• 한국태양에너지학회:학술대회논문집
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• 2011.04a
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• pp.17-22
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• 2011

There are some degradation factors for amorphous silicon solar cells. Light inducing is one of the factor that explained by Staebler-Wronski effect. Also, hotspot heating could be the reason that makes amorphous silicon solar cell degrade. Hotspot heating is occurred when a solar cell is shaded so this work is investigated into two types of shading condition and how these affect to solar cell differently. Reduced irradiance for whole cell and partially shaded as 0($W/m^2$) while the other part of cell is soaking as 1000($W/m^2$) of irradiance are two conditions that are experimented. The two types of shading show different characteristics of degradations. The result shows that partially shaded cell dropped maximum powerless and slower. Also sudden drop points have shown that should be concerned to decide the number of cells for a string. Otherwise, the current through a shaded cell might flow more than cell's capability. It makes cell and module damaged. This work would help to manufacture modules.

• Journal of the Korean Solar Energy Society
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• v.28 no.3
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• pp.60-66
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• 2008

This study is to investigate an optimal size and position of PV system for apartment complex through the electrical load matching analysis. The 4 types of arrangements of apartment buildings are considered as follows; ㅡtype, alternative ㅡtype, ㄱtype and ㅁtype. We assume that the studied site is composed of 9 buildings. Firstly, solar access evaluation of roof and facade in apartment buildings was performed with the hourly simulations of total received insolation on each surface considering the shading effect of buildings. Electrical load profile of typical Korean apartments were investigated for the load matching analysis. To calculate an annual total PV output, we used MERIT program which is a hourly based load matching tool developed by ESRD. TRY weather data of Daejeon are applied for this analysis. Result shows that approximately 11% of total electric load of the site can be supplied by the PV system in the case of full installation of PV system at the whole south-face roof area of 9 buildings in this stuided apartment complex. Depending on a various installation option of roof and facade area, the possible ratio of PV supply in total electrical load varies from 9% to 42%. Among the 4 arrangement types, the ㅡtype revealed the best option for the maximum output of PV system.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3399-3404
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• 2013

A new accepter unit, pyrrolo[3,2-b]pyrrole-2,5-dione, was prepared and utilized for the synthesis of the conjugated polymers containing electron donor-acceptor pair for OPVs. Pyrrolo[3,2-b]pyrrole-2,5-dione unit, regioisomer of the known pyrrolo[3,4-c]pyrrole-1,4-dione, is originated from the structure of stable synthetic pigment. The new conjugated polymers with 1,4-diphenylpyrrolo[3,2-b]pyrrole-2,5-dione, thiophene and carbazole were synthesized using Suzuki polymerization to generate P1 and P2. The solid films of P1 and P2 show absorption bands with maximum peaks at about 377, 554 and 374, 542 nm and the absorption onsets at 670 and 674 nm, corresponding to band gaps of 1.85 and 1.84 eV, respectively. To improve the hole mobility of the polymer with 1,4-bis(4-butylphenyl)-pyrrolo[3,2-b]-pyrrole-2,5-dione unit, which was previously reported by us, the butyl group at the 4-positions of the N-substituted phenyl group was substituted with hydrogen and methyl group. The field-effect hole mobility of P2 is $9.6{\times}10^{-5}cm^2/Vs$. The device with $P2:PC_{71}BM$ (1:2) showed $V_{OC}$ value of 0.84 V, $J_{SC}$ value of 5.10 $mA/cm^2$, and FF of 0.33, giving PCE of 1.42%.

