Physical and Chemical Properties of Silk Fiber Treated with Calcium Nitrate

질산칼슘 처리농도에 따른 수축견사의 이화학적 특성

  • 이광길 (농촌진흥청 잠사곤충연구소) ;
  • 이용우 (농촌진흥청 잠사곤충연구소, 서울대학교 농업생명과학대학, 서울대학교 노업생명과학대학)
  • Published : 1998.06.01

Abstract

This study was carried out in order to find out the relationship between physical and chemical properties of silk fiber treated by concentrated calcium nitrate solution. The tensile, thermal and dynamic mechanical properties are also examined on Ca(NO3)2 treated silk fibers. The tensile properties of silk fibers treated by calcium nitrate changed with a concentration. The thermal behavior were also affected by the concentration of calcium nitrate. The degradation temperature (endotherms) and glass transition temperature shifted to lower temperature as the treated concentration increased. It is thought that the physical properties are strongly related to the structure and morphology of Ca(NO3)2 treated silk fibers. As a result, these give property changes with a concentration dependence.

Keywords

References

  1. SEN-I Gakkaishi v.24 no.2 Studies on the dissolution of silk fibroin.(I)Studies on the dissolution of silk fibroin by CaCl₂-H ₂O-R · (OH)n, ternary system solution. 味澤 昭義
  2. SEN-I Gakkaishi v.24 no.2 Studies on the dissolution of silk fibroin. (II)Studies on the dissolution of silk fibroin by CaCl₂-H₂O solution 味澤 昭義
  3. J. Sericult. Sci. Japan v.38 no.4 絹フイブロインの溶解に關する硏究, (III) CaCl₂-H₂O-R .OH 3成分系溶液にる絹フイブロインの溶解 味澤 昭義
  4. J. Sericult. Sci. Japan v.38 no.5 絹フイブロインの溶解に關する硏究, (IV) CaCl₂-H₂O-R .OH 3成分系溶液にる絹フイブロインの溶解 味澤 昭義
  5. J. Sericult. Sci. Jappan v.38 no.5 絹フイブロインの溶解に關する硏究, (V) 中性鹽類 溶液 處理による絹フイブロインの鹽縮現象 味澤 昭義
  6. J. Sericult. Sci. Japan v.39 no.3 絹フイブロインの溶解に關する硏究, (VI) 中性鹽類 溶液の參透性と絹フイブロインの鹽縮現 味澤 昭義
  7. J. Sericult. Sci. Japan v.39 no.3 絹フイブロインの溶解に關する硏究, (VII) 絹フイブロインの中性鹽の吸着量 味澤 昭義
  8. 續絹絲の構造 絹の變形と構造形成 平林潔
  9. SEN-I Gakkaishi v.30 no.4 絹の鹽縮 平林潔;鈴木孝雄;石川博
  10. SEN-I Gakkaishi v.25 no.9 絹の示差熱分析 石川博;平林潔;早川忠男
  11. SEN-I Gakkaishi v.28 no.2 DSC thermograms of silk fibroin ISHIKAWA, H.; TSUKADA, M.; DOIZUME, T.; HIRABAYASHI, K.
  12. Polymer Journal v.12 no.8 Characteristics of water in polypeptide membrane KINOSHITA, T.; TANIGAMI, T.; WASHIZU, S.; HAYASHI, S.;TAKIZAWA, A.; TSUJITA, Y.
  13. 高分子化學 v.30 絹の結晶化とα-β轉移に關する硏究 馬越淳;笠井暢民;角戶正末
  14. Journal of Applied Polymer Science v.21 Physical properties and structure of silk. (III) The glass transition and conformational change of Tussah silk fibroin MAGOSHI, J.; MAGOSHI, Y.; NAKAMURA, S.
  15. J. Polym. Sci. Polym. Phys. Ed. v.15 Physical properties and structure of silk. (V) Thermal behavior of silk fibroin in the random-coil conformation MAGOSHI, J.; MAGOSHI, Y.; NAKAMURA, S.; Kasai, N.; Kakudo, M.
  16. J. Appl. Polym. Sci. Japan v.19 Studies on physical properties and structure of silk . Glass transition and crystallization of silk fibroin MAGOSHI, J.; NAKAMURA, S.
  17. 絹絲の構造 鹽縮過程より見たる絹絲の構造 村賴良一
  18. J. Sericult. Sci. Japan v.38 no.6 絹フイブロインの濕熱處理 佐藤信夫;平林潔;石川博
  19. J. Appl. Polym. Sci. v.46 Structural changes of silk fiber induced by heat treatment TSUKADA, H; KASAI, N.
  20. J. Appl. Polym. Sci. v.44 Structure and physical properties of epoxide treated Tussah silk fibers TSUKADA, M.; GOTOH, Y.; FREDDI, G.; MATSUMURA, M.; SHIOZAKI, H.; ISHIKAWA, H.
  21. J. Polym. Sci., Polym. Phys. v.32 Structural changes of silk fibroin membranes induced by immersion in methanol aqueous solution TSUKADA, M.; GOTOH, Y.; NAGURA, M.; MINOURA, N.; KASAI, N.; FREDDI, G.
  22. Journal of Applied Polymer Science v.51 Structural changes and dyeability of silk fibroin fiber following shrinkage in neutral salt solution TSUKADA, M.; KATO, H.;FREDDI, G.; KASAI, N.; ISHIKAWA, H.
  23. J. Sericult. Sci. Japan v.52 no.4