• 한국재료학회지
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• 제25권6호
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• pp.274-278
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• 2015

The possibility of using the chemical precipitation method of up-cycled ammonium paratungstate (APT) was studied and compared with the thermal decomposition method. $WO_3$ particles were synthesized by chemical precipitation method using a 1:2 weight ratio of APT: Di-water. For thermal decomposition, APT powder was heated for 4h at $600^{\circ}C$ in air atmosphere. The reaction products were characterized by X-ray diffraction (XRD), X-ray fluorescence spectrometer (XRF), particle size analyzer (PSA), and field emission-scanning electron microscopy (FE-SEM). Thermogravimetric analysis (TGA) of the up-cycled APT allowed for the identification of the sequence of decomposition and reduction reactions that occurred during the heat treatment. TGA data indicated a total weight loss of 10.78% with the reactions completed in $658^{\circ}C$. The XRD results showed that APT completely decomposed to $WO_3$ by thermal decomposition and chemical precipitation. The particle size of the synthesized $WO_3$ powders by thermal decomposition with 2 h of planetary milling was around $2{\mu}m$ During the chemical precipitation process, the particle size of the synthesized $WO_3$ powders showed a round-shape with ${\sim}0.6{\mu}m$ size.

• 한국재료학회지
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• 제23권2호
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• pp.98-103
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• 2013

$Mg_{3-x}Zn_xSb_2$ powders with x = 0-1.2 were fabricated by mechanical alloying in a planetary ball mill with a speed of 350 rpm for 24 hrs and then hot pressed under a pressure of 70 MPa at 773 K for 2 hrs. It was found that there were systematic shifts in the X-ray diffraction peaks of $Mg_3Sb_2$ (x = 0) toward a higher angle with increasing Zn for both the powder and the bulk sample and finally the phase of $Mg_{1.86}Zn_{1.14}Sb_2$ was formed at the Zn content of x = 1.2. The $Mg_{3-x}Zn_xSb_2$ compounds had nano-sized grains of 21-30 nm for the powder and 28-66 nm for the hot pressed specimens. The electrical conductivity of hot pressed $Mg_{3-x}Zn_xSb_2$ increased with increasing Zn content and temperature from 33 $Sm^{-1}$ for x = 0 to 13,026 $Sm^{-1}$ for x = 1.2 at 323 K. The samples for all the compositions from x = 0 to x = 1.2 had positive Seebeck coefficients, which decreased with increasing Zn content and temperature, which resulted from the increased charge carrier concentration. Most of the samples had relatively low thermal conductivities comparable to the high performance thermoelectric materials. The dimensionless figure of merit of $Mg_{3-x}Zn_xSb_2$ was directly proportional to the Zn content except for the compound with Zn = 1.2 at high temperature. The $Mg_{3-x}Zn_xSb_2$ compound with Zn = 0.8 had the largest value of ZT, 0.33 at 723 K.

• 대기
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• 제29권5호
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• pp.525-535
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• 2019

Vertical distributions of aerosol mass concentrations over Seoul and Gangneung from January to February 2015 were investigated using aerosol Mie-scattering lidars. Vertical mass concentration of aerosol was calculated from the lidar data using KALION's algorithm and quantitatively compared with ground PM₁₀ concentration to obtain objectivity of data. The backward trajectories calculated using HYSPLIT (version 4) were clustered into 5 traces for Seoul and 6 traces for Gangneung, and the observed aerosol vertical mass distribution was analyzed for individual trajectories. Result from the analysis shows that, aerosol concentrations with in the planetary boundary layer were highest when airflows into the measurement points originated in the Shandong Peninsula or the Inner Mongolia. In addition, the difference of aerosol mass concentrations in the two regions below 1 km was about twice as large as that in the long range transport from the Shandong Peninsula compared to the local emission. This result shows that the air quality over Korea related to particulate matters are affected more by aerosol emissions in the upstream source regions and the associated transboundary transports than local emissions. This study also suggests that the use of local aerosol observations is critical for accurate simulations of aerosol-cloud interactions.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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• pp.1205-1206
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• 2006

