• 제목/요약/키워드: Phonon

검색결과 298건 처리시간 0.025초

Growth of ${\gamma}$-Al2O3 (111) on an ultra-thin interfacial Al2O3 layer/NiAl(110)

  • Lee, M.B.;Frederick, B.G;Richardson, N.V.
    • Journal of Korean Vacuum Science & Technology
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    • 제2권2호
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    • pp.63-77
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    • 1998
  • The oxidation of NiAl(110) was investigated in the temperature regime between 300K and 1300 K using LEED (low energy electron diffraction), TPD (temperature programmed desorption) and HREELS (high resolution electron energy loss spectroscopy). The adsorption of N2O and O2 up to reconstructions. Stepwise annealing of the oxygen-saturated sample from 600 K to 1300K in UHV (ultra-high vacuum,) results in firstly the onset of randomly oriented then finally fairly well-ordered. 5 ${\AA}$ Al2O3 film with quasi-hexagonal periodicity. Ordered thicker oxide films of 18-30 ${\AA}$ seem to be grown on this interfacial oxide layer by direct oxidation of sample at elevated temperature between 1150 and 1300 K because of the LEED pattern consisting of new broad hexagonal spots and the previous 5 ${\AA}$ spots. Although the periodicity of surface oxygen arrays shows no significant change from an hexagonal close-packing, the O-O distance changes from ∼3.0 ${\AA}$ film to ∼2.9 ${\AA}$ for thicker oxides. with the appearance of Auger parameter, for the 5${\AA}$ film can be described better as an interfacial oxide layer. The observation of three symmetric phonon peaks can be also a supporting evidence for this phase assignment since thicker oxide films on the Same Ni2Al3(110) show somewhat different phonon structure much closer to that of the ${\gamma}$-Al2O3. The adsorption/desorption of methanol further proves the preparation of less-defective and/or oxygen-terminated Al2O3 films showing ordered phase transitions with the change of oxide thickness between 5 ${\AA}$ to 30 ${\AA}$.

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고출력 백색 광원용 Y3Al5O12;Ce3+,Pr3+ 투명 세라믹 형광체의 광학특성 (Optical Properties of Y3Al5O12;Ce3+,Pr3+ Transparent Ceramic Phosphor for High Power White Lighting)

  • 강태욱;임석규;김종수;정용석
    • 한국재료학회지
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    • 제29권2호
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    • pp.116-120
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    • 2019
  • We prepared $Y_3Al_5O_{12};Ce^{3+},Pr3^{+}$ transparent ceramic phosphor using a solid state reaction method. By XRD pattern analysis and SEM measurement, our phosphors reveal an Ia-3d(230) space group of cubic structure, and the transparent ceramic phosphor has a polycrystal state with some internal cracks and pores. In the Raman scattering measurement with an increasing temperature, lattice vibrations of the transparent ceramic phosphor decrease due to its more perfect crystal structure and symmetry. Thus, low phonon generation is possible at high temperature. Optical properties of the transparent ceramic phosphor have broader excitation spectra due to a large internal reflection. There is a wide emission band from the green to yellow region, and the red color emission between 610 nm and 640 nm is also observed. The red-yellow phosphor optical characteristics enable a high Color Rendering Index (CRI) in combination with blue emitting LED or LD. Due to its good thermal properties of low phonon generation at high temperature and a wide emission range for high CRI characteristics, the transparent ceramic phosphor is shown to be a good candidate for high power solid state white lighting.

Nonlocal bending, vibration and buckling of one-dimensional hexagonal quasicrystal layered nanoplates with imperfect interfaces

