• Title/Summary/Keyword: Physico-chemical Properties

Search Result 970, Processing Time 0.029 seconds

Physico-chemical Properties and Antibacterial Activities of Lactonic Sophorolipid (락톤형 소포로리피드의 물리화학적 특성 및 항균효과)

  • Cho, Soo A;Eom, Gyeong Tae;Jin, Byung Suk
    • Applied Chemistry for Engineering
    • /
    • v.30 no.3
    • /
    • pp.303-307
    • /
    • 2019
  • Sophorolipid is a biological surfactant of the glycolipid structure produced by Candida bombicola, which generally exists as a mixture of acidic and lactonic forms. In this study, we investigated physico-chemical properties, antibacterial activities, and cytotoxicity of the sophorolipid containing more than 96% of the lactonic form, produced by the gene regulation of production strains and application of a metabolic engineering technique. The lactonic sophorolipid showed a weak acidity in the range of pH 3.2~4.6 when diluted in water at the concentrations from 1 to 0.001 wt%. The $pK_a$ value of the lactonic sophorolipid was estimated to be around 4.3 from the acid-base titration curve. The critical micelle concentration (CMC) of the lactonic sophorolipid was $10^{-2}wt%$, at which the surface tension of aqueous solution was reduced to 36 mN/m. The lactonic sophorolipid showed the minimum inhibitory concentrations (MIC) of $1{\times}10^{-3}$ and $5{\times}10^{-3}g/mL$ against Propionibacterium acnes and Corynebacterium xerosis, respectively. The MTT (3-(4,5-Dimethylthiazol-2-yl)-2,5-Diphenyltetrazolium Bromide] assay showed that cytotoxicity of the lactonic sophorolipid was ten times lower than that of triclosan.

The Changes of Vulcanization and Physico-Mechanical Properties of NR/BR Blend with the Content of Sulfur and Accelerator (황 및 가황 촉진제의 함량에 따른 NR/BR 블렌드의 가황과 물리적·기계적 특성의 변화)

  • Kim, Wan-Young;Lee, Dai-Soo;Kim, Youn-Sop;Kim, Hyung-Soon;Nah, Chang-Woon
    • Applied Chemistry for Engineering
    • /
    • v.2 no.4
    • /
    • pp.356-362
    • /
    • 1991
  • The physico-mechanical properties of NR/BR blend were measured, and the results were interpreted in terms of the crosslink density with cure system. The cure rate, maximum torque and crosslink density increase with the content and ratio of curative for cure system. Hardness, 300 % tensile modulus, rebound and wear resistance increase with crosslink density of the vulcanizate but heat build-up and tan $\delta$ at $60^{\circ}C$ decrease. It is expected that semi-EV(efficient vulcanization) cure system is appropriate for application in tire tread of truck/bus in which load bearing property is impotant.

  • PDF

Development of Gold Phosphorus Supported Carbon Nanocomposites

  • Mayani, Vishal J.;Mayani, Suranjana V.;Kim, Sang Wook
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.2
    • /
    • pp.401-406
    • /
    • 2014
  • Metal-containing carbon nanocomposites have shown significance promise in the area of energy storage, heterogeneous catalysis and material science because of their morphology and combined properties. Phosphorus-doped carbon nanocomposites with gold nanoparticles were developed by applying a simple impregnation method and metal deposition technique. Gold-phosphorus supported carbon nanocomposites with two sized (25 and 170 nm) were prepared from economical petroleum pitch residue as the carbon source using an advanced silica template method. These nanocomposites will lead to the novel applications in the field of material science with the combined properties of gold, phosphorus and carbon. The newly prepared gold phosphorus supported carbon nanocomposites were fully characterized using a range of different physico-chemical techniques.

Refractive Index and Excess Volume for Diisopropylamine + Isomeric Butanol Mixtures in terms of Nakata and Sakurai model

  • Kumari, Kavitha;Maken, Sanjeev
    • Korean Chemical Engineering Research
    • /
    • v.59 no.4
    • /
    • pp.644-651
    • /
    • 2021
  • Alkyl amines are widely used in various industries. Nowadays these are also used in CO2 capture technology because amines react with CO2 and remove it from the flue gas. To make the amines more compatible towards this technology, physico chemical properties may be altered by mixing with other solvents. In the present report, we measured the refractive properties of pure diisopropylamine (DIPA) (1) + isomeric butanol (2) at 298.15 K to 308.15 K. The 𝚫n values were positive for DIPA + n-butanol or sec-butanol or isobutanol or tert-butanol mixtures. The measured data was correlated with Redlich-Kister equation. The excess molar volume data were predicted from refractive index data using Nakata and Sakurai model. The experimental data were also predicted by various correlations, and the prediction capability of these correlations was reported through standard deviation. Further, the deviation in refractive index (𝚫n) data was interpreted by the consideration of specific molecular interactions between DIPA and isomeric butanol.

