• 제목/요약/키워드: Polarization curves

검색결과 222건 처리시간 0.021초

용사코팅층의 분극특성 (Polarization Characteristics of Thermal Sprayed Coating Layer)

  • 안석환;김선진;김영식
    • 동력기계공학회지
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    • 제8권4호
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    • pp.38-43
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    • 2004
  • Thermal spraying onto the metal substrate has been widely used as a technique of the surface treatment in the various industrial field. A wide range of thermal spray technologies exist and all rely on the fundamental process of fusing a metal feedstock, atomizing it and transporting it to the surface of a substrate. Specially, these methods have been taken into account as the protection method against the corrosion. In this study, the polarization characteristics were carried out on the thermal sprayed coating layer immersed in various pH of diluted aqueous solutions at $25^{\circ}C$. Aluminum, Zinc, Ni-base alloy, alumina and polyethylene powder were used with sprayed coating materials. From the polarization curves, the electrochemical corrosion potential($E_{corr}$) and the corrosion current density($I_{corr}$) were investigated.

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SERKOWSKI'S EMPIRICAL RELATION FOR INTERSTELLAR LINEAR POLARIZATION VIEWED FROM DAVIS-GREENSTEIN ALIGNMENT MECHANISM

  • Hong, Seung-Soo;Lee, Hyung-Mok
    • 천문학회지
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    • 제11권1호
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    • pp.31-36
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    • 1978
  • Although Serkowski used a single value K=1.15 in representing all the observed interstellar linear polarization curves by his empirical relation $p({\lambda})/P_{max}$=exp (-K $1n^2({\lambda}_{max}/{\lambda})$), where $p_{max}$ is the maximum polarization at wavelength ${\lambda}_{max}$, we have noticed a meaningful variation in K from observations of 72 stars. By comparing K's with $P_{max}/E_{B-V}\;and\;with\;{\lambda}_{max}$, we have examined how the shape of the polarization curve is related with the degree of grain alignment on one hand, and with grain sizes on the other. We have shown that correlations between K, $P_{max}/E_{B-V}\;and\;with\;{\lambda}_{max}$, are consistent with the idea of Davis-Greenstein mechanism for grain alignment.

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생체용 Ti-Zr-Pd계 합금의 양극분극특성 (Anodic Polarization Properties of Ti-Zr-Pd Based Alloys for Biomedical Applications)

  • 정종현
    • 대한치과기공학회지
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    • 제23권1호
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    • pp.21-30
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    • 2001
  • For biomedical applications. Ti-X%Zr-Y%Pd(X: $10{\sim}20$, Y:0.2 or 0.4) based alloys not containing harmful Al and V were newly designed, and polarization curves for their alloys were measured at $37^{\circ}C$ in 5% HCl solution in order to understand effects of Zr on the corrosion. From the results of anodic polarization behavior, it was found that the corrosion resistance increased with increasing Zr content. The results show their potential to develope Ti-based alloys for biomedical materials. The Ti-20%Zr-0.2%Pd alloy shows excellent corrosion resistance and was superior to those of the Ti. Ti-6%Al-4%V ELI alloy, Co-30%Cr-6%Mo alloy and STS 316L stainless steel.

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Al-황동의 분극특성에 미치는 응력의 영향 (Effect of Stress on the Polarization Characteristic of Al-brass)

  • 임우조;정해규;심경태
    • 한국안전학회지
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    • 제19권2호
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    • pp.1-5
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    • 2004
  • Al-brass is the raw material of mnufacturing tubes for heat exchanger of vessel where seawater is used to coolant because it has high level of heat coductivity and excellent mechanical properties and high level of corrosion resistance due to cuprous oxide($Cu_2O$) layer against seawater. However, damage of Al-brass tubes for heat exchanger of vessel is reported that local corrosion such as stress corrosion cracking occurred by synergism effect between mechanical factor and corrosion environment. In this study, to investigate on the effect of stress on the polarization characteristics of Al-brass. At the stress of 0% and 95% yield strength by constant displacement tester, in 3.5% NaCl + 0.1% $NH_4OH$ solution, the polarization tests were carried out. And thus open circuit potential, corrosion current density, anodic polarization, cyclic polarization and dezincification behavior of Al-brass are investigated.

