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Modification of surface pretreatment of white spot lesions to improve the safety and efficacy of resin infiltration

  • Yim, Hyun-Kyung;Min, Ji-Hyun;Kwon, Ho-Keun;Kim, Baek-Il
    • The korean journal of orthodontics
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    • v.44 no.4
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    • pp.195-202
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    • 2014
  • Objective: A low-viscosity resin (infiltrant) was used to inhibit the progression of white spot lesions (WSLs) and resolve associated esthetic issues. An alternative pretreatment was explored to increase the pore volume of the surface layer of the WSLs. Also, the penetration effects of the infiltrant were evaluated for various pretreatments. Methods: Sixty two artificial lesions were fabricated on bovine teeth. As a positive control, 15% HCl gel was applied for 120 seconds. Further, 37% $H_3PO_4$ gel was applied for 30 seconds using three methods. The samples were divided as follows: $H_3PO_4$ only group, $H_3PO_4$ sponge group, and $H_3PO_4$ brush group. The acid was gently rubbed with the applicators (i.e., a sponge or brush) throughout the application time. To compare the effects of resin infiltration, twenty paired halves of specimens were treated with an infiltrant (ICON$^{(R)}$). Results: Thicknesses of the removed surface layers and infiltrated areas were evaluated by confocal laser scanning microscope. The positive control and the 37% $H_3PO_4$ brush group failed to show significant differences in the removed thickness (p > 0.05); however, the mean percentage of the infiltrated area was higher in the 37% $H_3PO_4$ brush group ($84.13{\pm}7.58%$%) than the positive control ($63.51{\pm}7.62%$, p < 0.001). Scanning electron microscope observations indicate higher pore volumes for the 37% $H_3PO_4$ brush group than for the positive control. Conclusions: Application of 37% $H_3PO_4$ with a brush for 30 seconds increased the pore volume of WSL surface layers and the percentage of infiltrated areas in comparison to the use of 15% HCl for 120 seconds.

Facile Synthesis of In2S3 Modified Ag3PO4 Nanocomposites with Improved Photoelectrochemical Properties and Stabilities

  • Zeng, Yi-Kai;Bo, Shenyu;Wang, Jun-hui;Cui, Bin;Gu, Hao;Zhu, Lei;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.11
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    • pp.601-608
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    • 2020
  • In this work, Ag3PO4/In2S3 nanocomposites with low loading of In2S3 (5-15 wt %) are fabricated by two step chemical precipitation approach. The microstructure, composition and improved photoelectrochemical properties of the as-prepared composites are studied by X-ray diffraction pattern (XRD), field emission scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), photocurrent density, EIS and amperometric i-t curve analysis. It is found that most of In2S3 nanoparticles are deposited on the surfaces of Ag3PO4. The as-prepared Ag3PO4/In2S3 composite (10 wt%) is selected and investigated by SEM and TEM, which exhibits special morphology consisting of lager size substrate (Ag3PO4), particles and some nanosheets (In2S3). The introduction of In2S3 is effective at improving the charge separation and transfer efficiency of Ag3PO4/In2S3, resulting in an enhancement of photoelectric behavior. The origin of the enhanced photoelectrochemical activity of the In2S3-modified Ag3PO4 may be due to the improved charge separation, photocurrent stability and oriented electrons transport pathways in environment and energy applications.

Laser Damage Threshold Increase of A/R Coating Films for 200MHz AOM (A/R 코팅 변화에 따른 200MHz AOM의 laser damage threshold 증가)

  • Kim, Yong-Hun;Lee, Hang-Hun;Lee, Jin-Ho;Park, Yeong-Jun;Park, Jeong-Ho
    • Korean Journal of Materials Research
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    • v.7 no.3
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    • pp.213-217
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    • 1997
  • AOhf(Hcousto-r)l)tic niodulator) with :!OOlIiz freclucncl- and Sfi(;(Seconrl harmonic generation) green lasel-Lvith 53% nm wavelength were used for Il\'IIII~Dii.it,ii v~ilco disk recorder) FOI rhe appli~aptin of high densit]. optical recording, a high po\ver I ~ c r is r c ~ ~ l i ~ i l - u l ic I !tic. s\-sti,m a n d optic.,~I io;iting l,t)c>rs of each optical device must have a high laser damage threshoid hie rn;itie ant] retlwtive coatings on a $TeO_{2}$ singlc crystal. which is used as an acoustooptic material, by E-beam evaporation method. Laser damage threshold \vas nicdsureci hy Ar laser with the input power oi 0.55LV 1,aser damage threiholti 01 $ZrO_{2}$ and $SiO_{2}$. filn-is were higher than $AI_{2}O_{3}$ f i l m U'e also investigated a long--tern1 stability of the output po\ver of St{(; green laser

