• Title/Summary/Keyword: Phonon energy

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Nanopatterned Surface Effect on the Epitaxial growth of InGaN/GaN Multi-quantum Well Light Emitting Diode Structure

  • Kim, Keun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.40-43
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    • 2009
  • The authors fabricated a nanopatterned surface on a GaN thin film deposited on a sapphire substrate and used that as an epitaxial wafer on which to grow an InGaN/GaN multi-quantum well structure with metal-organic chemical vapor deposition. The deposited GaN epitaxial surface has a two-dimensional photonic crystal structure with a hexagonal lattice of 230 nm. The grown structure on the nano-surface shows a Raman shift of the transverse optical phonon mode to $569.5\;cm^{-1}$, which implies a compressive stress of 0.5 GPa. However, the regrown thin film without the nano-surface shows a free standing mode of $567.6\;cm^{-1}$, implying no stress. The nanohole surface better preserves the strain energy for pseudo-morphic crystal growth than does a flat plane.

Heat jet approach for finite temperature atomic simulations of two-dimensional square lattice

  • Liu, Baiyili;Tang, Shaoqiang
    • Coupled systems mechanics
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    • v.5 no.4
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    • pp.371-393
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    • 2016
  • We propose a heat jet approach for a two-dimensional square lattice with nearest neighbouring harmonic interaction. First, we design a two-way matching boundary condition that linearly relates the displacement and velocity at atoms near the boundary, and a suitable input in terms of given incoming wave modes. Then a phonon representation for finite temperature lattice motion is adopted. The proposed approach is simple and compact. Numerical tests validate the effectiveness of the boundary condition in reflection suppression for outgoing waves. It maintains target temperature for the lattice, with expected kinetic energy distribution and heat flux. Moreover, its linear nature facilitates reliable finite temperature atomic simulations with a correct description for non-thermal motions.

Co-doping Effects on the Blue Up-conversion Characteristics of Fluoride Glasses (희토류 원소의 복합첨가에 의한 fluride 유리에서의 청색 상향전이현상)

  • 류선윤
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.33-43
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    • 2000
  • Up-conversion of rare-earth element added glass is promising area for short wavelength laser source by utilizing high power semiconductor infra-red laser if the efficiency can be increased by proper method. In this study, relatively low phonon energy fluoride glasses were prepared by co-doping rare-earth elements to realize the high efficiency up-convertor. The physical, chemical, andoptical properties of co-doped fluoride glasses were measured. 10 combinations of 5 different rare-earth fluoride elements doped samples were prepared and their transition temperatures, chemical durability, density, hardness, refractive index, absorption, fluorescence, and fluorescence lifetime were measured. 480nm wavelengths blue up-conversion was found in the Yb3+/Tm3+ co-doped glass sample with 800nm laser source and the optimum composition for the most efficient blue up-conversion was found from the glass sample with 0.3 mol% TmF3 and 1 mol% YbF3.

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Low-Temperature Small Polaron Hopping Conduction in Bilayer La1.4(Sr0.2Ca1.4)Mn2O7 Ceramics (이중 층 La1.4(Sr0.2Ca1.4)Mn2O7 세라믹스의 저온에서의 Small Polaron Hopping 전도)

  • Jung, Woo-Hwan
    • Korean Journal of Materials Research
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    • v.18 no.1
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    • pp.26-31
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    • 2008
  • The dc resistivity and thermoelectric power of bilayered perovskite $La_{1.4}(Sr_{0.2}Ca_{1.4})Mn_2O_7$ were measured as a function of the temperature. In the ferromagnetic phase, ${\rho}(T)$ was accurately predicted by $a_0+a_2T^2+a_{4.5}T^{4.5}$ with and without an applied field. At high temperatures, a significant difference between the activation energy deduced from the electrical resistivity and thermoelectric power, a characteristic of small polarons, was observed. All of the experimental data can be feasibly explained on the basis of the small polaron.

Lattice Thermal Conductivity Calculation of Sb2Te3 using Molecular Dynamics Simulations

  • Jeong, Inki;Yoon, Young-Gui
    • Journal of the Korean Physical Society
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    • v.73 no.10
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    • pp.1541-1545
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    • 2018
  • We study lattice thermal conductivity of $Sb_2Te_3$ using molecular dynamics simulations. The interatomic potentials are fitted to reproduce total energy and elastic constants, and phonon properties calculated using the potentials are in reasonable agreement with first-principles calculations and experimental data. Our calculated lattice thermal conductivities of $Sb_2Te_3$ decrease with temperature from 150 K to 500 K. The in-plane lattice thermal conductivity of $Sb_2Te_3$ is higher than cross-plane lattice thermal conductivity of $Sb_2Te_3$, as in the case of $Bi_2Te_3$, which is consistent with the anisotropy of the elastic constants.

A Study of Characteristics of lnxGa1-xP by Photoreflectance measurement (Photoreflectance 측정에 의한 InxGa1-xP의 특성 연구)

  • Kim D. L.;Yu J. I.
    • Laser Solutions
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    • v.8 no.3
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    • pp.5-10
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    • 2005
  • [ $InxGa_{1-x}P/GaAs$ ] structures were grown by chemical beam epitaxy(CBE), Pure phosphine($PH_3$) gases were used as group V sources. for the group III sources, TEGa, TmIn were used. $InxGa_{1-x}P$ epilayer was grown on SI-GaAs substrate and has a 1-${\mu}m$ thick. We have investigated the characteristics of $InxGa_{1-x}P$ by the photoreflectance(PR) spectroscopy, The PR spectrum of $InxGa_{1-x}P$ shows third-derivative feature whose Peaks Provide energy gap. The energy gap of $InxGa_{1-x}P$ has deduced composition x. From temperature dependance of PR spectra, temperature coefficient is $dEg/dT=-3.773{\times}10^{-4}$ eV/K, and Varshni coefficients $\alpha$ and $\beta$ values obtained $4{\times}10^4$ eV/K and 267 K respectively. Also, interaction $\alpha$B was 19.4 meV using the Bose-Einstein temperature relation, and $\Theta$ value related the average phonon frequency were 101.4 K. In particular, shoulder peak related to defects observed in PR signal that measured in temperature 82 K.

