• 한국응용과학기술학회지
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• 제20권3호
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• pp.221-229
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• 2003

A copolymer ${\sim}$550cps ; $M_n$, 2590${\sim}$2850 ; and conversion, 82${\sim}$89%, respectively. It was found from the plotting of $T_g$ versus viscosity and $T_g$ versus molecular weight that viscosity increased with $T_g$ while number averaged molecular weight decreased with increasing $T_g$.

• Elastomers and Composites
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• 제23권4호
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• pp.299-307
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• 1988

The mono-, di- and polysulfidic concentrations of the carbon black filled NR and SBR vucanizates which have different cure systems were determined. The n-decane was used as a swelling solvent. The propane-2-thiol and hexane thiol were used as specific chemical probes to cleavage the chemical crosslinks such as di- and polysulfide. In order to understand the effect of crosslink structure on the physical properties of vulcanizates, the tensile properties, fatigue failure, heat build up, compression set and viscoelastic properties were measured. From the results, the significant relationships between crosslink sturctures and physical properties, especially a gins resistance were obtained. Therefore, the better performances of the product can be satisfied by using the interpretations and approaches in this study.

• 한국잠사곤충학회지
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• 제40권1호
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• pp.70-77
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• 1998

This study was carried out in order to find out the relationship between physical and chemical properties of silk fiber treated by concentrated calcium nitrate solution. The tensile, thermal and dynamic mechanical properties are also examined on Ca(NO3)2 treated silk fibers. The tensile properties of silk fibers treated by calcium nitrate changed with a concentration. The thermal behavior were also affected by the concentration of calcium nitrate. The degradation temperature (endotherms) and glass transition temperature shifted to lower temperature as the treated concentration increased. It is thought that the physical properties are strongly related to the structure and morphology of Ca(NO3)2 treated silk fibers. As a result, these give property changes with a concentration dependence.

• Korean Chemical Engineering Research
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• 제46권1호
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• pp.23-36
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• 2008

고분자-점토 나노복합체는 소량의 점토를 사용하여 큰 기계적 물성향상을 나타내 많은 관심을 끌고 있는 분야이다. 층상 구조를 갖고 있는 점토를 고분자 matrix에 분산하는 과정으로 요약할 수 있는 고분자-점토 나노복합체 제조는 친수성 점토 표면을 조절하는 기술, 점토의 물리적 성질을 이용하는 무기재료에 관한 지식, 고분자 합성, 고분자 유변학, 고분자 용액 거동, 기계적 물성이 복합적으로 작용하는 계이다. 이러한 복잡성을 설명하기 위해, 이 총설에서 점토 종류와 그 특성을 설명하였다. 또한 점토 특성과 고분자-점토 나노복합체 제조 방법의 연관성에 대해 설명하고, 제조된 복합체의 구조 분석과 방법에 대해 설명하였다. 그리고 복합체의 특징적인 물성을 분류한 후 그 물성과 복합체의 구조를 연관하여 살펴보았다. 마지막으로 최근의 연구 경향과 향후 연구 경향을 제시하였다.

• Elastomers and Composites
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• 제58권4호
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• pp.161-172
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• 2023

Because particulate matter has emerged as a major contributor to air pollution, the tire industry has conducted studies to reduce particulate matters from tires by improving tire performance. In this study, we compared the conventional blending method, in which rubber, filler, and additives are mixed simultaneously, to the Y-blending method, in which masterbatches are blended. We manufactured carbon black (CB)-filled natural rubber (NR)/butadiene rubber (BR) blend and silica-filled epoxidized NR/BR blend compounds to compare the effects of the two blending methods on the physical properties of the compounds and the amount of particulate matter generated. The Y-blending method provided uniform filler distribution in the heterogeneous rubber matrix, improved processability, and exhibited low rolling resistance. This method also improved physical properties owing to the excellent filler-rubber interaction. The results obtained from measuring the generation of particulate matter indicated that, the Y-blending method reduced PM_2.5 particulate matter generation from the CB-filled and silica-filled compounds by 38% and 60%, and that of PM₁₀ by 29% and 67%, respectively. This confirmed the excellence of the Y-blending method regarding the physical properties of truck bus radial tire tread compounds and reduced particulate matter generated.

