DOI QR코드

DOI QR Code

Synthesis and Photovoltaic Properties of Novel Ruthenium(II) Sensitizers for Dye-sensitized Solar Cell Applications

  • Ryu, Tae-In (Department of Chemistry Education, Interdisciplinary Program of Advanced Information and Display Materials, and Center for Plastic Information System, Pusan National University) ;
  • Song, Myung-Kwan (Department of Chemistry Education, Interdisciplinary Program of Advanced Information and Display Materials, and Center for Plastic Information System, Pusan National University) ;
  • Lee, Myung-Jin (Department of Chemistry Education, Interdisciplinary Program of Advanced Information and Display Materials, and Center for Plastic Information System, Pusan National University) ;
  • Jin, Sung-Ho (Department of Chemistry Education, Interdisciplinary Program of Advanced Information and Display Materials, and Center for Plastic Information System, Pusan National University) ;
  • Kang, Sun-Woo (Department of Chemistry, Sungkyunkwan University) ;
  • Lee, Jin-Yong (Department of Chemistry, Sungkyunkwan University) ;
  • Lee, Jae-Wook (Department of Chemistry, Dong-A University) ;
  • Lee, Chan-Woo (Department of Chemistry, University of Ulsan) ;
  • Gal, Yeong-Soon (Polymer Chemistry Lab, Kyungil University)
  • Published : 2009.10.20

Abstract

Three heteroleptic ruthenium sensitizers, Ru(L)($L^1)(NCS)_2$ [L = 4,4'-dicarboxylic acid-2,2'-bipyridine, Ru-T1: $L^1$ = (E)-2-(4'-methyl-2,2'-bipyridin-4-yl)-3-(thiophen-2-yl)acrylonitrile, Ru-T2: $L^2$ = (E)-3-(5'-hexyl-2,2'-bithiophen-5- yl)-2-(4'-methyl-2,2'-bipyridin-4-yl)acrylonitrile, and Ru-T3: $L^3$ = (E)-3-(5"-hexyl-2,2':5',2"-terthiophen-5-yl)-2- (4'-methyl-2,2'-bipyridin-4-yl)acrylonitrile)], were synthesized and used as photosensitizers in nanocrystalline dyesensitized solar cells (DSSCs). The introduction of the 3-(5-hexyloligothiophen-5-yl)acrylonitrile group increased the conjugation length of the bipyridine donor ligand and thus improved their molar absorption coefficient and light harvesting efficiency. DSSCs with the configuration of Sn$O_2$: F/Ti$O_2$/ruthenium dye/liquid electrolyte/Pt devices were fabricated using these Ru-$T1{\sim}T3$ as a photosensitizers. Among the devices, the DSSCs composed of Ru-T2 exhibited highest power conversion efficiency (PCE) of 2.84% under AM 1.5 G illumination (100 mW/$cm^2$).