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InP crystal growth by modified SSD method (변형된 SSD법에 의한 InP결정 성장)

  • 송복식;정성훈;문동찬;김선태
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.291-297
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    • 1995
  • The InP crystals have been grown by modified synthesis solute diffusion (SSD) method and its properties have been investigated. The crystals have been grown by lowering the crucible quartz for growth in the furnace and crystal growth rate is 1.8mm/day. The lattice constant a. of the grown crystals is 5.867.angs.. Etch pits density along growth direction of crystal changes from 3.0*10.sup 3/cm$\^$-2/ of first freeze part to 6.7*10$\^$4/cm$\^$-2/ of last freeze part and the radial direction of wafer shows nearly uniform distribution. The resistivity and the carrier concentration of the grown crystals are 1.43*10$\^$-1/.ohm.-cm, 7.7*10$\^$15/cm$\^$-3/ at room temperature, respectively. In the photolurninescence at 10K, the radiation transitions are observed by the near band edge recombination, a pair recombination due to Si donor - Zn acceptor and its phonon replica in the InP. The activation energy by Zn diffusion in undoped n-InP crystals is 1.22eV.

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Optical characteristics of p-type ZnO epilayers doped with Sb by metalorganic chemical vapor deposition

  • Kwon, B.J.;Cho, Y.H.;Choi, Y.S.;Park, S.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.122-122
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    • 2010
  • ZnO is a widely investigated material for the blue and ultraviolet solid-state emitters and detectors. It has been promoted due to a wide-band gap semiconductor which has large exciton binding energy of 60 meV, chemical stability and low radiation damage. However, there are many problems to be solved for the growth of p-type ZnO for practical device applications. Many researchers have made an efforts to achieve p-type conductivity using group-V element of N, P, As, and Sb. In this letter, we have studied the optical characteristics of the antimony-doped ZnO (ZnO:Sb) thin films by means of photoluminescence (PL), PL excitation, temperature-dependent PL, and time-resolved PL techniques. We observed donor-to-acceptor-pair transition at about 3.24 eV with its phonon replicas with a periodic spacing of about 72 meV in the PL spectra of antimony-doped ZnO (ZnO:Sb) thin films at 12 K. We also investigate thermal activation energy and carrier recombination lifetime for the samples. Our result reflects that the antimony doping can generate shallow acceptor states, leading to a good p-type conductivity in ZnO.

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Thermal Properties of Two-Layered Materials Composed of Dielectric Layer on Metallic Substrate along the Thickness Direction (금속기판에 유전체 후막을 형성시켜 제조한 2층 층상재료에서 두께 방향의 열전도 특성)

  • Kim, Jong-Gu;Jeong, Ju-Young;Ju, Jae-Hoon;Park, Sang-Hee;Cho, Young-Rae
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.4
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    • pp.87-92
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    • 2016
  • The importance of heat dissipation for the electric device modules along the thickness direction is increasing. Two types of two-layered materials, metal-metal bonding and dielectric-metal bonding, have been fabricated by roll bonding process and a thermal diffusivity of the specimens was measured along the thickness direction. The thermal diffusivity of specimens with metal-metal bonding measured by light flash analysis (LFA) showed a same value independent on the direction of heat flow. However, the thermal diffusivity of specimens with dielectric-metal bonding showed a big difference of 17.5% when the direction of heat flow changed oppositely in the LFA process. The measured thermal diffusivity of specimens when the heat flows from metal to dielectric direction showed smaller value of 17.5% compared to the value when the heat flow from dielectric to metal direction. The difference in thermal diffusivity of specimens with dielectric-metal bonding dependence on direction of heat flow is due to the electron-phonon resistance that occurred transfer process of electron energy to phonon energy near the interface.

A Study on the Temperature dependent Impact ionization for GaAs using the Full Band Monte Carlo Method (풀밴드 몬데카를로 방법을 이용한 GaAs 임팩트이온화의 온도 의존성에 관한 연구)

  • 고석웅;유창관;정학기
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.4 no.3
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    • pp.697-703
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    • 2000
  • As device dimensions are lastly scaled down, impact ionization(I.I.) events are very important to analyze hot carrier transport in high energy region, and the exact model of impact ionization is demanded on device simulation. We calculate full band model by empirical pseudopotential method and the impact ionization rate is derived from modified Keldysh formula. We calculate impact ionization coefficients by full band Monte Carlo simulator to investigate temperature dependent characteristics of impact ionization for GaAs as a function of field. Resultly impact ionization coefficients are in good agreement with experimental values at look. We how energy is increasing along increasing the field, while energy is decreasing along increasing the temperature since the phonon scattering rates for emission mode are very high at high temperature. The logarithmic fitting function of impact ionization coefficients is described as a second orders function of temperature and field. The residuals of the logarithmic fitting function are mostly within 5%. We Dow, therefore, the logarithm of impact ionization coefficients has quadratic dependence on temperature, and we can save time of calculating the temperature dependent impact ionization coefncients as a function of field.

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