• Macromolecular Research
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• 제17권12호
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• pp.950-955
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• 2009

The physical and rheological properties of thermoplasticized irradiation-crosslinked polyethylene foam using supercritical methanol treatment were investigated by GPC, FTIR, DSC, WAXS, DMTA and UDS. The polyethylene foam was selectively decrosslinked into thermoplasticized polyethylene in an appropriate supercritical methanol condition without any undesirable side reactions such as oxidation and disproportionation. The thermoplasticization was promoted with increasing reaction temperature to reach completion above $380^{\circ}C$. The supercritical reaction condition affected the crystallization behavior, and mechanical and rheological properties of the decrosslinked polyethylene foam, but not its crystallographic structure or crystallinity.

• Bulletin of the Korean Chemical Society
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• 제15권2호
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• pp.106-112
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• 1994

Six physical properties (molecular weight, heat capacity, side chain weight, side chain volume, standard entropy and partial molar volume) of amino acids, peptides and their derivatives were examined by molecular modeling techniques. The molecular connectivity index, Wiener distance index and ad hoc descriptor are employed as structural parameters to encode information about branching, size, cyclization, unsaturation, heteroatom content and polarizability. This paper examines the correlation of the molecular modeling techique's parameters and the physicochemical properties of amino acids and their derivatives. As a result, calculated values were in agreement with experimental data in the above six physical properties of amino acids, peptides and their derivatives and the molecular connectivity index was superior to the other indices in fitting the calculated data.

• 한국분말재료학회지
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• 제8권3호
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• pp.207-209
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• 2001

Nano particles have recently been a major research interest, motivated by their unusual physical and chemical properties. Such particles can be synthesized using physical and chemical methods. The physical methods need expensive installation like vacuum induction furnace, whereas in chemical methods the process in generally very simple and low cost. In this study, simple and new fabrication process by using ultrasound was investigated to prepare the nano-sized metal particles on various powders at room temperature.

• 공업화학
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• 제32권1호
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• pp.83-90
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• 2021

본 연구에서는 저온 열처리 탄소의 물리·화학적 특성이 이차전지 음극재로서의 전기화학적 거동에 미치는 영향에 대하여 고찰하였다. 석유계 핏치의 코크스화를 위하여 600 ℃ 열처리를 수행하였으며 제조된 코크스는 700~1500 ℃로 탄화 온도를 달리하여 저온 열처리 탄소 음극재로 제조되었다. 탄소 음극재의 물리 화학적 특성은 N2 흡·탈착 등온선, X-ray diffraction (XRD), 라만 분광(Raman spectroscopy), 원소 분석 등을 통하여 확인하였으며,저온 열처리 탄소의 음극 특성은 반쪽 전지를 통한 용량, 초기 쿨롱 효율(ICE, initial Coulomb efficiency), 율속, 수명 등의 전기화학적 특성을 통하여 고찰하였다. 저온 열처리 탄소의 결정 구조는 1500 ℃ 이하에서 결정자의 크기와 진밀도가 증가하였으며 비표면적은 감소하였다. 저온 열처리 탄소의 물리화학적 특성 변화에 따라 음극재의 전기화학 특성이 변화하였는데 수명 특성은 H/C 원소 비, 초기 쿨롱 효율은 비표면적, 율속 특성은 진밀도의 특성에 기인하는 것으로 판단되었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.141-144
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• 2006

In this study, evaluation of physical and chemical properties of crushed sand was performed to establish optimal mix proportion standard for concrete using crushed sand afterward. Most of properties of crushed sand were satisfied with KS F 2527. Especially, chemical stabilities such as alkali-aggregate reaction were fairly good. However, considerable attention would be required in using crushed sand from lime stone judging from the result that weight loss of it was more than 23.8%. There were some differences in the properties with production region, stone type and capacity of facility, therefore it is thought that quality should be controled by optimal regulations for corresponding items.