• 제목/요약/키워드: Plant derived carbon

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다양한 바이오매스 기반의 탄소 제조 및 리튬이온전지 음극활물질로의 응용 (Synthesis of Various Biomass-derived Carbons and Their Applications as Anode Materials for Lithium Ion Batteries)

  • 김찬교;제갈석;김하영;김지원;추연룡;심형섭;윤창민
    • 유기물자원화
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    • 제31권3호
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    • pp.27-34
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    • 2023
  • 본 연구에서는 여러 종류의 식물성 바이오매스 폐기물을 리튬이온전지용 음극활물질로 재활용하고자 하였다. 수거한 바이오매스는 세척 및 분쇄 후 질소 환경(850℃)으로 탄화하였으며, 이를 FE-SEM, EDS, FT-IR을 사용하여 물리·화학적 특성을 비교하였다. 바이오매스 기반의 탄소 전구체로 왕겨, 밤껍질, 녹차 티백, 커피 폐기물을 사용했으며, 전구체의 성분에 따라 형태 및 탄소화 정도의 차이가 발생함을 확인하였다. 바이오매스 폐기물로 제조된 탄소를 음극재로 활용하여 전기화학 성능을 비교한 결과 각각 65.8, 80.2, 90.6, 104.7mAh g-1의 방전용량을 나타내었으며, 커피 폐기물을 전구체로 제조한 탄소가 가장 높은 방전용량을 나타내었다. 이는 바이오매스의 원소 조성 및 구성성분 차이로 인해 탄화 정도가 달라지기 때문이다. 최종적으로, 환경오염을 유발하는 다양한 식물성 바이오매스를 탄화를 통해 효과적인 에너지 저장매체로 활용할 수 있는 가능성을 제시하였다.

Chemical Compositions of Primary PM2.5 Derived from Biomass Burning Emissions

  • Ichikawa, Yujiro;Naito, Suekazu
    • Asian Journal of Atmospheric Environment
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    • 제11권2호
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    • pp.79-95
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    • 2017
  • A number of field studies have provided evidence that biomass burning is one of the major global sources of atmospheric particles. In this study, we have collected $PM_{2.5}$ emitted from biomass burning combusted at open burning and laboratory chamber situations. The open burning experiment was conducted with the cooperation of 9 farmers in Chiba Prefecture, Japan, while the chamber experiment was designed to evaluate the characteristics of chemical components among 14 different plant species. The analyzed categories were $PM_{2.5}$ mass concentration, organic carbon (OC), elemental carbon (EC), ionic components ($Na^+$, ${NH_4}^+$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Cl^-$, ${NO_3}^-$ and ${SO_4}^{2-}$), water-soluble organic carbon (WSOC), water-insoluble inorganic carbon (WIOC), char-EC and soot-EC. OC was the dominant chemical component, accounting for the major fraction of primary $PM_{2.5}$ derived from biomass burning, followed by EC. Ionic components contributed a small portion of $PM_{2.5}$, as well as that of $K^+$. In some cases, $K^+$ is used as biomass burning tracer; however, the observations obtained in this study suggest that $K^+$ may not always be suitable as a tracer for biomass burning emissions. Also, the results of all the samples tested indicate relatively low values of char-EC compared to soot-EC. From our results, careful consideration should be given to the usage of $K^+$ and char-EC as indicators of biomass burning. The calculated ratios of WSOC/OC and WIOC/OC were 55.7% and 44.3% on average for all samples, which showed no large difference between them. The organic materials to OC ratio, which is often used for chemical mass closure model, was roughly estimated by two independent methods, resulting in a factor of 1.7 for biomass burning emissions.

벼의 소포자 배양을 통한 식물체 재분화 (Plant Regeneration from Rice Microspore Cultures)

  • 김영수
    • Journal of Plant Biology
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    • 제36권2호
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    • pp.183-192
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    • 1993
  • Efficient plant regeneration system was established through the culture of rice (Oryza sativa L.) microspores. Microspores released by anther shedding culture developed into proembryos and calluses in B5 medium within two weeks of culture. The optimal hormone and carbon sources were dependent on the genotypes used. Microspore's viability decreased rapidly in culture time, therefore less than 3% of the total microspores were viable at the 9th day when the first microspore division was observed. Of two types of microspores (pollen dimorphism) observed in culture, only the P-grain, larger microspores than normal one was able to divide. Using 4',6-diamidino-2-phenylindole (DAPI) fluorescence staining, it was confirmed that the symmetrical division of uninucleate microspore was the first step leading to continuous microspore development. Microspore-derived proembryos and calluses were regenerated to plants in N6 medium containing 1 mg/L NAA and 5 mg/L kinetin, and 78.3% of the regenerated plants were haploids.

