• Title/Summary/Keyword: Phase stability

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The Thermal Stability and Elevated Temperature Mechanical Properties of Spray-Deposited $SiC_P$/Al-11.7Fe-1.3V-1.7Si Composite

  • Hao, L.;He, Y.Q.;Wang, Na;Chen, Z.H.;Chen, Z.G.;Yan, H.G.;Xu, Z.K.
    • Advanced Composite Materials
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    • v.18 no.4
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    • pp.351-364
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    • 2009
  • The thermal stability and elevated temperature mechanical properties of $SiC_P$/Al-11.7Fe-1.3V-1.7Si (Al-11.7Fe-1.3V-1.7Si reinforced with SiC particulates) composites sheets prepared by spray deposition (SD) $\rightarrow$ hot pressing $\rightarrow$ rolling process were investigated. The experimental results showed that the composite possessed high ${\sigma}_b$ (elevated temperature tensile strength), for instance, ${\sigma}_b$ was 315.8 MPa, which was tested at $315^{\circ}C$, meanwhile the figure was 232.6 MPa tested at $400^{\circ}C$, and the elongations were 2.5% and 1.4%, respectively. Furthermore, the composite sheets exhibited excellent thermal stability: the hardness showed no significant decline after annealing at $550^{\circ}C$ for 200 h or at $600^{\circ}C$ for 10 h. The good elevated temperature mechanical properties and excellent thermal stability should mainly be attributed to the formation of spherical ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase particulates in the aluminum matrix. Furthermore, the addition of SiC particles into the alloy is another important factor, which the following properties are responsible for. The resultant Si of the reaction between Al matrix and SiC particles diffused into Al matrix can stabilize ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase; in addition, the interface (Si layer) improved the wettability of Al/$SiC_P$, hence, elevated the bonding between them. Furthermore, the fine $Al_4C_3$ phase also strengthened the matrix as a dispersion-strengthened phase. Meanwhile, load is transferred from Al matrix to SiC particles, which increased the cooling rate of the melt droplets and improved the solution strengthening and dispersion strengthening.

Effect of Concentration of Trioctylphosphine Oxide and Thenoyltrifluoroacetone on the Preparation and Stability of Colloidal Liquid Aphrons (Trioctylphosphine Oxide와 Thenoyltrifluoroacetone의 농도가 콜로이드 액상 에이프런의 제조와 안정성에 미치는 영향)

  • Yeo, Kil Hwan;Jeon, Sang Jun;Hong, Won Hi;Lee, Hong Ki
    • Clean Technology
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    • v.12 no.1
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    • pp.45-51
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    • 2006
  • Colloidal Liquid Aphrons(CLAs) were prepared from different solvents such as nonpolar hydrocarbons, alcohols, and amines. Water-soluble surfactant and oil-soluble surfactant were used in this study. The effect of PVR (phase volume ratio) and concentration of extractant on the stability of CLA was investigated. The stability of CLA was affected by PVR. As PVR was increased, the stability of CLA was decreased.

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Stability of concentrated Colloidal Liquid Aphrons containing a quaternary ammonium salt in the continuous phase (사차 암모늄 염을 함유하는 농축된 콜로이드 액상 에이프런의 연속상에서의 안정성)

  • Hahm, Hyung Chul;Hong, Won Hi;Lee, Choul Ho
    • Clean Technology
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    • v.7 no.4
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    • pp.291-297
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    • 2001
  • In this study, the stability of concentrated colloidal liquid aphrons (CLAs) containing Aliquat 336 was measured. CLAs in the continuous phase are stabilized by water-soluble surfactant and oil-soluble surfactant. To compare the stability of CLAs, half-life was introduced. According to the change of state of solution, the rate of break-up of concentrated CLAs changed rigorously at critical coagulation concentration. Critical coagulation concentration was measured with changing pH. The effects of ionic strength and concentration of Sodium Dodecyl Benzene Sulfonate (SDBS) on the stability of concentrated CLAs in the continuous phase were also investigated.