• Journal of the Korean Chemical Society
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• v.38 no.9
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• pp.632-639
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• 1994

For dye sensitization of zinc oxide in the visible region, copper phthalocyanine(CuPc) and sunfast yellow(SY) were adsorbed in two layers on zinc oxide powder. The adsorption structures of $\alpha-and\beta-CuPc$ on zinc oxide were investigated by photoacoustic, IR and Raman spectra. The ${\alpha}-and\;{\beta}$-polymorphs exhibited dimeric structure or molecular aggregates. The surface photovoltaic effect of ZnO/CuPc/SY showed higher than that of ZnO/SY/CuPc and $ZnO/\beta-CuPc/SY$ indicated better photosensitive than $ZnO/\alpha-CuPc/SY.$ Electrophotographic sensitivity of $ZnO/\beta-CuPc/SY$ was $$S_{1/2}=2.99{\times}10^{-2}(erg/cm^2)^{-1}$ at 630 nm.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.569-574
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• 2014

Inverted bulk hetero-junction polymer solar cells (iPSC) composed of P3HT/PC61BM blends on the ZnO modified with benzoic acid derivatives-based self-assembled monolayers (SAM) are fabricated. Compared with the device using the pristine ZnO, the devices with ZnO surface modified SAMs derived from benzoic acid such as 4-(diphenylamino)benzoic acid (DPA-BA) and 4-(9H-carbazol-9-yl)benzoic acid (Cz-BA) as an electron transporting layer show improved the performances. It is mainly attributed to the favorable interface dipole at the interface between ZnO and the active layer, the eective passivation of the ZnO surface traps, decrease of the work function and facilitating transport of electron from PCBM to ITO electrode. The power conversion eciency (PCE) of iPSCs based on DPA-BA and Cz-BA treated ZnO reaches 2.78 and 2.88%, respectively, while the PCE of the device based on untreated ZnO is 2.49%. The open circuit voltage values ($V_{oc}$) of the devices with bare ZnO and SAM treated ZnO are not much different. Whereas, higher the fill factor (FF) and lower the series resistance ($R_s$) are obtained in the devices with SAMs modification.

• 한국태양에너지학회:학술대회논문집
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• 2011.11a
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• pp.87-92
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• 2011

The heat from PV modules should be removed for better electrical performance, and can be converted into useful thermal energy. A photovoltaic-thermal(PVT)module is a combination of PV module with a solar thermal collector which forms one device that converts solar radiation into electricity and heat simultaneously. The performance of the PV/Thermal combined collector module is directly influenced by solar radiation that also has an effect on PV module temperature. It is also has believe that the energy performance of PV/T collector is related to absorber design as well as PV module temperature. The existing study has been paid to the PV/Thermal combined collector module with circle tube absorbers. The aim of this study is to analyze the experimental performance of the PV/Thermal combined collector rectangular tube absorbers according to solar radiation. The experimental result show that the average thermal and electrical efficiencies of the PVT collector were 43% and14.81% respectively. Solar radiation is one of the most influential factors to determine the energy performance of PVT collector, but from a certain level of solar radiation the PVT collector receives on, its efficiencies began to decrease.

• Korean Management Science Review
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• v.30 no.2
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• pp.97-106
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• 2013

Of the new and renewable energies currently being pursued domestically, wind energy, together with solar photovoltaic energy, is a new core growth driver industry of Korea. As of May 2012, 33 wind farms at a capacity of 347.8MW are in operation domestically. The purpose of this study was to compare and analyze how efficiently each operational wind farm is utilizing its power generation capacity and the weather resource of wind. For this purpose, the study proceeded in 3 phases. In phase 1, ANOVA analysis was performed for each wind farm, thereby categorizing farms according to capacity, region, generator manufacturer, and quantity of weather resources available and comparing and analyzing the differences among their operating efficiency. In phase 2, for comparative analysis of the operating efficiency of each farm, Data Envelopment Analysis (DEA) was used to calculate the efficiency index of individual farms. In the final phase, phase 3, regression analysis was used to analyze the effects of weather resources and the operating efficiency of the wind farm on the power generation per unit equipment. Results shows that for wind power generation, only a few farms had relatively high levels of operating efficiency, with most having low efficiency. Regression analysis showed that for wind farms, a 1 hour increase in wind speeds of at least 3m/s resulted in an average increase of 0.0000045MWh in power generation per 1MW generator equipment capacity, and a unit increase in the efficiency scale was found to result in approximately 0.20MWh power generation improvement per unit equipment.