  • Haotian Wang;Junhong Guo
    • Structural Engineering and Mechanics
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    • 제89권6호
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    • pp.557-570
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    • 2024
  • Due to interfacial ageing, chemical action and interfacial damage, the interface debonding may appear in the interfaces of composite laminates. Particularly, the laminates display a side-dependent effect at small scale. In this work, a three-dimensional (3D) and anisotropic thick nanoplate model is proposed to investigate the effects of imperfect interface and nonlocal parameter on the bending deformation, vibrational response and buckling stability of one-dimensional (1D) hexagonal quasicrystal (QC) layered nanoplates. By combining the linear spring model with the transferring matrix method, exact solutions of phonon and phason displacements, phonon and phason stresses of bending deformation, the natural frequencies of vibration and the critical buckling loads of 1D hexagonal QC layered nanoplates are derived with imperfect interfaces and nonlocal effects. Numerical examples are illustrated to demonstrate the effects of the imperfect interface parameter, aspect ratio, thickness, nonlocal parameter, and stacking sequence on the bending deformation, the vibrational response and the critical buckling load of 1D hexagonal QC layered nanoplate. The results indicate that both the interface debonding and nonlocal effect can reduce the stiffness and stability of layered nanoplates. Increasing thickness of QC coatings can enhance the stability of sandwich nanoplates with the perfect interfaces, while it can reduce first and then enhance the stability of sandwich nanoplates with the imperfect interfaces. The biaxial compression easily results in an instability of the QC layered nanoplates compared to uniaxial compression. QC material is suitable for surface layers in layered structures. The mechanical behavior of QC layered nanoplates can be optimized by imposing imperfect interfaces and controlling the stacking sequence artificially. The present solutions are helpful for the various numerical methods, thin nanoplate theories and the optimal design of QC nano-composites in engineering practice with interfacial debonding.

Nanopatterned Surface Effect on the Epitaxial growth of InGaN/GaN Multi-quantum Well Light Emitting Diode Structure

  • Kim, Keun-Joo
    • Transactions on Electrical and Electronic Materials
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    • 제10권2호
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    • pp.40-43
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    • 2009
  • The authors fabricated a nanopatterned surface on a GaN thin film deposited on a sapphire substrate and used that as an epitaxial wafer on which to grow an InGaN/GaN multi-quantum well structure with metal-organic chemical vapor deposition. The deposited GaN epitaxial surface has a two-dimensional photonic crystal structure with a hexagonal lattice of 230 nm. The grown structure on the nano-surface shows a Raman shift of the transverse optical phonon mode to $569.5\;cm^{-1}$, which implies a compressive stress of 0.5 GPa. However, the regrown thin film without the nano-surface shows a free standing mode of $567.6\;cm^{-1}$, implying no stress. The nanohole surface better preserves the strain energy for pseudo-morphic crystal growth than does a flat plane.

Commissioning of neutron triple-axis spectrometers at HANARO

  • Hiraka, Haruhiro;Lee, Jisung;Jeon, Byoungil;Seong, Baek-Seok;Cho, Sangjin
    • Nuclear Engineering and Technology
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    • 제52권9호
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    • pp.2138-2150
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    • 2020
  • We report the status of the cold neutron triple-axis spectrometer (Cold TAS) and thermal neutron triple-axis spectrometer (Thermal TAS) installed at HANARO. Cold TAS, whose specifications are standard across the world, is in the final phase of commissioning. Proper instrument operation was confirmed through a feasibility study of phonon measurements and data analyses with resolution convolution. In contrast, Thermal TAS is in the initial phase of commissioning, and improvement of the monochromator drum is now in progress from the viewpoint of radiation shielding. In addition, we report recent activities in the development of neutron basic elements, that is, film-coated Si-wafer collimators, which are promising for use in triple-axis spectroscopy, particularly in Cold TAS.

The magnetic properties of optical Quantum transitions of electron-piezoelectric potential interacting systems in CdS and ZnO

  • Lee, Su Ho
    • 전기전자학회논문지
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    • 제22권1호
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    • pp.61-67
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    • 2018
  • We investigated theoretically the magnetic field dependence of the quantum optical transition of qusi 2-Dimensional Landau splitting system, in CdS and ZnO. In this study, we investigate electron confinement by square well confinement potential in magnetic field system using quantum transport theory(QTR). In this study, theoretical formulas for numerical analysis are derived using Liouville equation method and Equilibrium Average Projection Scheme (EAPS). In this study, the absorption power, P (B), and the Quantum Transition Line Widths (QTLWS) of the magnetic field in CdS and ZnO can be deduced from the numerical analysis of the theoretical equations, and the optical quantum transition line shape (QTLS) is found to increase. We also found that QTLW, ${\gamma}(B)_{total}$ of CdS < ${\gamma}(B)_{total}$ of ZnO in the magnetic field region B<25 Tesla.