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Heterogeneity-aware Energy-efficient Clustering (HEC) Technique for WSNs

  • Sharma, Sukhwinder;Bansal, Rakesh Kumar;Bansal, Savina
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.11 no.4
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    • pp.1866-1888
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    • 2017
  • Efficient energy consumption in WSN is one of the key design issues for improving network stability period. In this paper, we propose a new Heterogeneity-aware Energy-efficient Clustering (HEC) technique which considers two types of heterogeneity - network lifetime and of sensor nodes. Selection of cluster head nodes is done based on the three network lifetime phases: only advanced nodes are allowed to become cluster heads in the initial phase; in the second active phase all nodes are allowed to participate in cluster head selection process with equal probability, and in the last dying out phase, clustering is relaxed by allowing direct transmission. Simulation-based performance analysis of the proposed technique as compared to other relevant techniques shows that HEC achieves longer stable region, improved throughput, and better energy dissipation owing to judicious consumption of additional energy of advanced nodes. On an average, the improvement observed for stability period over LEACH, SEP, FAIR and HEC- with SEP protocols is around 65%, 30%, 15% and 17% respectively. Further, the scalability of proposed technique is tested by varying the field size and number of sensing nodes. The results obtained are found to be quite optimistic. The impact of energy heterogeneity has also been assessed and it is found to improve the stability period though only upto a certain extent.

A simplified phase diagram in the ternary system $Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ ($Y_2O_3-Ta(Nb)_2O_5-ZrO_2$ 삼성분계 상태도)

  • 이득용;김대준;장주웅;이명현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.3
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    • pp.377-383
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    • 1997
  • Yttria-stabilized TZP alloyed with pentavalent oxides $(Ta_2O_5,\;Nb_2O_5)$ were fabricated by the conventional sintering method at $1500^{\circ}C$ in air to construct the simplified ternary phase diagram. The phase stability of tetragonal -$ZrO_2$ from the quasi-binary system $ZrO_2-YTa(Nb)O_4$, which do not transform to monoclinic-$ZrO_2$ even for a wide range of grain size and annealing temperature, was investigated to determine composition region of the non-transformable $t-ZrO_2$ solid solution$(NT_{ss})$. Phase stability of $NT_{ss}$ was probably due to the enhanced stability of $_YTa(Nb)O4$ having the tetragonal fergusonite structure. It was experimentally found that mixtures having $NT_{ss}$ alloyed with $T_{ss}$ by weight%% showed both excellent phase stability of $t-ZrO_2$ and fracture toughness even though the calculated composition of the mixture /was located outside $NT_{ss}$ composition region.

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Low-temperature phase stability and mechanical properties of $Y-Nb-TZP/Al_2O_3$ compoites ($Y-Nb-TZP/Al_2O_3$ 복합체의 저온 상안정성 및 기계적 특성)

  • 이득용;김대준;조경식;장주웅
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.634-639
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    • 1998
  • $Y_2O_3$ and $Nb_2O_5$ co-doped zirconia composites containing 10~30 vol% $Al_2O_3$ with two different particle sizes were sintered for 5 h at $1550^{\circ}C$ to evaluate low-temperature phase stability of the composite using X-ray diffractometry after heat-treatments for 1000 h at $250^{\circ}C$ in air or for 5 h at $180^{\circ}C$ in 0.3 MPa $H_2O$ vapor pressure. No tetragonal to monoclinic phase transformation during degradation, so called enhanced low-temperature phase stability, was observed for all composites. It is concluded that Nb addition to the composite for the phase stability is more effective than $Al_2O_3$ addition. The optimum combination of strength (670 MPa) and fracture toughness ($7.1{\textrm} {MPam}^{1/2}$) were obtained for the composite containing 20 vol% of $Al_2O_3$ with 2.8 $\mu$m to 0.2 $\mu$m, the flexural strength increases but the fracture toughness decreases.

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Phase Stability of Laser-ablated $SmBa_2Cu_3O_{7-y}$ thin Films Investigated by Raman Scattering Spectroscopy

  • Kim, G.;Jeong, A.R.;Jo, W.;Park, D.Y.;Cheong, H.;Tsukada, A.;Hammond, R.H.;Beasley, M.R.
    • Progress in Superconductivity
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    • v.11 no.2
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    • pp.141-146
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    • 2010
  • Phase stability diagram and boundary of a- and c-axis orientation of $SmBa_2Cu_3O_{7-y}$ (SmBCO) thin films grown by pulsed laser deposition (PLD) were reported with studies based on x-ray diffraction [1]. Four different samples are systematically analyzed: normal c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$, a-axis oriented $SmBa_2Cu_3O_{7-y}$, c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ with $Sm_2BaCuO_5$ phase, and a mixture with c-axis oriented orthorhombic $SmBa_2Cu_3O_{7-y}$ and anomalously long-c tetragonal $SmBa_2Cu_3O_x$. Raman scattering spectroscopy equipped with polarization analysis elucidates the crystal orientation and the origin of the growth of the materials. It indicates that the technique can be used for quality control of conductor manufacturing processes as well as for enhancement of the materials properties.

