• Current Photovoltaic Research
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• v.4 no.1
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• pp.8-11
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• 2016

Strong deep ultraviolet emitting aniline and $TiO_2$ composite has been synthesized via hydrolysis and condensation reactions of titaniumisopropoxide ($Ti(OPr)_4$), aniline, and acetic anhydride. Three different weight ratios of aniline and $Ti(OPr)_4$ including 3:1 ($TiO_2An-A$), 2:1 ($TiO_2An-B$), and 1:1 ($TiO_2An-C$) were synthesized and characterized their optical properties. The FTIR spectra of the $TiO_2An-A$, -B, and -C showed the absorption intensities of the benzene ring stretching and bending vibrations, and benzene ring -CH stretching, bending, and deformation vibrations increased with the increase of the amount of aniline. The UV-visible absorption spectra showed that the UV region absorption was slightly increased with the increase of the amount of aniline. The photoluminescence (PL) intensities were exponentially increased with the increase the excitation wavelength from 307 to 317 nm, steadily increased from 300 to 313 nm and slowly increased from 302 to 308 nm for $TiO_2An-A$, -B, and -C, respectively and decreased thereafter. Therefore, the PL intensity is strongly dependent on the weight ratio of $Ti(OPr)_4$ and aniline.

• Current Photovoltaic Research
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• v.7 no.4
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• pp.130-133
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• 2019

The Ag crystallite formed during the formation of the front electrode forms a contact between the metal of the electrode and the emitter of the cell. Contact between the electrode and emitter plays an important role in collecting electrons generated by the solar cell. Therefore, Ag crystallite formation is an important factor. In order for solar cells to have good characteristics, it is important to understand the factors influencing the Ag crystallite formation. Factors affecting the formation of Ag crystallites include Si emitter, morphology, Si defect and firing temperature. The influence of surface morphology on Ag crystallite formation was confirmed throughout this study. In the case of fine texturing, the Ag crystallites were formed at the pointed parts. The finer the texturing, the sharper areas and more Ag crystallites were formed. This was confirmed by SEM image and FF calculation.

• Korean Journal of Materials Research
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• v.26 no.8
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• pp.417-421
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• 2016

We improve the energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC) by preparing a working electrode (WE) with localized surface plasmon resonance (LSPR) by inducing Au thin films with thickness of 0.0 to 5.0 nm, deposited via sputtering. Field emission scanning electron microscopy and atomic force microscopy were used to characterize the microstructure of the blocking layer (BL) of the Au thin films. Micro-Raman measurement was employed to confirm the LSPR effect, and a solar simulator and potentiostat were used to evaluate the photovoltaic properties, including the impedance and the I-V of the DSSC of the Au thin films. The results of the microstructural analysis confirmed that nano-sized Au agglomerates were present at certain thicknesses. The photovoltaic results show that the ECE reached a value of 5.34% with a 1-nm thick-Au thin film compared to the value of 5.15 % without the Au thin film. This improvement was a result of the increase in the LSPR of the $TiO_2$ layer that resulted from the Au thin film coating. Our results imply that the ECE of a DSSC may be improved by coating with a proper thickness of Au thin film on the BL.

• Proceedings of the KIEE Conference
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• 2011.07a
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• pp.1405-1405
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• 2011

Sudden earthquake is changing national energy stratagem for future energy resource. In case Germany, current nuke power station will be shut down with several decades. Newly constructed build in Japan must have photovoltaic system as a obligations.. As a long-term sustainable energy one, PV should give confidence to customers up to more than 20 years. Today, IEC 61215 and IEC 61646 standards are representative one for ensuring performance and safety of PV module. But it is still needed to develop more realistic test method. For example, if we think about extreme condition like desert and North Pole, the temperature condition describe in test standards can have little effect on life time expectation of PV module. Installation speed of PV system is very high, but establishing test standards are very complex and not easy. So in this paper, I tried to open the long-term test method for PV module to ensure 25 year's old life time. It is just starting point of PV related long-term test methods. The specific and technical explanation will be shown in the following paper in detail.

• Current Photovoltaic Research
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• v.5 no.2
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• pp.59-62
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• 2017

Surface texturing is affected the uniformity and size of pyramid with saw mark defect density. To analysis the influence of the saw mark defect density, we textured various si wafer. When the texturing process proceeds without the saw mark removal, silicon wafer of low-saw mark defect density showed small pyramid size of $3.5{\mu}m$ with the lowest average value of the reflectance of 10.6%. When texturing carried out after removal of the saw mark using the TMAH solution, we obtained a reflectance of about 11% and the large pyramid size of $5{\mu}m$. As a result, saw mark wafers showed a better pyramid structure than saw mark-free wafer. This result showed that saw mark can take place more smooth etching by the KOH solution and saw mark-free wafer is determined to be a factor that have a higher reflectance and a large pyramid.