Ultrafast probes of coherent oscillations in Fe-based superconductors

  • Kim, K.W.
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권1호
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    • pp.1-4
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    • 2017
  • Forefront ultrafast experimental techniques have recently proven their potential as new approaches to understand materials based on non-equilibrium dynamics in the time domain. The time domain approach is useful especially in disentangling complicated coupling among charge, spin and lattice degrees of freedom. Various ultrafast experiments on Fe-based superconductors have observed strong coherent oscillations of an $A_{1g}$ phonon mode of arsenic ions, which shows strong coupling to the electronic and magnetic states. This paper reviews the recent reports of ultrafast studies on Fe-based superconductor with a focus on the coherent oscillations. Experimental results with ultrashort light sources from the terahertz-infrared pulses to the hard X-rays from a free electron laser will be presented.

광전소자의 기술동향 (Technology trend of optoelectronic device)

  • 라용춘;조장연;박대희
    • E2M - 전기 전자와 첨단 소재
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    • 제7권6호
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    • pp.549-556
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    • 1994
  • 광전변화소자(Photo electric conversion device)는 광전효과-내부 광전효과(광도전 및 광기전력) 및 외부광전효과(광전자방출)을 이용하여 광을 전기신호로 변화시키는 소자를 광전자소자라 하며, 광전자 및 양자전자공학의 발전과 함께 많은 개발이 되고 있다. 이 광전변환소자는 주로서 고체박막의 재료를 이용하며, 소자의 소형화, 고성능화, 고신뢰성등의 요구와 함께 광전기술연구가 활발하게 진행되고 있다. 현재 광전소자의 광의 파장은 가시부만이 아니고, X선으로 부터 적외선까지에 걸쳐 있다. 이 파장에 대응하여 각종의 단결정이 필요하고, 소자의 설계가 요구된다. 이들의 응용은 소자의 광의 발진, 증폭, 검출의 소자만이 아니고 변조, 편향, 기록, 전달로등 다종다양의 기능을 갖는 소자가 요구되고 있다. 이들의 Optoelectronic Device의 연구가 활발하게 진행되어 새로운 광전소자의 제품이 개발되고 있어, 이에 대한 소개를 하고져 한다.

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Spectroscopic effects of negative and positive stresses on the transition metal-ion activated sapphire fibers

  • Lim, Ki-Soo
    • 한국광학회:학술대회논문집
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    • 한국광학회 1990년도 제5회 파동 및 레이저 학술발표회 5th Conference on Waves and lasers 논문집 - 한국광학회
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    • pp.115-120
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    • 1990
  • The spectroscopic properties of Cr3+-doped sapphire and Ti3+-doped sapphire fibers are reported. Tensile stress produces blue shifts of the R lines and changes in their radiative lifetimes and integrated intensities which can be correlated to stress-induced changes of the crystal-field parameters in a Cr3+-doped sapphire fiber. A net red shift of the zero phonon fluorescence line of 2Eg state and a decrease of the splittings of 2T2g state with uniaxial stress are observed in a Ti3+-doped sapphire. In excitation spectra the two peaks from the 2Eg state are shifted to the blue with different rates. The changes are attributed to the stress-induced changes of crystal field and Jahn-Teller effect.

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정공과 격자의 온도를 고려한 새로운 정공 이동도 모델 (New hole mobility model including hole and lattice)

  • 김중식;김진양;김찬호;신형순;박영준;민홍식
    • 전자공학회논문지D
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    • 제35D권8호
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    • pp.31-37
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    • 1998
  • A new self-consistent hole mobility model that includes lattice and hole temeprature has been proposed. By including the lattice and hole temperatures as well as the effective transverse field and the interface fixed charge, the model predicted the saturation of hole drift velocity and showed the effects of coulomb scattering, surface phonon scattering, and surface roughness scattering. The calculated data by the model were compared with the reported experimental data and they were shown to agree quite well. The new model is expected to estimate the characteristics of very short channel devices in the in the hydrodynamic model simulation.

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