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바이오에너지 원료작물 생산 및 연구동향 (Bioenergy Crop Production and Research Trends)

  • 김광수;김용범;장영석;방진기
    • Journal of Plant Biotechnology
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    • 제34권2호
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    • pp.103-109
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    • 2007
  • The increasing industrialization of the world has led to precipitous rise for the demand of petroleum-based fuels. The world is presently confronted with the twin crises of fossil fuel depletion and environmental pollution. The search for alternative fuels, which promise a harmonious correlation with sustainable development, energy conservation, efficiency and environmental preservation, has become highly pronounced in the present. Bioenergy is playing an increasingly important role as an alternative and renewable source of energy. Use of Bioenergy has several potential environmental advantages. The most important perhaps is reduction in life cycle greenhouse gases emissions relatives petroleum fuels, since bioenergy is derived from plants which convert Carbon dioxide ($CO_{2}$) into Carbohydrates in their growth. Bioenergy includes solid biomass, biomas and liquid bio-fuels which are fuels derived from crop plants, and include biomass that's directly burned. The two most important bio liquid fuels today are bioethanol from fermenting grain, grass, straw or wood, and biodiesel from plant seed oil.

인산감수성(燐酸感受性)이 다른 대두품종간(大豆品種間) 유기산(有機酸) 및 당(糖)에 대(對)한 질소원(窒素源)의 영향(影響) (Effects of Nitrogen Sources on Sugars and Organic Acids of Soybean Cultivars Different in Phosphorus Sensitivity)

  • 박훈;찰스 에이 스뚜디
    • 한국토양비료학회지
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    • 제10권2호
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    • pp.85-92
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    • 1977
  • 인산감수성(燐酸感受性)이 다른 9개대두재배종(個大豆栽培種) Lee, Hill, Harosoy, Clark-63, Chippewa 및 R56-49을 서로 다른 질소원(窒素源)으로 수경재배(水耕栽培)하여 엽중유리당(葉中遊離糖)과 유기산(有機酸)을 gas chronatograph로 조사(調査)하여 미동정(未同定)의 X, Y peak와 Sucrose peak가 주(主) peak로 나타났다. X 화합물(化合物)은 NO3-N 급여(給與)경우 흔적으로 나타난데 반하여 NH4-N나 urea 급여(給與)경우에 다량(多量)나타났다. Y 화합물(化合物)을 Urea 급여(給與)경우 감소하는 경향이었다. Sucrose는 NH4-N 급여(給與)에서 흔적으로 나타나고 Urea에서 NO3-N에서보다 높았다. X 화합물(化合物)은 erythrose에서 유래(由來)한 4 탄소(炭素) 산성당(酸性糖)이거나 Purine이나 Pyrimidine에서 유래(由來)한 환상화합물(環狀化合物)로 Y 화합물(化合物)은 glycolysis path에서 유래(由來)한 6 탄당(炭糖)으로 추정(推定)되었다. Y/X 치(値)는 인산감수성(燐酸感受性)의 좋은 지표(指標)가 되므로(역관계(逆關係)) 이 두 화합물(化合物)은 ammonia 독작용(毒作用) 및 인산감수성(燐酸感受性) 기작(機作)에 관여(關與)하는 요인화합물(要因化合物)로 보였다.

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에너지사용시설의 온실가스 배출 특성 연구 -유연탄 화력발전소의 이산화탄소를 중심으로- (Development of Emission Factors for Greenhouse Gas (CO2) from Bituminous coal Fired Power Plants)

  • 전의찬;사재환;이성호;정재학;김기현;배위섭
    • 한국대기환경학회지
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    • 제22권1호
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    • pp.107-116
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    • 2006
  • The main purpose of this study is to develop the greenhouse gas emission factor for power plant using bituminous coal. The power plant is a major source of greenhouse gases among the sectors of fossil fuel combustion, thus information of its emission factors is very essential to the establishment of control strategies for the greenhouse gas emissions. These emission factors derived in this study were compared with those of U. S. EPA, AGO and CCL. The $CO_{2}$ concentrations in the flue gas were measured using NDIR analyser and the GC-FID with a methanizer. The amount of carbon (C) and hydrogen (H) in fuel was measured using an elemental analyzer. Calorific values of fuel were also measured using a calorimeter. Caloric value of bituminous coal used in the power plants were 5,957 (as received basis), 6,591 (air-dried basis) and 6,960 kcal/kg (dry basis). Our estimates of carbon emission factors were lower than those of IPCC. The CO2 emission factors for the power plants using bituminous coal were estimated to be 0.791 Mg/MWh (by carbon contents and caloric value of the fuel) and 0.771 Mg/MWh (by $CO_{2}$ concentration of the flue gas). The $CO_{2}$ emission factors estimated in this study were $3.4\sim 5.4\%$ and $4.4\sim 6.7\%$ lower than those of CCL (2003) and U. S. EPA (2002).

Establishment of Cell Suspension Cultures and Plant Regeneration in White Dandelion (Taraxacum coreanum NAKAI.)

