• Bulletin of the Korean Chemical Society
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• v.33 no.9
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• pp.3061-3070
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• 2012

Novel 2-hexylthieno[3,2-b]thiophene-containing conjugated molecules have been synthesized via a reduction reaction using tin chloride in an acidic medium. They exhibited good solubility in common organic solvents and good self-film and crystal-forming properties. The single-crystalline objects were fabricated by a solvent slow diffusion process and then were employed for fabricating field-effect transistors (FETs) along with thinfilm transistors (TFTs). TFTs made of 5 and 6 exhibited carrier mobility as high as 0.10-0.15 $cm^2V^{-1}s^{-1}$. The single-crystal-based FET made of 6 showed 0.70 $cm^2V^{-1}s^{-1}$ which was relatively higher than that of the 5-based FET (${\mu}=0.23cm^2V^{-1}s^{-1}$). In addition, we fabricated organic photovoltaic (OPV) cells with new 2-hexylthieno [3,2-b]thiophene-containing conjugated molecules and methanofullerene [6,6]-phenyl C61-butyric acid methyl ester ($PC_{61}BM$) without thermal annealing. The ternary system for a bulk heterojunction (BHJ) OPV cell was elaborated using $PC_{61}BM$ and two p-type conjugated molecules such as 5 and 7 for modulating the molecular energy levels. As a result, the OPV cell containing 5, 7, and $PC_{61}BM$ had improved results with an open-circuit voltage of 0.90 V, a short-circuit current density of 2.83 $mA/cm^2$, and a fill factor of 0.31, offering an overall power conversion efficiency (PCE) of 0.78%, which was larger than those of the devices made of only molecule 5 (${\eta}$~0.67%) or 7 (${\eta}$~0.46%) with $PC_{61}BM$ under identical weight compositions.

• Journal of the Society of Disaster Information
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• v.14 no.2
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• pp.130-140
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• 2018

Purpose: In this paper, we propose a design technique for the safety characterization grounding in the construction of the photovoltaic power generation complex which can be useful and useful as an alternative power energy source in our society. In other words, we will introduce the application of safety grounding for each application, which can improve and optimize the reliability of the internal grid from the cell module to the electric room in the photovoltaic power generation complex. Method: We analyze the earth resistivity of the soil in the solar power plant and use the computer program (CDEGS) to analyze the contact voltage and stratospheric voltage causing the electric shock, and propose the calculation and calculation method of the safety ground. In addition, we will discuss the importance of semi-permanent ground electrode selection in consideration of soil environment. Results: We could obtain the maximum and minimum value of ground resistivity for each of the three areas of the data measured by the Wenner 4 - electrode method. The measured data was substituted into the basic equation and calculated with a MATLAB computer program. That is, it can be determined that the thickness of the minimum resistance value is the most favorable soil environment for installing the ground electrode. Conclusion: Through this study, we propose a grounding system design method that can suppress the potential rise on the ground surface in the inner grid of solar power plant according to each case. However, the development of smart devices capable of accumulating big data and a monitoring system capable of real-time monitoring of seismic changes in earth resistances and grounding systems should be further studied.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.505-512
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• 2014