Lornoxicam & Tenoxicam Drugs as Green Corrosion Inhibitors for Carbon Steel in 1 M H2SO4 Solution

  • Fouda, A.S.;El-Defrawy, A.M.;El-Sherbeni, M.W.
    • Journal of Electrochemical Science and Technology
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    • 제4권2호
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    • pp.47-56
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    • 2013
  • Inhibition performance of Lornoxicam & Tenoxicam against corrosion of carbon steel in 1M $H_2SO_4$ solutions was investigated by weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements. The inhibition efficiency increased with increasing inhibitor's concentration, but decreased with increase in temperature. Potentiodynamic polarization curves showed that, the inhibitors were of mixed type. The apparent activation energy ($E^*_a$) and other thermodynamic parameters for the corrosion process have also been calculated and discussed. The inhibition of carbon steel corrosion is due to the adsorption of the inhibitor molecules on the surface, which follows Temkin adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the undertaken inhibitors.

운전 조건에 따른 PEM 연료전지 모델링 및 성능 분석 (Modeling and parametric studies of PEM fuel cell performance)

  • 노영우;김세훈;정귀성;손익제;한국일;안병기
    • 한국수소및신에너지학회논문집
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    • 제19권3호
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    • pp.209-216
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    • 2008
  • In the present study, a mathematical model has been formulated for the performance of polymer electrolyte fuel cells. Modify the concentration polarization equation using concentration coefficient that represents the characteristics of bipolar plate reactant distribution. The model predictions have been compared with experimental results and good agreement has been demonstrated for the cell polarization curves. The effects of operating parameters on the performance of fuel cells have been studied. Increases of operation pressure reduce the effect of temperature on the performance.

Investigation of Resonant Wavelength Separation in Microband-induced Fiber Gratings

  • Sohn Kyung-Rak;Shim Joon-Hwan;Kim Kwang-Taek
    • Journal of the Optical Society of Korea
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    • 제10권2호
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    • pp.63-66
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    • 2006
  • In microband-induced fiber gratings, polarization properties and birefringence are investigated as a function of an applied line force. With the transmission curves associated with the maximum and minimum resonant wavelengths, the polarization-dependent behaviors are analyzed. By increasing the transverse line force, the resonance wavelength for an incident light polarized to the same direction of the force is blue-shifted as much as 0.69 nm/(N/cm) while that for the other polarization is insensitive. Using the resonant wavelength separation corresponding to the force variation, the transverse effective index change or modal birefringence variation is obtained. The ratio of modal birefringence versus applied line force is ${\Delta}B/{\Delta}f_x={\sim}8.38{\times}10^{-7}$.

다양한 코팅 방법에 따른 전조한 강 볼트의 내부식성 (2) (Corrosion Resistance of the Roll Formed Steel Bolts with the Various Types of Coating Methods (2))

  • 사바르;보보무로드;손요헌;김인수
    • 소성∙가공
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    • 제28권2호
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    • pp.77-82
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    • 2019
  • Corrosion occurs well on surface of roll formed and Zn alloy subsequently electro-deposited on steel bolt under wet condition. In this study, variations in corrosion resistance were investigated through the measurement of polarization curves on steel bolts which were roll formed and subsequently coated with various types of coating methods. According to the measured polarization curve, Ni-P electroless deposits on roll formed steel increased the resistance to corrosion. The corrosion resistance of Zn alloy powder coated steel bolt was found to be better than that of Zn-Ni electro-deposited sample.

강판의 부식방지를 위한 도금층 조직관찰 (The Investigation of Microstructure of Electro-deposited Layer for the Corrosion Resistance on Sheet Steel)

  • 김인수;이세광
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1997년도 추계학술대회논문집
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    • pp.224-227
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    • 1997
  • In Ni and Zn plating, microstructure and corrosion behavior of electrodeposits with various electroplating condition were investigated. Optical microstructure, SEM images and polarization curves of electrodeposits are different with plating time and temperature.

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