Keywords

References

  1. Bilgen, S.; Kaygusuz, K.; Sari, A. Energy Sources 2004, 26, 1119. https://doi.org/10.1080/00908310490441421
  2. O'Regan, B.; Gratzel, M. Nature 1991, 353, 737. https://doi.org/10.1038/353737a0
  3. Nazeeruddin, M. K.; Kay, A.; Rodicio, I.; Humphry-Baker, R.; Muller, E.; Liska, P.; Vlachopoulos, N.; Gr$\ddot{a}$tzel, M. J. Am. Chem. Soc. 1993, 115, 6382. https://doi.org/10.1021/ja00067a063
  4. Nazeeruddin, M. K.; Pechy, P.; Renouard, T.; Zakeeruddin, S. M.; Humphry-Baker, R.; Comte, P.; Liska, P.; Cevey, L.; Costa, E.; Shklover, V.; Spiccia, L.; Deacon, G. B.; Bignozzi, C. A.; Gr$\ddot{a}$tzel, M. J. Am. Chem. Soc. 2001, 123, 1613. https://doi.org/10.1021/ja003299u
  5. Ushiroda, S.; Ruzycki, N.; Lu, Y.; Spitler, M. T.; Parkinson, B. A. J. Am. Chem. Soc. 2005, 127, 5158. https://doi.org/10.1021/ja044001t
  6. Horiuchi, T.; Miura, M.; SumioKa, K.; Uchida, S. J. Am. Chem. Soc. 2004, 126, 12218. https://doi.org/10.1021/ja0488277
  7. Wang, Z. S.; Yamaguchi, T.; Sugihara, H.; Arakawa, H. Langmuir 2005, 21, 4272. https://doi.org/10.1021/la050134w
  8. Nazeeruddin, M. K.; Zakeeruddin, S.; Humphry-Baker, R.; Jirousek, M.; Liska, P.; Vlachopoulos, N.; Shklover, V.; Fischer, C. H.; Gr$\ddot{a}$tzel, M. Inorg. Chem. 1999, 38, 6298. https://doi.org/10.1021/ic990916a
  9. Nazeeruddin, M. K.; Angelis, F. D.; Fantacci, S.; SElloni, A.; Viscardi, G.; Liska, P.; Ito, S.; Takeru, B.; Gr$\ddot{a}$tzel, M. J. Am. Chem. Soc. 2005, 127, 16835. https://doi.org/10.1021/ja052467l
  10. Nazeeruddin, M. K.; Pechy, P.; Gr$\ddot{a}$tzel, M. Chem. Comm. 1997, 1705
  11. Yanagida, M.; Singh, L. P.; Sayama, K.; Hara, K.; Katoh, R.; Islam, A.; Sugihara, H.; Arakawa, H.; Nazeeruddin, M. K.; Gr$\ddot{a}$tzel, M. J. Chem. Soc. Dalton Trans. 2000, 2817.
  12. Sugihara, H.; Singh, L. P.; Sayama, K.; Arakawa, H.; Nazeeruddin, M. K.; Gr$\ddot{a}$tzel, M. Chem. Lett. 1998, 10, 1005.
  13. Renouard, T.; Fallahpour, R. A.; Nazeeruddin, M. K.; Humphry- Baker, R.; Gorelsky, S. I.; Lever, A. B. P.; Gr$\ddot{a}$tzel, M. Inorg. Chem. 2002, 41, 367. https://doi.org/10.1021/ic010512u
  14. Wang, P.; Zakeeruddin, S. M.; Moser, J.-E.; Humphry-Baker, R.; Comte, P.; Aranyos, V.; Hagfeldt, A.; Nazeeruddin, M. K.; Gr$\ddot{a}$tzel, M. Adv. Mater. 2004, 16, 1806. https://doi.org/10.1002/adma.200400039
  15. Wang, P.; Klein, C.; Humphry-Baker, R.; Comte, P.; Aranyos, V.; Hagfeldt, A.; Nazeeruddin, M. K.; Gr$\ddot{a}$tzel, M. J. Am. Chem. Soc. 2005, 127, 808. https://doi.org/10.1021/ja0436190
  16. Abbotto, A.; Barolo, C.; Bellotto, L.; Angelis, F. D.; Grätzel, M.; Manfredi, N.; Marinzi, C.; Fantacci, S.; Yum, J. H.; Nazeeruddin, M. K. Chem. Comm. 2008, 42, 5318.
  17. Frisch, M. J. Gaussian 03, Revision A1; Gaussian Inc.: Pittsburgh, PA, 2003.
  18. Kang, M. G.; Kim, K. M.; Ryu, K. S.; Chang, S. H.; Park, N. G.; Hong, J. S.; Kim, K. J. J. Electrochem. Soc. 2004, 151, E257. https://doi.org/10.1149/1.1759698
  19. Raposo, M. M. M.; Fonseca, A. M. C.; Kirsch, G. Tetrahedron 2004, 60, 4071. https://doi.org/10.1016/j.tet.2004.03.022
  20. Klein, C.; Nazeeruddin, M. K.; Di Censo, D.; Liska, P.; Gr$\ddot{a}$tzel, M. Inorg. Chem. 2004, 43, 4216. https://doi.org/10.1021/ic049906m
  21. Hagfeldt, A.; Gr$\ddot{a}$tzel, M. Chem. Rev. 1995, 95, 49. https://doi.org/10.1021/cr00033a003

Cited by

  1. Influence of Ancillary Ligands in Dye-Sensitized Solar Cells vol.116, pp.16, 2016, https://doi.org/10.1021/acs.chemrev.5b00621
  2. Synthesis and properties of an ionic polyacetylene by the activated polymerization of 2-ethynylpyridine with the ring-opening of propiolactone vol.161, pp.5, 2009, https://doi.org/10.1016/j.synthmet.2010.12.026
  3. Synthesis and Characterization of 5′-Hexyl-2,2′-bithiophene Based on Organic Dyes for Dye-Sensitized Solar Cell Applications vol.599, pp.1, 2009, https://doi.org/10.1080/15421406.2014.935986