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Production and Structural Analysis of Cellulose by Acetobacter sp. V6 Using Static Culture (정치배양을 이용하여 Acetobacter sp. V6의 셀룰로오스 생산 최적화 및 구조 분석)

  • Kim, Jeong-Do;Jung, Ho-Il;Jeong, Jin-Ha;Park, Ki-Hyun;Jeon, Young-Dong;Hwang, Dae-Youn;Lee, Chung-Yeol;Son, Hong-Joo
    • Korean Journal of Microbiology
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    • v.45 no.3
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    • pp.275-280
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    • 2009
  • The optimal medium compositions for the production of bacterial cellulose (BC) by a Acetobacter sp. V6, which was isolated from the traditionally fermented vinegar in Korea, were investigated in static cultures. The optimum medium compositions for BC production were 3% glucose, 3% soytone, 0.8% $K_2HPO_4$, and 0.4% ethanol, respectively. Adding $NaH_2PO_4$ or $KH_2PO_4$ had not shown the increase in BC production. Under the optimum medium compositions, the highest BC production was 44.67 g/$m^2$ in 8 days and the thickness of BC pellicle was about 1 cm. Structural properties of BC produced in the optimal medium were studied using Fourier-transform infrared spectroscopy and X-ray diffractometer. BC from the optimal medium was found to be of cellulose type I, the same as typical native cellulose. No difference in the compositions between bacterial and plant celluloses, but BC showed unique micro-network structure and high crystallinity (82%).

Origin and Spatial Distribution of Organic Matter at Gwangyang Bay in the Fall (추계 광양만의 유기물 기원과 분포 특성)

  • Lee, Young-Sik;Kang, Chang-Keun;Choi, Yong-Kyu;Lee, Sang-Yong
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.12 no.1
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    • pp.1-8
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    • 2007
  • Environment factors related to the distribution of organic matter in surface seawater and sediments were investigated to estimate main pollution sources and range of their influence in Gwangyang Bay. The main pollution sources for the factors that affect organic matter distribution could be divided into three main sources: fresh water runoffs from Seomjin and Dong River, Gwangyang-si domestic sewage, and Yosu Industrial Complex. Considering the characteristics in horizontal distributions of the environmental factors in water column, sediment, and water current regime, the influencing range of these main sources was likely to be divided into three areas within the bay as follows: Area I receiving lots of fresh water from Seomjin River, Area II receiving lots of domestic sewage from Gwangyang-si and fresh water of Dong River, Area III receiving lots of materials from Yosu Industrial Complex. Area I seems to be characterized as low salinity, high concentration of $NO_3-N,\;and\;SiO_2-Si$, Area II as low salinity, high concentration of $NO_3-N,\;NH_4-N,\;and\;SiO_2-Si$, and Area III as high water temperature, high concentration of $NH_4-N,\;and\;PO_4-P$ in water column, high concentration of $NH_4-N,\;PO_4-P,\;and\;SiO_2-Si$ in surface sediments.

Conjectual Study on Korean Costume in the Prehistoric Period (선사시대(先史時代)에 있었을 우리 민족복식(民族服飾)을 생각하며)

  • You, Hi-Kyung
    • Journal of the Korean Society of Costume
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    • v.5
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    • pp.7-11
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    • 1981
  • In the vast extent of time, man and his ancestors have existed on earth about 2,000,000 years. For Near-Man, they knew how to make fire and protected themselves with hairs. Old-Man covered their bodies with the skins of wild animals. New Man improved the quality, the range and ingenuity, so they fabricated clothes with the animal skins. New Man is considered as ancestor of Modern Man. They had spread widely over the earth to take advantage of their surroundings. The next period, New Stone Age was chiefly distinguished by agricultural age. He was now about to make clothes from natural fibers. The two most obvious orgins of clothing are to protect the body against environment and to decorate the body. The forms of clothing were different from the various climates and regions they had settled, for example Yo-po Hyung (Apron), Kwae-po Hung (Sewn garment), Kwan-doo Hyung (Poncho), Chun-kae Hyung (Frontopend garment), Chai-hyung Hyung (Body-conforming shape). Our ancestor had moved from Baikal Lake, Central Asia toward northeast; Shun-tung in China, Manchuria and at last Han Panninsula. Considering our basic costume of ancient times were Yu(jacket), Ko(trousers), Sang(skirt), Po (coat) with the accessories of Kwan (crown), Mo (hat), Dai (belt), Hwa, Eie (footwear), here I conjecture our costume of prehistoric period was Chaihyung Hyung(Body-conforming shape) in the purpose of body covering.

