• 제목/요약/키워드: Polarization curves

검색결과 222건 처리시간 0.023초

전기화학기법에 의한 슈퍼 오스테나이트 스테인리스강의 열화손상 평가 (An Evaluation of Degraded Damage for Superaustenitic Stainless Steel by Electrochemical Polarization Technique)

  • 권일현;이송인;백승세;이종기;;유효선
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 추계학술대회논문집A
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    • pp.143-148
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    • 2001
  • This research was undertaken to clarify effects of thermal aging on electrochemical and mechanical properties of superaustenitic stainless steel. The steel was artificially aged at $300{\sim}650^{\circ}C$ for $240{\sim}10,000hrs$. and investigated at $-196{\sim}650^{\circ}C$ using small punch(SP) test. Also, the change in electrochemical properties caused by effects of thermal aging was investigated using electrochemical anodic polarization test in a KOH electrolyte. Carbides and ${\eta}-phase(Fe_2Mo)$ precipitated in the grain bounderies seem to deteriorate the mechanical properties by decreasing cohesive strength in the grain bounderies and promote the current density observed in electrochemical polarization curves. The electrochemical and mechanical properties of superaustenitic stainless steel was drastically decreased in the specimen aged at $650^{\circ}C$.

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보수용접봉의 종류와 용접후 열처리가 용접금속부의 내식성에 미치는 영향에 관한 전기화학적 평가 (An Electrochemical Evaluation on the Corrosion Resistance of Welding Zone due to Kinds of Repair Welding Filler Metals and Post Weld Heat Treatment)

  • 신재현;문경만
    • Corrosion Science and Technology
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    • 제9권6호
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    • pp.310-316
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    • 2010
  • Recently a fuel oil of the diesel engine of the marine ship is being changed with heavy oil of low quality as the oil price is higher more and more. Therefore the wear and corrosion in all parts of the engine such as cylinder liner, piston crown, spindle and seat ring of exhaust valves are predominantly increased. In particular the degree of wear and corrosion of piston crown is more seriously compared to the other parts of the engine due to operating in severe environment such as the high temperature of exhaust gas and repeating impact. Thus the repair weldment of the piston crown is a unique method to prolong the its life in a economical point of view. In this case, filler metals having a high corrosion and wear resistance such as stellite 6, Inconel 625 and Inconel 718 are mainly being used for repair welding. However it has been often happened that piston crown on the ship,s job site is being actually inevitably welded with mild filler metals. Therefore in this study, filler metals such as E4301, E4313 and E4316 were welded at SS401 steel as the base metal, and corrosion property of their weld metals in the case of post weld heat treatment or not was investigated with some electrochemical methods such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram and polarization resistance etc. in 0.1% $H_2SO_4$ solution. Corrosion resistance of the weld metal of E4301 was better than the other weld metals in the case of no heat treatment, however, its resistance was considerably decreased with post weld heat treatment(annealing:$625^{\circ}C$, 2 hr) compared to other weld metals. The weld metals of E4313 and E4316 showed a relatively good corrosion resistance by post weld heat treatment.

Inductively Coupled Plasma를 이용한 lead-zirconate-titanate 박막의 식각 손상 개선 (The reduction of etching damage in lead-zirconate-titanate thin films using Inductively Coupled Plasma)

  • 임규태;김경태;김동표;김창일
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 센서 박막재료 반도체 세라믹
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    • pp.178-181
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    • 2003
  • In this work, we etched PZT films with various additive gases ($O_2$ and Ar) in $Cl_2/CF_4$ plasmas, while mixing ratio was fixed at 8/2. After the etching, the plasma induced damages are characterized in terms of hysteresis curves, leakage current, retention properties, and switching polarization. When the electrical properties of PZT etched in $O_2$ or Ar added $Cl_2/CF_4$ were compared, the value of remanent polarization in $O_2$ added $Cl_2/CF_4$ plasma is higher than that in Ar. added plasma. The maximum etch rate of the PZT thin films was 145 nm/min for 30% Ar added $Cl_2/CF_4$ gas having mixing ratio of 8/2 and 110 nm/min for 10% $O_2$ added to that same gas mixture. In order to recover the ferroelectic properties of the PZT thin films after etching, we annealed the etched PZT thin films at $550^{\circ}C$ in an $O_2$ atmosphere for 10 min. From the hysteresis curves, leakage current, retention property and switching polarization, the reduction of the etching damage and the recovery via the annealing was turned out to be more effective when $O_2$ was added to $Cl_2/CF_4$ than Ar. X-ray diffraction (XRD) showed that the structural damage was lower when $O_2$ was added to $Cl_2/CF_4$. And the improvement in the ferroelectric properties of the annealed samples was consistent with the increased intensities of the (100) and the (200) PZT peaks.

