• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.141-142
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• 2019

As part of the recent low-energy policy, insulation standards for buildings are increasing every year. In addition, the conventional styrofoam heat insulation material has a problem in that the thickness of the heat insulation material to achieve the standard heat transmission rate is rapidly increased. Although the risk of spreading the structure vulnerable to fire due to insufficient spacing between buildings due to thickened insulation is increasing, the high cost of high efficiency insulation is difficult to solve. On the other hand, it is known that the method to be used as a formwork using insulation is excellent in cost reduction effect by reducing the amount of formwork used and simplifying the subsequent insulation work. The purpose of this study is to evaluate the strength characteristics of multi - layered insulation materials with appropriate strength by reducing the thickness of the insulation by appropriately combining high performance phenolic foam insulation and styrofoam insulation.

• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3177-3183
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• 2012

The carbon nanofibers (CNFs) used in this study were synthesized with an iron catalyst and ethylene as a carbon source. A concentration of 30 wt % iron(III) acetylacetonate was dissolved in resol type phenol resin and polyurethane foam was put into the solution. The sample was calendered after being cured at $80^{\circ}C$ in air for 24 h. Stabilization and carbonization of the resol type phenol resin and reduction of the $Fe^{3+}$ were completed in a high-temperature furnace by the following steps: 1) heating to $600^{\circ}C$ at a rate of $10^{\circ}C/min$ with a mixture of $H_2/N_2$ for 4 h to reduce the $Fe^{3+}$ to Fe; 2) heating to $1000^{\circ}C$ in $N_2$ at a rate $10^{\circ}C/min$ for 30 minutes for pyrolysis; 3) synthesizing CNFs in a mixture of 20.1% ethylene and $H_2/N_2$ at $700^{\circ}C$ for 2 h using a CVD process. Finally, the structural characterization of the CNFs was performed by scanning electron microscopy and a synthesis analysis was carried out using energy dispersive spectroscopy and X-ray photoelectron spectroscopy. Specific surface area analysis of the CNFs was also performed by $N_2$-sorption.

• Applied Chemistry for Engineering
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• v.22 no.1
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• pp.37-44
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• 2011

The critical micelle concentration (CMC) of sorbitan laurate SP 20 surfactant in this paper was near $7.216{\times}10^{-4}mol/L$ and the surface tension at CMC was about 26.0 mN/m, which showed higher CMC and lower surface tension than those of octylphenol ethoxylate octylphenol ethoxylate (OPE) 10 surfactant. Dynamic surface tension measurement using a maximum bubble pressure tensiometer showed that the adsorption rate at the interface between air and surfactant solution was found to be slower with SP 20 surfactant, presumably due to a low mobility of SP 20 surfactant monomer. The contact angle of SP 20 surfactant solution was observed to decrease with an increase in surfactant concentration and showed a larger value than that of OPE 10 surfactant solution. Half-life time for foams generated with 1 wt% surfactant solution was also larger with SP 20 surfactant, which indicated higher foam stability with SP 20 surfactant. Dynamic behavior study reveals that the solubilization of n-decane oil was much lower with SP 20, which is in good agreement with experimental results of foam stability, contact angle and CMC. Dynamic interfacial tension measurement by a spinning drop tensiometer shows that interfacial tensions at equilibrium condition in both systems were almost the same but the time required to reach equilibrium was longer with SP 20.

• Journal of Powder Materials
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• v.26 no.6
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• pp.502-507
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• 2019

Macro-porous carbon foams are fabricated using cured spherical phenolic resin particles as a matrix and furfuryl alcohol as a binder through a simple casting molding. Different sizes of the phenolic resin particles from 100-450 ㎛ are used to control the pore size and structure. Ethylene glycol is additionally added as a pore-forming agent and oxalic acid is used as an initiator for polymerization of furfuryl alcohol. The polymerization is performed in two steps; at 80℃ and 200℃ in an ambient atmosphere. The carbonization of the cured body is performed under Nitrogen gas flow (0.8 L/min) at 800℃ for 1 h. Shrinkage rate and residual carbon content are measured by size and weight change after carbonization. The pore structures are observed by both electron and optical microscope and compared with the porosity results achieved by the Archimedes method. The porosity is similar regardless of the size of the phenolic resin particles. On the other hand, the pore size increases in proportion to the phenol resin size, which indicates that the pore structure can be controlled by changing the raw material particle size.

• Journal of the Korea Institute of Building Construction
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• v.18 no.6
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• pp.559-567
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• 2018

In the case of fire, surface treatment agents used in external insulation finishing methods are substances that are vulnerable to fire due to thin finishes and the combustion of polymers. In this study, it was expected that the performance of surface preparation mortars could be improved by using expandable graphite with excellent thermal performance. Experimental results showed that the mechanical properties of surface preparation mortar were improved by using the fly ash and silica fume. Surface treatment materials using expanded graphite have a characteristic of expanding when a fire occurs. It has been shown that heat-swellable surface treatment materials can reduce the penetration of heat sources into the surface of synthetic insulation.

• Journal of the Korean Wood Science and Technology
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• v.45 no.3
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• pp.360-367
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• 2017

This study was carried out to compare the characteristics of low density fiberboards (LDFs) manufactured with different adhesive types such as melamine urea formaldehyde (MUF), phenol formalehyde (PF), emulsified MDI (eMDI) and latexes resins. As results, hard LDFs were successfully manufactured by MUF, PF and eMDI resins. Thermal conductivities of all LDFs were significantly lower than commercial medium density fiberboard. Especially, all LDFs showed comparable thermal insulation performance with extruded polystyrene foam (XPS). LDF manufactured with eMDI resins showed the highest physical properties such as thickness/length swelling by water absorption and bending strength.

• Journal of the Korean Recycled Construction Resources Institute
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• v.7 no.4
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• pp.395-404
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• 2019

In the case of fire, surface treatment agents used in external insulation finishing methods are substances that are vulnerable to fire due to thin finishes and the combustion of polymers. In this study, it was expected that the performance of surface preparation mortars could be improved by using expandable graphite with excellent thermal performance. Experimental results showed that the mechanical properties of surf ace preparation mortar were improved by using the fly ash and silica fume. Surface treatment materials using expanded graphite have a characteristic of expanding when a fire occurs. It has been shown that heat-swellable surface treatment materials can reduce the penetration of heat sources into the surface of synthetic insulation.