• Journal of Powder Materials
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• v.25 no.1
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• pp.1-6
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• 2018

Uniform $TiO_2$ blocking layers (BLs) are fabricated using ultrasonic spray pyrolysis deposition (USPD) method. To improve the photovoltaic performance of dye-sensitized solar cells (DSSCs), the BL thickness is controlled by using USPD times of 0, 20, 60, and 100 min, creating $TiO_2$ BLs of 0, 40, 70, and 100 nm, respectively, in average thickness on fluorine-doped tin oxide (FTO) glass. Compared to the other samples, the DSSC containing the uniform $TiO_2$ BL of 70 nm in thickness shows a superior power conversion efficiency of $7.58{\pm}0.20%$ because of the suppression of electron recombination by the effect of the optimized thickness. The performance improvement is mainly attributed to the increased open-circuit voltage ($0.77{\pm}0.02V$) achieved by the increased Fermi energy levels of the working electrodes and the improved short-circuit current density ($15.67{\pm}0.43mA/cm^2$) by efficient electron transfer pathways. Therefore, optimized $TiO_2$ BLs fabricated by USPD may allow performance improvements in DSSCs.

• KIEAE Journal
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• v.3 no.3
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• pp.19-25
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• 2003

The Address No.0 of Eco-friendly Architecture offers unique experience for those who visit the place to envisage the future architecture where nature, human and building exist in harmony. It is open to the general public including the students of elementary and secondary schools. This house has been built to provide opportunities for the general public to experience eco-friendly architecture. It's floor area is 42 pyung($140m^2$) and the overall site has the area of 180 pyung($600m^2$). The following illustrates some of its prominent features : ${\bullet}$ Remodeling of a traditional Korean residence ${\bullet}$ Application of passive solar systems ${\bullet}$ Use of clerestory windows and daylighting systems(washroom and machine room) ${\bullet}$ Operation of solar water heaters with flat plate collectors ${\bullet}$ Construction of Biotop(small ecological world) ${\bullet}$ Water circulation for Biotop by photovoltaic(150W) and wind power(400W) generation ${\bullet}$ Outdoor hot water supplied by all-glass evacuated solar tubes. Through this Address No.0 of Eco-friendly Architeture conclusions are as followings. 1. The array of tubes in collector has the best nice in that the number of tube is nine and the tilt angle is the latitude $+20^{\circ}$. 2. The thermal performance of the all-glass solar vacuum collector was excellent than of the flate-plate solar collector. 3. The adaption of new small wind power systems to buildings were proved to produce a profit if it is considered the expense of environment improvement and the wind speed increasing according to rise of building hight.

• Transactions on Electrical and Electronic Materials
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• v.16 no.3
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• pp.124-129
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• 2015

Organic electronics are the domain in which the components and circuits are made of organic materials. This new electronics help to realize electronic and optoelectronic devices on flexible substrates. In recent years, organic materials have replaced conventional semiconductors in many electronic components such as, organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs) and organic photovoltaic (OPVs). It is well known that organic light emitting diodes (OLEDs) have many advantages in comparison with inorganic light-emitting diodes LEDs. These advantages include the low price of manufacturing, large area of electroluminescent display, uniform emission and lower the requirement for power. The aim of this paper is to model polymer LEDs and OLEDs made with small molecules for studying the electrical and optical characteristics. The purpose of this modeling process is, to obtain information about the running of OLEDs, as well as, the injection and charge transport mechanisms. The first simulation structure used in this paper is a mono layer device; typically consisting of the poly (2-methoxy-5(2'-ethyl) hexoxy-phenylenevinylene) (MEH-PPV) polymer sandwiched between an anode with a high work function, usually an indium tin oxide (ITO) substrate, and a cathode with a relatively low work function, such as Al. Electrons will then be injected from the cathode and recombine with electron holes injected from the anode, emitting light. In the second structure, we replaced MEH-PPV by tris (8-hydroxyquinolinato) aluminum (Alq₃). This simulation uses, the Poole-Frenkel -like mobility model and the Langevin bimolecular recombination model as the transport and recombination mechanism. These models are enabled in ATLAS- SILVACO. To optimize OLED performance, we propose to change some parameters in this device, such as doping concentration, thickness and electrode materials.