• KIEE International Transaction on Electrical Machinery and Energy Conversion Systems
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• v.5B no.1
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• pp.57-62
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• 2005

Grid-connected photovoltaic (PV) systems were installed and monitored at the field demonstration test center (FDTC) in Korea in October 2002. Before long-term field testing of installed PV systems, the performances of PV components were evaluated and compared through short-term performance tests of each of the PV system components such as power conditioning system and PV module under standard test conditions. A data acquisition system has been constructed for measuring and analyzing the performance of PV systems to observe the overall effect of environmental conditions on their operation characteristics. Performances of PV systems have been evaluated and analyzed not only for component perspective (PV array, power conditioning unit) but also for global perspective (system efficiency, capacity factor, electrical power energy) by review of the field test and loss factors of the systems. These results indicate that it is highly imperative to develop an optimum design technology of grid connected PV systems. The objective of this paper is not only to evaluate and analyze the performance of domestic PV systems application through long-term field testing at FDTC but also to develop evaluation, analysis and optimum technology for long-term stability and reliability of grid-connected PV systems in Korea.

• Journal of the Korean Solar Energy Society
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• v.24 no.2
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• pp.9-15
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• 2004

3kW grid connected PV(photovoltaic) systems have been constructed for evaluating and analyzing performance of PV system at FDTC(field demonstration test center) in Korea, PV systems installed in FDTC have been operating and monitored since November 2002. As climatic and irradiation conditions have been varied through long-term field test, data acquisition system has been constructed for measuring performance of PV system to observe the overall effect of environmental conditions on their operation characteristics. The performance of PV systems has been evaluated and analyzed for component perspective(PV array and power conditioning system) and global perspective(system efficiency, capacity factor, and electrical power energy) by field test. By the results, it is very important to develop optimal design technology of grid connected PV system.

• 한국태양에너지학회:학술대회논문집
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• 2009.04a
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• pp.220-224
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• 2009

The effect of addition of single and binary additives on the performance of dye-sensitized $TiO_2$ solar cells based on 1,2-dimethyl-3-propylimidazolium iodide (DMPII) in ethylene carbonate (EC) and gamma-butyrolactone (GBL) has been evaluated at different cell temperatures in the $30-120^{\circ}C$ range. The electrolyte containing a single additive, 2-(dimethylamino)-pyridine (DMAP) showed best performance, which showed further enhancement for an electrolyte containing binary additives, DMAP and 5-chloro-1-ethyl-2-methylimidazole (CEMI) in equal molar ratio. The performance of the dye sensitized solar cell (DSC) based on electrolyte containing binary additives were found to be better than an acetonitrile based electrolyte. The dependence of different photovoltaic parameters (Voc, Jsc, ff, n) of the DSC upon temperature has been studied over the $30-120^{\circ}C$ range and only a small decrease in conversion efficiency has been observed. Thus the electrolyte containing binary additives (DMAP, CEMI) in EC/GBL solvent and show better performance in the investigated temperature range ($30-120^{\circ}C$).

• Journal of ILASS-Korea
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• v.18 no.4
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• pp.209-214
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• 2013

The present study aims to determine the optimized shape for the maximum electric energy production of building integrated photovoltaic system (BIPV) noise barrier through numerical analysis. The shape of BIPV noise barrier is one of the important factors in determining angle difference between direction vector of the sun and normal vector of the sound barrier surface. This study simulated numerically the flow and thermal fields for different angles in the range from $90^{\circ}$ to $180^{\circ}$, and from the results, the amount of isolation onto noise barrier surface was estimated along the angle between ground and top side of noise barrier. The commercial CFD code (Fluent V. 13.0) was used for calculation. It was found that the maximum amount of insolation per unit area was 19.6 MJ for $105^{\circ}$ case during a day in summer and was estimated 12.4 MJ in $150^{\circ}$ case during a day in winter. The results of the summer and winter cases showed the different tendency and this result would be useful in determining the appropriate shape of noise barrier which can be mounted under various circumstances.

• Journal of Electrochemical Science and Technology
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• v.2 no.2
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• pp.68-75
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• 2011

In this review, we have investigated the effect of $TiO_2$-based blocking layers (t-BLs), deposited on a transparent conductive oxide (TCO)-coated glass substrate, on the photovoltaic performance of dye-sensitized solar cells (DSSCs). The t-BL was deposited using spin-coating or sputtering technique, and its thicknesses were varied to study the influence of the thin $TiO_2$ layer in between transparent conducting glass and nanocrystalline $TiO_2$ (nc-$TiO_2$). The DSSC with the t-BL showed the improved adhesion and the suppressed charge recombination at a TCO glass substrate than those without the t-BL, which led to the higher conversion efficiency.