Effect of green tea supplementation on probiotic potential, physico-chemical, and functional properties of yogurt (요구르트의 프로바이오틱 활성과 물리화학적 및 기능적 특성에 대한 녹차 추출물의 영향)

  • Lim, Eun-Seo
    • Korean Journal of Microbiology
    • /
    • v.53 no.2
    • /
    • pp.103-117
    • /
    • 2017
  • The aim of this study was to evaluate the effect of green tea extract on probiotic potential, physico-chemical and functional properties of yogurt fermented with Lactobacillus acidophilus D11 or Lactobacillus fermentum D37 strains isolated from Doenjang. Probiotic activities such as the resistance to artificial digestive juices and the ability to adhere to epithelial cells were slightly higher in yogurt supplemented with green tea extract than in plain yogurt, which may be attributed to the increase in the number of lactic acid bacteria (LAB) by green tea extract supplementation. Furthermore, the microbiological and physico-chemical properties such as the number of LAB, organic acid production and viscosity were significantly (P<0.05) increased in yogurt added green tea extract compared to plain yogurt fermented with L. acidophilus D11. However, the green tea extract did not significantly (P>0.05) affect these properties of yogurt fermented with L. fermentum D37 strain. Meanwhile, the antibacterial activities against Escherichia coli O157 ATCC 43889, Salmonella enteritidis ATCC 13076, and Salmonella typhimurium KCTC 2514 and antioxidant activities including total phenol content, radical scavenging ability, and ferric-reducing antioxidant power were significantly higher in plain yogurt fermented with L. fermentum D37 than with L. acidophilus D11. The antibacterial and antioxidant activities of the yogurt were significantly (P<0.05) increased in proportion to the concentration of green tea extract added to plain yogurt. Consequently, green tea yogurt fermented with L. acidophilus D11 or L. fermentum D37 was considered to be a useful functional food that can inhibit the growth of pathogenic bacteria and scavenge the free radicals from the body cells.

A Study on a Classification Technique of Natural Mineral Waters by Its Constitution and Physico-Chemical Properties (鑛泉水 理化學的 水質評價 技法 에 관한 연구)

  • Nam, Sang-Ho
    • Journal of Environmental Health Sciences
    • /
    • v.14 no.1
    • /
    • pp.33-38
    • /
    • 1988
  • Natural mineral water is generally quite different from ordinary drinking water due to its original nature and various properties. The complexity of natural mineral water requires, therefore, not only to identify its nature and proper characteristics, but also to classify them by a reasonable scientific basis of comparison. The study was concentrated on a possible classification technique to natural mineral waters by their constitutions and physico-ehemical properties. The classification was carried out by the computation of such numerical parameters as ionic equivalent percentage, electrolytic conductance or mobility, ionic molecular weight, molecular concentration, equivalent conductivity and degree of ionization in consideration of the determinative criteria as follows -particular single element or molecule -major components of natural waters as bicarbonate, sulphate, chloride,caloride, calcium, magnesium, and sodium -moleculat concentration related to blood osmotic pressure -water temperature at emergence from spring -contents of free carbon dioxide (CO2) -pH value of water -total dissolved solids or salts (NaCl) The results obtained proved out to be clearly distinguhhable from ordinary drinking water as far as concern natural mineral water as an example on the subject -simple water -bicarbonate-predominating water -cold spring -carbonated-non gaseous water -weak alkaline water -non saline water Putting these various results together, the sample turned out to be a kind of natural mineral water that can be used as a drinking water if microbiologically safe.