A Study on the Thermal Stability of Duplex High Mn-Steel Structure (고 망간강 2상 혼합조직의 열적 안정성에 관한 연구)

  • Wey, Myeong Yong
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.1
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    • pp.13-22
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    • 1992
  • The thermal stability of duplex high Mn-steel structure have been investigated using 15%Mn~1.0~2.4%C steels which are composed of ${\gamma}$-and ${\theta}$-phases in the range of temperature from 900 to $1100^{\circ}C$, and time from 50 to 300h. The results are as follows ; 1) The grain growth in single-phase region proceeds by grain boundary migration and the relation between mean radius $\bar{r}$ and annealing time t is described as follows ; $\bar{r}^2-{\bar{r}_0}^2=k_0{\cdot}t$ 2) The grain growth of duplex, (${\gamma}+{\theta}$), strucrure is slower than that single phase because the chemical composition of ${\gamma}$-and ${\theta}$-phases differs esch others. 3) The grain of (${\gamma}+{\theta}$) duplex structure grow slowly in a mode of Ostwald ripening. Because grain boundaries of ${\gamma}$-phase migrate under a restriction of pinning by ${\theta}$-phases. 4) In the duplex structures. the dispersed structures change to the dual-structures, as the volume fraction of the dispersed second-phase increase. Consequently, the growth-law, which is controlled by boundary-diffusion change to that of the volume diffusion-mechanism.

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Design and Stability Analysis of a Fuzzy Adaptive SMC System for Three-Phase UPS Inverter

  • Naheem, Khawar;Choi, Young-Sik;Mwasilu, Francis;Choi, Han Ho;Jung, Jin-Woo
    • Journal of Power Electronics
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    • v.14 no.4
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    • pp.704-711
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    • 2014
  • This paper proposes a combined fuzzy adaptive sliding-mode voltage controller (FASVC) for a three-phase UPS inverter. The proposed FASVC encapsulates two control terms: a fuzzy adaptive compensation control term, which solves the problem of parameter uncertainties, and a sliding-mode feedback control term, which stabilizes the error dynamics of the system. To extract precise load current information, the proposed method uses a conventional load current observer instead of current sensors. In addition, the stability of the proposed control scheme is fully guaranteed by using the Lyapunov stability theory. It is shown that the proposed FASVC can attain excellent voltage regulation features such as a fast dynamic response, low total harmonic distortion (THD), and a small steady-state error under sudden load disturbances, nonlinear loads, and unbalanced loads in the existence of the parameter uncertainties. Finally, experimental results are obtained from a prototype 1 kVA three-phase UPS inverter system via a TMS320F28335 DSP. A comparison of these results with those obtained from a conventional sliding-mode controller (SMC) confirms the superior transient and steady-state performances of the proposed control technique.

High-Pass-Filter-Based Virtual Impedance Control for LCL-filtered Inverters Under Weak Grid

  • Wang, Jiangfeng;Xing, Yan;Zhang, Li;Hu, Haibing;Yang, Tianyu;Lu, Daorong
    • Journal of Power Electronics
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    • v.18 no.6
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    • pp.1780-1790
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    • 2018
  • Voltage feed-forward control (VFFC) is widely used in LCL-type grid-tied inverters due to its advantages in terms of disturbance rejection performance and fast dynamic response. However, VFFC may worsen the stability of inverters under weak grid conditions. It is revealed in this paper that a large phase-lag in the low-frequency range is introduced by VFFC, which reduces the phase margin significantly and leads to instability. To address this problem, a novel virtual-impedance-based control, where a phase-lead is introduced into the low-frequency area to compensate for the phase lag caused by VFFC, is proposed to improve system stability. The proposed control is realized with a high-pass filter, without high-order-derivative components. It features easy implementation and good noise immunity. A detailed design procedure for the virtual impedance control is presented. Both theoretical analysis and experimental results verify the effectiveness of the control proposed.