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Monitoring of Gamma-ray Bright Quasars 3C279 and 1510-089 at 22, 43 and 86GHz using KVN Single Dish Telescopes

  • 백준현;이상성;변도영;양지혜;한명희;손봉원
    • 천문학회보
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    • 제37권2호
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    • pp.240.2-240.2
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    • 2012
  • AGN(Active Galactic Nucleus) consists of a supermassive black hole located at its center, an accretion disk around the black hole, and bipolar jets. Since May 2011, we have performed the MOGABA(Monitoring Of GAmma-ray Bright AGN) project for observing gamma-ray bright AGN once a week at multifrequencies using KVN(Korean VLBI Network) 21m radio telescopes. The MOGABA project is the observations for measuring the degree of polarization, polarization angle, and total flux of about 20 AGN at 22, 43 and 86GHz. By this project, we are able to investigate polarization characteristics, spectral index, and variation of rotation measure at radio wavelengths of gamma-ray bright AGN and to study possible relation between gamma-ray flares and magnetic field structure change in AGN. According to previous research, gamma-ray flares of some AGN are coincident with large changes in angle of linear polarization. In this paper we report the preliminary results of linear polarization and total flux at 22, 43, 86GHz of gamma-ray bright quasars 3C279 and 1510-089 showing noticeable variation of total flux at 22GHz in late 2011, and discuss possible correlation with gamma ray light curves.

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슈퍼 오스테나이트 스테인리스강의 열화손상에 대한 비파괴적 평가 (An Nondestructive Evaluation of Degraded Damage for Superaustenitic Stainless Steel)

  • 권일현;백승세;;유효선
    • 대한기계학회논문집A
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    • 제26권7호
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    • pp.1332-1339
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    • 2002
  • This research was undertaken to clarify effects of thermal aging on electrochemical and mechanical properties of superaustenitic stainless steel and to detect the material degradation nondestructively. The steel was artificially aged at $300{\sim}650^{\circ}C$ for $240{\sim}10,000h$ and the mechanical properties were investigated at $-196{\sim}650^{\circ}C$ using small punch(SP) test. Also, the change in electrochemical properties caused by effects of thermal aging on superaustenitic stainless steel was investigated using electrochemical anodic polarization test in a KOH electrolyte. Carbides and ${\eta}-phase(Fe_2Mo)$ precipitated in the grain boundaries seem to deteriorate the mechanical properties by decreasing cohesive strength in the grain boundaries and to promote the current density observed in electrochemical polarization curves, The electrochemical and mechanical properties of superaustenitic stainless steel decreased significantly in the specimen aged at $650^{\circ}C$ corresponding to the sensitization temperature for conventional austenitic stainless steels.

Distributions of Amplitude and Phase Around C-points: Lemon, Mon-Star, and Star

  • Yu, Renlong;Ye, Dong;Xin, Yu;Chen, Yanru;Zhao, Qi
    • Journal of the Optical Society of Korea
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    • 제20권1호
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    • pp.192-198
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    • 2016
  • The distributions of (or constraints for) amplitude and phase around C-points, including Lemon, Mon-Star and Star, are studied. A Cartesian coordinate system with origin at the C-point is established. Four curves, where the azimuthal angles of polarization ellipses are 0°, 45°, 90°, and 135° respectively, are used to determine the distributions. Discussions of these constraints illustrate why Mon-Star is rarer than Lemon or Star in experiments. The transformation relationships between these three polarization singularities (PSs) are also discussed. We construct suitable functions for amplitude and phase according to their constraints, and simulate several PSs of particular shapes. With the development of modulation techniques for amplitude and phase, it is clear that this work is helpful for generating arbitrarily shaped C-points in experiments.

Al-Cu-Li-Mg-Ag-Zr합금의 시효에 따른 전기화학적 분극 거동과 공식특성 (Pitting Characteristics and Electrochemical Polarization Behaviors in Al-Cu-Si-Mg-Ag-Zr Alloys with Ageing)

  • 민병철;정동석;손태원;조현기
    • 열처리공학회지
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    • 제9권2호
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    • pp.103-111
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    • 1996
  • In this paper, we studied on both electrochemical polarization behaviors and pitting characteristics of ultra high strength Al-Cu-Li-Mg-Ag-Zr alloys(named C1 and C2) and 2090 alloy according to their treatments in the deaerated 3.5% NaCl, using by the potentiodynamic and the potentiostatic method, SEM micrograph and surface roughness including depth of pitting attack. With the cyclic polarization curves, the hysteresis of the C1 and C2 alloys appeared more remarkably than that of the 2090 alloy, because of precipitation microstructural difference between C1, C2 alloys and 2090 alloy. In the pitting experiments, the correlations between pitting growth and aging conditions were analyzed with the SEM micrograph and measurement of the pit depth.