A new donor-accepter-donor-accepter-donor (D-A-D-A-D) type 2,1,3-benzothiadiazole-thiophene-based acceptor unit 2,5-di(4-(5-bromo-4-octylthiophen-2-yl)-2,1,3-benzothiadiazol-7-yl)thiophene ($DTBTTBr_2$) was synthesized. Copolymerized with fluorene and indeno[1,2-b]fluorene electron-rich moieties, two alternating narrow band gap (NBG) copolymers PF-DTBTT and PIF-DTBTT were prepared. And two copolymers exhibit broad and strong absorption in the range of 300-700 nm with optical band gap of about 1.75 eV. The highest occupied molecular orbital (HOMO) energy levels vary between -5.43 and -5.52 eV and the lowest unoccupied molecular orbital (LUMO) energy levels range from -3.64 to -3.77 eV. Potential applications of the copolymers as electron donor material and $PC_{71}BM$ ([6,6]-phenyl-$C_{71}$ butyric acid methyl ester) as electron acceptors were investigated for photovoltaic solar cells (PSCs). Photovoltaic performances based on the blend of PF-DTBTT/$PC_{71}BM$ (w:w; 1:2) and PIF-DTBTT/$PC_{71}BM$ (w:w; 1:2) with devices configuration as ITO/PEDOT: PSS/blend/Ca/Al, show an incident photon-to-current conversion efficiency (IPCE) of 2.34% and 2.56% with the open circuit voltage ($V_{oc}$) of 0.87 V and 0.90 V, short circuit current density ($J_{sc}$) of $6.02mA/cm^2$ and $6.12mA/cm^2$ under an AM1.5 simulator ($100mA/cm^2$). The photocurrent responses exhibit the onset wavelength extending up to 720 nm. These results indicate that the resulted narrow band gap copolymers are viable electron donor materials for polymer solar cells.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.23 no.2
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• pp.149-155
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• 2023

Photovoltaic power generation is the most familiar power generation facility among new and renewable energies, and its supply began to expand about 10 years ago, and at this point, interest in solutions and technologies for system maintenance management is increasing. In particular, it is necessary to take measures to maximize the overall efficiency of the solar power generation system, whether or not there is an abnormality in the solar power generation system, and when to replace parts. The PV inverter, one element of the photovoltaic power generation system, is a power conversion system that relies on power switching devices, and DC-Link capacitors are used according to the configuration of DC/DC converters and DC-AC inverters. These DC capacitors also affect system safety (Safety) through renewable energy facilities due to the decrease in power generation of PV inverters, power loss, and increase in harmonics (THD, total distortion of AC output current) due to aging and deterioration due to long-term use. factors can be analyzed. Therefore, in this paper, the PV inverter operating characteristics according to the DC capacitor capacity state currently operating in the photovoltaic power generation system were considered, and research contents were proposed to secure the safety and reliability of renewable energy facilities.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.62 no.10
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• pp.1383-1389
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• 2013

There were telecommunication noise and malfunctions of the electronic devices occurred over a wide area due to the high harmonic voltage and/or current levels of the Back-to-back converter in the DFIG wind power system even though the magnitude of all harmonics is within the international standards. The triangular carrier signals of the PWM used in the power converter system is related to the telecommunication noise because they are in the range of audible frequencies and amplified by a variety of the standing waves that were excited by harmonic voltage sources in the weak grid system such as a long distance distribution transmission lines. This paper describes the characteristics of the harmonics in the wind turbine-generator, numerical analysis and simulation of the harmonics resonance phenomena in the distribution lines as well as measuring induced voltage of the telecommunication lines in parallel with power lines in order to verify the root cause of the telecommunication noise. These noise problems can occur in a wind turbine power system with a non-linear converter at any time, as well as photovoltaic power system. So, the preliminary review of suitable filter devices and switching frequencies of the PWM have to be required by considering the stability of the controller at the design stage but as part of the measures the effect of the telecommunication cable shields was analyzed by comparing the measured data between multi-conductor with/without shields so as to attenuate the sources of the harmonics voltage induced into the telecommunication lines and to apply the most cost-effective measures in the field.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.17 no.2
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• pp.263-272
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• 2013

Printed electronics creates electrically functional devices by printing on variety of substrates. Printing typically uses common printing equipment or other low-cost equipment suitable for defining patterns on material, such as screen printing, flexography, gravure, offset lithography and inkjet. Compared to conventional manufacturing of microelectronics, printed electronics is characterized by simpler and more cost-effective fabrication of high and low volume products. Now there is huge effort towards printing many other more functional components, from displays to transistors to photovoltaic cells, using the full range of printing technologies - from inkjet to roll to roll analogue print techniques. The market for printed electronics will rise from $1.99 billion in 2010 to $55.10 billion in 2020. In 2030, this industry could be $300 billion - larger than the silicon semiconductor industry - from lighting to displays[8].