Dispersion-strengthened copper with $TiB_2$ was produced by ball-milling and spark plasma sintering (SPS).Ball-milling was performed at a rotation speed of 300rpm for 30 and 60min in Ar atmosphere by using a planetary ball mill (AGO-2). Spark-plasma sintering was carried out at $650^{\circ}C$ for 5min under vacuum after mechanical alloying. The hardness of the specimens sintered using powder ball milled for 60min at 300rpm increased from 16.0 to 61.8 HRB than that of specimen using powder mixed with a turbular mixer, while the electrical conductivity varied from 93.40% to 83.34%IACS. In the case of milled powder, hardness increased as milling time increased, while the electrical conductivity decreased. On the other hand, hardness decreased with increasing sintering temperature, but the electrical conductiviey increased slightly

• 한국분말재료학회지
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• 제20권3호
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• pp.215-220
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• 2013

In the present work, 6061 Al-$B_4C$ sintered composites containing different $B_4C$ contents were fabricated and their characteristic were investigated as a function of sintering temperature. For this, composite powders and their compacts with $B_4C$ various contents from 0 to 40 wt.% were fabricated using a planetary ball milling equipment and cold isostatic pressing, respectively, and then they were sintered in the temperature ranges of 580 to $660^{\circ}C$. Above sintering temperature of $640^{\circ}C$, real density was decreased due to the occurrence of sweat phenomena. In addition, it was realized that sinterability of 6061Al-$B_4C$ composite material was lowered with increasing $B_4C$ content, resulting in the decrease in its real density and at the same time in the increment of porosity.

• 한국우주과학회:학술대회논문집(한국우주과학회보)
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• 한국우주과학회 2009년도 한국우주과학회보 제18권2호
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• pp.48.1-48.1
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• 2009

In recent years, many candidates for extra-solar planet have been discovered from various measurement techniques. Fueled by such discoveries, new space missions for direct detection of earth-like planets have been proposed and actively studied. TPF instrument is a fair example of such scientific endeavors. One of the many technical problems that space missions such as TPF would need to solve is deconvolution of the collapsed (i.e. spatially and temporally) spectral signal arriving at the detector surface and the deconvolution computation may fall into a local minimum solution, instead of the global minimum solution, in the optimization process, yielding mis-interpretation of the spectral signal from the potential earth-like planets. To this extend, observational and theoretical understanding on the spectral bio-signal from the Earth serves as the key reference datum for the accurate interpretation of the planetary bio-signatures from other star systems. In this study, we present ray tracing computational model for the on-going simulation study on the Earth bio-signatures. A multi-layered atmospheric model and sea ice variation model were added to the existing target Earth model and a hypothetical space instrument (called AmonRa) observed the spectral bio-signals of the model Earth from the L1 halo orbit. The resulting spectrums of the Earth show well known "red-edge" spectrums as well as key molecular absorption lines important to harbor life forms. The model details, computational process and the resulting bio-signatures are presented together with implications to the future study direction.

• 드라이브 ㆍ 컨트롤
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• 제11권4호
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• pp.15-24
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• 2014

It is difficult to analytically derive a volumetric displacement formula for a gerotor hydraulic motor due to the complexity of the geometric shape of its gear lobes. This work proposes an analytical method for the volumetric displacement, a relatively easy method based upon two physical concepts: conservation between hydraulic energy and mechanical shaft energy, and torque equilibrium for the rotor's motion. The first research using these concepts was conducted on inner and outer rotors rotating with respect to each rotor axis. This work represents the second report conducted on an inner rotor revolving as a planetary motion on the stationary outer rotor. The formula equations regarding the volumetric displacement and flow rate are derived, and the proposed formula about the volumetric displacement is proven to be the same as another analytical displacement formula: the so-called vane length method. From the formula, volumetric displacement is calculated for an example geometry of the gear lobes. The resultant displacement is confirmed to be the same as the value calculated from the chamber volume method. The proposed analytical formula can be utilized in the analysis and design of gerotor hydraulic motors. Because it is based on torque equilibrium, this formula can provide a better understanding of torque performance, such as torque ripple, in designing a gerotor type motor.