  • PDF

Fluorescent Nanoparticles: Synthesis and Applications (형광 나노입자: 합성 및 응용)

  • Kim, Y.K.;Song, B.K.;Lee, J.G.;Baek, Y.K.
    • Journal of Powder Materials
    • /
    • v.27 no.2
    • /
    • pp.154-163
    • /
    • 2020
  • Fluorescent nanoparticles are characterized by their unique properties such as luminescence, optical transparency, and sensitivity to various chemical environments. For example, semiconductor nanocrystals (quantum dots), which are nanophosphors doped with transition metal or rare earth ions, can be classified as fluorescent nanoparticles. Tuning their optical and physico-chemical properties can be carried out by considering and taking advantage of nanoscale effects. For instance, quantum confinement causes a much higher fluorescence with nanoparticles than with their bulk counterparts. Recently, various types of fluorescent nanoparticles have been synthesized to extend their applications to other fields. In this study, State-of-the-art fluorescent nanoparticles are reviewed with emphasis on their analytical and anti-counterfeiting applications and synthesis processes. Moreover, the fundamental principles behind the exceptional properties of fluorescent nanoparticles are discussed.

Composition and Physico-Chemical Properties of Vacuum Packaged Korean Pork Loins for Export during Cold Storage (수출용 진공포장 냉장 돈육 등심의 일반성분 및 물리화학적 품질변화)

  • 최염순;박범영;이성기;김일석;김병철
    • Food Science of Animal Resources
    • /
    • v.22 no.2
    • /
    • pp.151-157
    • /
    • 2002
  • The Korean fresh pork loins in vacuum packaged were obtained from three different Korean export companies and investigated for their proximate composition and physico-chemical characteristics. The fresh pork loins were stored at 2$^{\circ}C$ for 50 days and analyzed with an interval of 5∼10 days. In proximate analyses, the moisture contents of pork loins from the company I were higher, the protein contents from the company II were higher, and fat contents from the companies II and III were higher compared to those from the other companies. The pH of loins increased as storage period increased. The shear value of loins from company II showed significantly lower level and tended to decrease during storage. However, the water holding capacity and the purge loss of loins from company II increased during storage periods.

Physico-chemical Changes of Commercial Ssamjang during Storage (공장식 쌈장의 저장기간에 따른 이화학적 성분변화)

  • Kim, Yong-Kook;Kim, Seong-Ju;Han, Min-Soo;Chang, Young-Il;Chang, Kyu-Seob
    • Korean Journal of Food Science and Technology
    • /
    • v.37 no.3
    • /
    • pp.389-396
    • /
    • 2005
  • Physico-chemical properties of ssamjang prepared by industrial process were investigated. Overall experiments were planned by central composite design for five independent variables, kochujang mash aging period $(X_{1})$, doenjang aging period $(X_{2})$, doenjang content $(X_{3})$, sterilization temperature $(X_{4})$, and storage temperature $(X_{5})$. Storage period had no consistent effect on moisture content of ssamjang. Doenjang having longer aging period showed lower moisture content than that having shorter aging period. Titratable acidity and pH of ssamjang gradually increased and decreased with storage period, respectively, with pH of ssamjang significantly affected by aging period of doenjang and kochujang mashes, and sterilization and storage temperatures. Amino nitrogen contents of ssamjang increased during storage and were more affected by sterilization temperature than by aging period and content of doenjang, and storage temperature. Crude protein content of ssamjang irregularly changed during storage, and was slightly affected by content of doenjang.

Comparison of Physico-Chemical, Sensory and Nutritional Characteristics for Water Extract from Bull's Bones of Different Breed (소 품종에 따른 뼈 용출액의 이화학적, 관능적 및 영양적 특성 비교)

  • 김진형;박범영;조수현;유영모;채현석;김학균;김용곤;이종문
    • Food Science of Animal Resources
    • /
    • v.22 no.4
    • /
    • pp.358-362
    • /
    • 2002
  • The physico-chemical, sensory and nutritional properties of water extract from bull's bones of Hanwoo, Holstein, and imported breed were investigated to provide scientific information for consumers. The turbidity, viscosity, lightness(L value) and sensory scores were highest for water extract from Hanwoo's bones among three breeds(p<0.05). Total nitrogen and calcium contents, and calories were higher for water extract from the bones of Hanwoo and Holstein than the imported one(p<0.05), but no differences in the water extract were observed between Hanwoo and Holstein. In amino acid compositions, the percentages of methionine were the highest for water extract from Hanwoo's bones. These results indicated that the water extract from the bones of Hanwoo had the most acceptable quality among three breeds.