• Journal of the Korea Convergence Society
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• v.2 no.2
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• pp.35-45
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• 2011

Recently, with the increasement of the interest about global warming, pollutions, and so on, a number of distributed generations(DGs) such as photovoltaic(PV) and wind power(WP), are interconnected with distribution systems. However, installing of DGs makes power flow changes such as directions, one-direction to bi-direction, and increasing/decreasing of fault current. Therefore, it may cause the critical problems. This paper proposes an evaluation algorithm for bi-directional protection coordination and presents an evaluation system for protection coordination based on this algorithm. Additionally, the result shows that the existing method may cause critical problems, and also the effectiveness of proposed method is verified.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.6
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• pp.2971-2978
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• 2013

Recently, with the world-wide issues about global warming and CO2 reduction, a number of distributed generations(DGs) such as photovoltaic(PV) and wind power(WP), are interconnected with the distribution systems. However, DGs can change the direction of the power flow from one-direction to bi-direction, and also change the direction and amount of fault current of existing distribution systems. Therefore, it may cause the critical problems on the power quality and protection coordination. This paper proposes an operation algorithm for bi-directional protection coordination using and apply it for the evaluation system for protection coordination. From the simulation results It is found that the proposed method is more effective and convenient than existing method.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.99.2-99.2
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• 2011

Transparent conducting oxides (TCOs) supported on glass are widely used as substrates in PEC studies for photovoltaic hydrogen generation applications However, high sheet resistane ($10{\sim}15{\Omega}/cm^2$) and fragileness of glass-supported TCO substrates are the obstacles to produce the large area PEC cells. Such internal sheet resistance is detrimental to efficient collection of photogenerated majority charge carriers at the photoactive material and electrolyte interface. Moreover, these TCO substrates are very expensive and consume about 40~60% cost of the devices. Hence, a low sheet resistance of the substrate is a key point in improving the performance of PEC devices. Metallic substrates coated with a photoactive material would be a good choice for efficient charge collection. Such metal substrates based photanodes are best candidate for large-scale phtoelectrochemical water splitting for hydrogen generation. In this study, we report the enhanced PEC performance of $WO_3$ film on metal(chemical etched, bare) substrate. It is proposed that interface between $WO_3$ and the metal substrate is responsible for efficient charge transfer and demonstrated significant improvement in the photoelectrochmical performance. X-ray diffration and FESEM suduies reveled that $WO_3$ films are monoclinic, porous, polycrystalline with average grain size of ~50nm. Photocurrent of $WO_3$ prepared on metal substrates was measured in 0.5M $H_2SO_4$ electroyte under simulated $100mW/cm^2$ illumination.

• Bulletin of the Korean Chemical Society
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• v.30 no.10
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• pp.2329-2337
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• 2009

Three heteroleptic ruthenium sensitizers, Ru(L)($L^1)(NCS)_2$ [L = 4,4'-dicarboxylic acid-2,2'-bipyridine, Ru-T1: $L^1$ = (E)-2-(4'-methyl-2,2'-bipyridin-4-yl)-3-(thiophen-2-yl)acrylonitrile, Ru-T2: $L^2$ = (E)-3-(5'-hexyl-2,2'-bithiophen-5- yl)-2-(4'-methyl-2,2'-bipyridin-4-yl)acrylonitrile, and Ru-T3: $L^3$ = (E)-3-(5"-hexyl-2,2':5',2"-terthiophen-5-yl)-2- (4'-methyl-2,2'-bipyridin-4-yl)acrylonitrile)], were synthesized and used as photosensitizers in nanocrystalline dyesensitized solar cells (DSSCs). The introduction of the 3-(5-hexyloligothiophen-5-yl)acrylonitrile group increased the conjugation length of the bipyridine donor ligand and thus improved their molar absorption coefficient and light harvesting efficiency. DSSCs with the configuration of Sn$O_2$: F/Ti$O_2$/ruthenium dye/liquid electrolyte/Pt devices were fabricated using these Ru-$T1{\sim}T3$ as a photosensitizers. Among the devices, the DSSCs composed of Ru-T2 exhibited highest power conversion efficiency (PCE) of 2.84% under AM 1.5 G illumination (100 mW/$cm^2$).