  • Sun, Yan-Lin;Kim, Jae-Hak;Hong, Soon-Kwan
    • 한국자원식물학회지
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    • 제24권3호
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    • pp.280-285
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    • 2011
  • In this study, we established a novel somatic embryogenesis and plant regeneration system through cell suspension culture of white dandelion (Taraxacum coreanum NAKAI.). Embryogenic calli could be initiated from leaf and root explants of sterile seedlings on solid Murashige and Skoog (MS) medium supplemented with 1.0 mg/L 2,4-dichlorophenoxyacetic acid (2,4-D) after 3-week cultures. To proliferate embryogenic calli rapidly, cell suspension culture was performed with transferred to liquid MS medium with various combinations of plant growth regulators (PGRs) including 2,4-D, ${\alpha}$-naphthalene acetic acid (NAA), indole-3-acetic acid (IAA), $N^6$-benzylamino purine (BAP), thidiazuron (TDZ), and kinetin. During suspension cultures, embryogenic calli not only greatly proliferated, but shoot organogenesis also simultaneously occurred from the surface of somatic embryos. Among them, TDZ at lower concentration, 0.1 mg/L produced the highest efficiency of somatic embryo formation and shoot organogenesis. Rooting of embryogenic calli with adventitious shoots was done on solid MS medium containing 0.1 mg/L NAA and 0.3% activated carbon. Nearly 80% of embryogenic calli with shoot organogenesis could be rooted normal. Well-rooted plantlets were transferred into pots under a greenhouse condition, and plants derived from this system appeared phenotypically normal.

Formation of Assimilable Organic Carbon from Algogenic Organic Matter

  • Kim, Ji-Hoon;Chung, Soon-Hyung;Lee, Jing-Yeon;Kim, In-Hwan;Lee, Tae-Ho;Kim, Young-Ju
    • Environmental Engineering Research
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    • 제15권1호
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    • pp.9-14
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    • 2010
  • The objective of this study was to assess the variation in the concentration of assimilable organic carbon (AOC) in a drinking water resource, and investigate the characteristics of AOC derived from algae. The seasonal change in AOC at the Kamafusa dam corresponded to changes in the algal cell number. In order to understand the relationship between AOC and algae in a water resource and water purification plant, two kinds of laboratory experiment were performed. The algal culture experiment showed that extracellular organic matter (EOM) that was released during the growth of Phormidium tenue with M-11 medium led to significant increases in the AOC concentration, but no significant variation in the AOC concentration was observed with CT medium containing a high dissolved organic carbon concentration. The chlorination experiment showed that the AOC included in EOM was not easily removed by chlorination, although the AOC included in intercellular organic matter released from the algal cells by chlorination was removed under conditions where residual chlorine was detected.

한·미 그린 뉴딜 사업의 추진체계와 사업특성에 관한 연구 -국내 스마트 그린도시와 미국의 주 및 부족 지원 보조금의 비교를 중심으로- (Implementation System and Project Characteristics of Green New Deal Projects in Korea and the U.S.A. -A Comparison between the Smart Green City in Korea and State and Tribal Assistance Grants in the U.S.A.-)

  • 윤지희;염성진
    • 한국환경과학회지
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    • 제31권7호
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    • pp.593-607
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    • 2022
  • Climate change has recently become a serious global issue, and carbon emissions and energy consumption are increasing, particularly in cities where economic activities and populations are concentrated. Accordingly, various countries worldwide are promoting the Green New Deal and promoting urban-centered climate change response policies with the aim of carbon neutrality. In Korea, following the "smart green city" project that creates a city where humans and the environment coexist, a similar "carbon neutral green city" policy is set to be introduced. Therefore, in this study, implications and directions for the sustainable introduction of the carbon neutral green city policy will be derived by comparing and analyzing the State and Tribal Assistance Grants of the U.S. bipartisan infrastructure law and the smart green city of the Korean new deal.

자유 말단형 침지식 분리막을 이용한 정수장 배출수 처리 연구 - 막오염 발생 원인과 해결 방안 - (A study on the treatment of water discharge from the water treatment plant using end-free submerged membrane - Causes and solution of membrane fouling -)

  • 김준현;장정우;김진호;박광덕
    • 상하수도학회지
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    • 제34권2호
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    • pp.93-104
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    • 2020
  • As water resources are limited and legal regulations are strengthened, there is a growing need to reuse residuals in WTP(Water Treatment Plant). In this study, membrane filtration system was constructed and its operation method was studied for water quality stabilization and reuse of WTP residuals. The operation parameters were stable for 1 year and 6 months. Membrane fouling was identified as particulate pollution (activated carbon) and inorganic pollution (manganese). The membrane system was operated steadily with raw water of high concentration SS(Suspended solid) containing activated carbon because membrane fouling was reduced by the effect of End-Free type. In the case of inorganic contamination, dissolved manganese eluted by chemicals and acted as a membrane fouling source, and the operating conditions for minimizing membrane fouling. were confirmed by newly developing application methods and types of cleaning chemicals. Based on the results, design parameters for reducing manganese membrane fouling were derived.