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Seismic Performance Evaluation of Non-seismic T-bar type Steel-Panel Suspended Ceiling using Shaking Table Test (비내진 상세를 갖는 금속마감패널 천장시스템의 진동대 실험을 통한 내진성능평가)

  • Lee, Jae-Sub;In, Sung-Woo;Jung, Dam-I;Lee, Doo-Yong;Lee, Sang-Hyen;Cho, Bong-Ho
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.10
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    • pp.171-180
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    • 2019
  • In Korea, the seismic design of non-structural elements was interested by Earthquake of the 2016 Gyeong-ju and 2017 Po-hang. Among the non-structural elements, the ceiling system with steel panel used in Po-hang station showed failure examples of non-seismic design ceiling. In this study, the seismic performance of suspended ceiling with steel-panel, such as those used in Po-hang Station, was evaluated by shaking table tests. The shaking table tests were performed in accordance with the ICC-ES AC156 standard with floor acceleration being applied horizontally in one direction using a $3.3{\times}3.3m^2$ frame. The ceiling system consists of steel-panels, carrying channels, main and cross T-bars, and anti-falling clips. The anti-falling clip prevents the steel panel falling completely. The shaking table test confirmed that the damage at the previous stage had a direct impact on the damage state at the next stage. Through the shaking table test, the damage state of the T-bar type steel-panel suspended ceiling system was defined.

Asymmetric Cyanosilylation of Aldehydes by Chiral Ti-TADDOL Complex

  • Kim, Sung-Soo;Kwak, Ju-Myung;Rajagopal, Gurusamy
    • Bulletin of the Korean Chemical Society
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    • v.27 no.10
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    • pp.1638-1640
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    • 2006
  • A variety of chiral cyanohydrins were readily prepared from aldehydes with TMSCN under the influence of chiral titanium complex formed in situ from $Ti(O^iPr)_4$/TADDOL(I) in the presence of $Ph_3PO$ as additive. The double activation method produces trimethylsilylethers in excellent yield (95%) with moderate enantiomeric excess.

The Inhibition of C-steel Corrosion in H3PO4 Solution by Some Furfural Hydrazone Derivatives

  • Fouda, A.S.;Badr, G.E.;El-Haddad, M.N.
    • Journal of the Korean Chemical Society
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    • v.52 no.2
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    • pp.124-132
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    • 2008
  • effect of some furfural hydrazone derivatives (I -V) as corrosion inhibitors for C-steel in 3M H3PO4 solution in which M indicates mol/l has been studied using weight-loss and galvanostatic polarization techniques. A significant decrease in the corrosion rate of C-steel was observed in the presence of the investigated compounds. This study revealed that, the inhibition efficiency increases with increasing the inhibitor concentration, and the addition of iodide and thiocynate ions enhances it to a considerable extent. The effect of temperature on the corrosion behavior of C-steel was studied in the range from 30-60oC with and without 510-6 M investigated compounds using weight-loss method. Apparent activation corrosion energy (Ea*) and other thermodynamic parameters for the corrosion process were calculated and discussed. The polarization measurements show that the investigated compounds act as mixed-type inhibitors, but the cathode is more polarized when an external current was applied. The adsorption of these compounds on the surface of C-steel in 3M H3PO4 obeys Frumkins adsorption isotherm. The mechanism of inhibition was discussed in the light of the chemical structure of the investigated compounds.

Characterization of Chl a Fluorescence of Hydrophytes under Cadmium Stress (카드뮴 스트레스에 대한 수생식물 5종의 엽록소형광 반응)

  • Oh, Soon-Ja;Zhin, Kook-Lhim;Koh, Seok-Chan
    • Journal of Environmental Science International
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    • v.18 no.12
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    • pp.1361-1368
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    • 2009
  • The effects of $Cd^{2+}$ ions on the Chl a fluorescence of 5 hydrophytes (e.g. Lemna, Salvinia, Ricciocarp, Nymph, Typha plants) were investigated in order to select $Cd^{2+}$-sensitive plant species and to get informations on physiological responses of plants to $Cd^{2+}$ stress. Lemna plants were most sensitive to cadmium stress, while Nymph plants were tolerant. However, in all $Cd^{2+}$-treated plants, Fv/Fm, the maximum photochemical efficiency of PS II, decreased in proportion to the increase of $Cd^{2+}$ concentration and treatment time. The Chl a fluorescence transient O-J-I-P was also considerably affected by $Cd^{2+}$ ions; the fluorescence yield decreased consid- erably in steps J, I and P in $Cd^{2+}$ treated plants, although it followed a typical polyphasic rise in non-treated plants. In Lemna plants, the functional parameters, ABS/CS, TRo/CS와 ETo/CS and RC/CS, decreased in proportion to the increase of $Cd^{2+}$ concentration, while N, Mo and Kn increased. The structural parameters, ${\Phi}po$, ${\Phi}po$/($1-{\Phi}po$), Plabs, SFlabs, Kp and RC/ABS, also decreased according to the increase of $Cd^{2+}$ concentration. Consequently, Lemna plants will be useful as a experimental model system to investigate responses of plants. And several functional or structural parameters could be applied to determine quantitatively the physiological states of plants under stresses.