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편광 변조 방법에 의한 자기 Kerr 회전각 및 Faraday 회전각 측정 (Measurement of magnetic kerr rotation and faraday fotation angles by polarization modulation method)

  • 이용호;이상수;이용호
    • 한국광학회지
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    • 제3권2호
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    • pp.105-110
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    • 1992
  • 광자기 기록 박막의 자기 광학효과에 의한 미소 편광 회전각을 축정하기 위하여 편광 변조 방법을 이용하였다. 편광 변조 방법은 Faraday 회전자로 레이저광의 편광을 변조하고 phase sensitive detection방법을 써서 변조된 신호만을 선택적으로 검출하는 것이다. 본 실험에서는 진공증착법으로 제작된 TbFeCo박막과 RF 스퍼터링으로 제작된 iron garnet 다결정 박막의 자기 Kerr 회전 및 Faraday 회전 이력곡선을 이 방법으로 조사하였다. 그 결과 $0.25^{\circ}$정도의 미소한 회전각을 측정하였으며 특히 longitudinal Kerr 회전의 경우 $2.5\times10^{-3^\circ}$정도의 매우 작은 회전각도 측정할 수 있었다.

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RF 마그네트론 스퍼터링 법을 이용한 PZT 박막의 강유전 특성 (Ferroelectric Properties of PZT Thin Films by RF-Magnetron sputtering)

  • 박영;주필연;이준신;송준태
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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    • pp.341-344
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    • 1999
  • The effects of post annealing treatments of ferroelectrlclty in PZT(P $b_{1.05}$(Z $r_{0.52}$, $Ti_{0.48}$) $O_3$ thin film deposited on Pt/ $SiO_2$/Si substrate by RF-Magnetron sputtering methode was Investigated. Analyses by RTA(Rapid Thermal Annealing) treatments reveled that the crystallization process strongly depend on the healing temperature. The Perovskite structure with strong PZT (101) plan was obtained by RTA treatments at 75$0^{\circ}C$ With increasing RTA temperature of PZI thin films, the coercive field and remanent Polarization decreased, while saturation polarization( $P_{r}$) was decreased. P-E curves of Pt/PZT/Pt capacitor structures demonstrate typical hysteresiss loops. The measure values of $P_{r}$,. $E_{c}$ and dielectric constants by post annealed at 75$0^{\circ}C$ were 38 $\mu$C/$\textrm{cm}^2$ 35KV/cm and 974, respectively. Switching polarization versus fatigue characteristic showed 12% degradation up to 10$^{7}$ cycles.s.s.s.s.s.s.

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Electrical Properties of (Bi,Y)4Ti3O12 Thin Films Grown by RF Sputtering Method

  • Nam, Sung-Pill;Lee, Sung-Gap;Bae, Seon-Gi;Lee, Young-Hie
    • Journal of Electrical Engineering and Technology
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    • 제2권1호
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    • pp.98-101
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    • 2007
  • Yttrium(Y)-substituted bismuth titanate $(Bi_{4-x},Y_x)Ti_3O_{12}$ [x=0, 0.25, 0.5, 0.75, 1](BYT) thin films were deposited using an RF sputtering method on the $Pt/TiO_2/SiO_2/Si$ substrates. The structural properties and electrical properties of yttrium-substituted $(Bi_4-xYx)Ti_3O_{12}$ thin films were analyzed. The remanent polarization of $(Bi_4-xYx)Ti_3O_{12}$ films increased with increasing Y-content. The $(Bi_{3.25}Y_{0.75})Ti_3O_{12}$ films fabricated using a top Au electrode showed saturated polarization-electric field(P-E) switching curves with a remanent polarization(Pr) of $8{\mu}C/cm^2$ and coercive field (Ec) of 53 kV/cm at an applied voltage of 7 V. The $(Bi_{3.25}Y_{0.75})Ti_3O_{12}$ films exhibited fatigue-free behavior up to $4.5{\times}10^{11}$ read/write switching cycles at a frequency of 1MHz.