• 한국결정성장학회지
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• 제9권5호
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• pp.516-520
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• 1999

유형성 볼밀을 사용하여 순수한 철분말 암모니아가스 분위기 중에서 기계적 합금화(MA) 처리를 하였다. 그 결과 질소함량이 23 at% 까지 준안정 질화철 분말을 얻을 수 있었다. 질화철 분말의 생성상은 질소 함량이 14.5 at% N 이하의 경우 bcc과포화 고용체가, 20.8 at% N에서는 고온에서 안정한 비평형 hcp 결정 분말이었다. MA법으로 제조한 Fe-N계 분말의 포화 자화는 질소농도가 증가함에 따라 단조로운 감소를 보였으며 보고된 bct 질화철에서의 포화자화값 증가와 대조적인 결과를 나타냈다. 질소원자 주위의 상세한 를 조사하기 위하여 중성자 회절 실험을 행하였다. 그 결과, 9.5 at% N의 질화철 분말의 경우 질소원자 주위의 철원자의 배위수는 3.9이었으며, 이러한 결정구조해석 결과로부터 질소원자는 철원자로 이루어진 4면체의 중심에 위치하고 있는 것으로 판단되었다.

• 한국지구과학회지
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• 제35권5호
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• pp.342-353
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• 2014

Data for model analysis derived from the finite volume (fv) GCM (Goddard Earth Observing System Ver. 4, GEOS-4) and the Land Data Assimilation System (LDAS) have been utilized in a mesoscale model. These data are tested to provide initial conditions and lateral boundary forcings to the Purdue Mesoscale Model (PMM) for a case study of the Midwestern flood that took place from 21-23 May 1998. The simulated results with fvGCM and LDAS soil moisture and temperature data are compared with that of ECMWF reanalysis. The initial conditions of the land surface provided by fvGCM/LDAS show significant differences in both soil moisture and ground temperature when compared to ECMWF control run, which results in a much different atmospheric state in the Planetary Boundary Layer (PBL). The simulation result shows that significant changes to the forecasted weather system occur due to the surface initial conditions, especially for the precipitation and temperature over the land. In comparing precipitation, moisture budgets, and surface energy, not only do the intensity and the location of precipitation over the Midwestern U.S. coincide better when running fvGCM/LDAS, but also the temperature forecast agrees better when compared to ECMWF reanalysis data. However, the precipitation over the Rocky Mountains is too large due to the cumulus parameterization scheme used in the PMM. The RMS errors and biases of fvGCM/LDAS are smaller than the control run and show statistical significance supporting the conclusion that the use of LDAS improves the precipitation and temperature forecast in the case of the Midwestern flood. The same method can be applied to Korea and simulations will be carried out as more LDAS data becomes available.

• 한국세라믹학회지
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• 제53권6호
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• pp.652-658
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• 2016

Gadolinium zirconate, $Gd_2Zr_2O_7$, is one of the most versatile oxides among the new thermal-barrier-coating (TBC) materials for replacing conventional yttira-stabilized zirconia (YSZ). $Gd_2Zr_2O_7$ exhibits excellent properties, such as low thermal conductivity, high thermal expansion coefficient comparable with that of YSZ, and chemical stability at high temperature. In this study, bulk and coating specimens with $Gd_{2-x}Zr_{2+x}O_{7+0.5x}$ (x = 0.0, 0.5, 1.0) compositions were fabricated in order to examine the characteristics of this gadolinium zirconate system with different Gd content for TBC applications. Especially, coatings with $Gd_{2-x}Zr_{2+x}O_{7+0.5x}$ (x = 0.0, 0.5, 1.0) compositions were produced by suspension plasma spray (SPS) with suspension of raw powder mixtures prepared by planetary milling followed by ball milling. Phase formation, microstructure, and thermal diffusivity were characterized for both sintered and coated specimens. Single phase materials with pyrochlore or fluorite were fabricated by normal sintering as well as SPS coating. In particular, coated specimens showed vertically-separated columnar microstructures with thickness of $400{\sim}600{\mu}m$.