0.9 to 6.9 cP. The translational and rotational diffusion coefficients ranged from $1.5{\times}10^{-11}$ to $2.6{\times}10^{-12}m^2s^{-1}$ and from $2.9{\times}10^5$ to $5.6{\times}10^4s^{-1}$, respectively.

• Corrosion Science and Technology
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• 제20권6호
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• pp.412-425
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• 2021

Because austenitic stainless steel causes localized corrosion such as pitting and crevice corrosion in environments containing chlorine, corrosion resistance is improved by surface treatment or changes of the alloy element content. Accordingly, research using cyclic potentiodynamic polarization experiment to evaluate the properties of the passivation film of super austenitic stainless steel that improved corrosion resistance is being actively conducted. In this investigation, the electrochemical properties of austenitic stainless steel and super austenitic stainless steel were compared and analyzed through cyclic potentiodynamic polarization experiment with varying temperatures. Repassivation properties were not observed in austenitic stainless steels at all temperature conditions, but super austenitic stainless steels exhibited repassivation behaviors at all temperatures. This is expressed as α values using a relational formula comparing the localized corrosion rate and general corrosion rate. As the α values of UNS S31603 decreased with temperature, the tendency of general corrosion was expected to be higher, and the α value of UNS N08367 increased with increasing temperatures, so it is considered that the tendency of localized corrosion was dominant.

• 멤브레인
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• 제12권3호
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• pp.143-150
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• 2002

전기투석은 이온성 물질을 분리하고 농축하는데 안정하고 효과적인 공정으로 알려져 있다. 그러나 전기투석 공정은 고가의 이온교환막 때문에 실제 공정에 적용하는데 많은 제한을 받아오고 있다. 따라서 전기 투석공정의 운전 전류밀도를 가능한 높게 공급함으로써 이온교환막의 단면적당 flux를 증가시켜 주어야 한다. 그러나 실제 공정의 운전에 있어서 운전 전류밀도는 이온교환막 표면에서의 농도분극 현상으로 제한을 받게 된다. 본 총설에서는 이온교환막을 통한 이온의 이동현상을 설명하고 전류-전압 곡선을 이용한 막특성 분석을 소개하였다. 또한 한계전류밀도 전후의 전류 영역에서 농도분극 현상과 동반하는 전기대류(Electroconvection), 물 분해 현상 등에 대한 최근 연구결과를 정리하였다.

• 터널과지하공간
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• 제33권6호
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• pp.483-494
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• 2023

국내에서 널리 사용되는 전기비저항과 유도분극탐사는 지하 매질 정보를 얻는 대표적인 물성인 전기적 성질을 측정하는 방법이다. 다양한 현장에서 획득하는 탐사 자료에 대한 정밀한 해석을 위해서는 매질의 물성 정보를 정확하게 측정하는 것이 중요하다. 암석의 전기적 물성 측정은 전류 전극과 전위 전극을 동일한 전극으로 사용하는 2전극법과 전류 전극과 전위 전극을 분리하여 측정하는 4전극법으로 구분된다. 2전극법은 4전극법에 비해 시료와 전극의 접촉이 매우 용이하므로 일반적으로 많이 사용되고 있지만, 시료뿐만 아니라 전극의 임피던스가 함께 측정된다는 문제가 있다. 이 연구에서는 유도분극 특성을 갖지 않는 물시료와 유도분극 특성을 갖는 흑연과 시멘트를 혼합한 인공 시료에 대하여 2전극법과 4전극법을 사용하여 시간영역 유도분극 효과를 측정하고 그 결과를 비교하였다. 또한, 현장탐사를 모사한 수조모형 실험으로 두 전극법의 결과와 비교하여, 모형실험과 4전극법의 결과가 잘 일치하는 것을 확인하였다. 따라서, 4전극법이 전위전극의 설치에 어려움이 있지만 2전극법에 비해 전위전극의 임피던스에 의한 문제를 줄일 수 있어 전기적 물성 측정에 효과적임을 확인하였다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
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• pp.152-152
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• 2012