• 제목/요약/키워드: Phase stability

검색결과 1,985건 처리시간 0.026초

이중 페로브스카이트 촉매 PrBaMn2O5+δ의 고온전기분해조(Solid Oxide Electrolysis Cell) 연료극 촉매로 적용 가능성에 대한 연구 (Study on Possibility of PrBaMn2O5+δ as Fuel Electrode Material of Solid Oxide Electrolysis Cell)

  • 권영진;김동연;배중면
    • 한국군사과학기술학회지
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    • 제20권4호
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    • pp.491-496
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    • 2017
  • The hydrogen($H_2$) is promising energy carrier of renewable energy in the microgrid system such as small village and military base due to its high energy density, pure emission and convenient transportation. $H_2$ can be generated by photocatalytic water splitting, gasification of biomass and water electrolysis driven by solar cell or wind turbine. Solid oxide electrolysis cells(SOECs) are the most efficient way to mass production due to high operating temperature improving the electrode kinetics and reducing the electrolyte resistance. The SOECs are consist of nickel-yttria stabilized zirconia(NiO-YSZ) fuel electrode / YSZ electrolyte / lanthanum strontium manganite-YSZ(LSM-YSZ) air electrode due to similarity to Solid Oxide Fuel Cells(SOFCs). The Ni-YSZ most widely used fuel electrode shows several problems at SOEC mode such as degradation of the fuel electrode because of Ni particle's redox reaction and agglomeration. Therefore Ni-YSZ need to be replaced to an alternative fuel electrode material. In this study, We studied on the Double perovskite $PrBrMnO_{5+{\delta}}$(PBMO) due to its high electric conductivity, catalytic activity and electrochemical stability. PBMO was impregnated into the scaffold electrolyte $La_{0.8}Sr_{0.2}Ga_{0.85}Mg_{0.15}O_{3-{\delta}}$(LSGM) to be synthesized at low temperature for avoiding secondary phase generated when it exposed to high temperature. The Half cell test was conducted at SOECs and SOFCs modes.

PMS 시스템을 활용한 전력제어에 관한 연구 (A Study on Power Control using PMS)

  • 김성철;김경욱;우천희
    • 전기학회논문지P
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    • 제65권3호
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    • pp.194-198
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    • 2016
  • The electric power industry have recently been building out Smart Grids, a two-way electricity grid that connects power consumers and producers to a network that enables one to respond quickly to any eventuality. The construction of a two-way electricity grid means that the power control process becomes unified, from what used to be separate processes that originate individually from the consumption phase and the production and supply phases. The role of power control that takes place within each section of the power system may be independent. However, this does not mean the independent control sections are operated individually, but are configured to meet a single target and purpose. Each control section possesses enough degree of independency to respond to eventualities that may occur within different stages of the power system, but at the same time, possesses unified system elements for the stability of the entire power system. From this perspective, Smart Grids are widely regarded as the most rational power industry operation plan. A variety of different control and communication systems can be applied for an effective deployment of Smart Grids. Recently, we have seen systems such as PMS(Power Management System) and PAS(Process Automation System) applied in the deployment of Smart Grids, which are developed from the techniques utilized in the industry. The PMS is attracting particular attention for its power operations management ability. In this study, we propose plans for improvement in the rational development of power system controls through case studies of live PMS operations.

나노결정 InGaZnO 산화물 박막트랜지스터와 비결정 InGaZnO 산화물 박막트랜지스터의 소자 신뢰성에 관한 비교 연구 (Comparison of Stability on the Nano-crystalline Embedded InGaZnO and Amorphous InGaZnO Oxide Thin-film Transistors)

  • 신현수;안병두;임유승;김현재
    • 한국전기전자재료학회논문지
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    • 제24권6호
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    • pp.473-479
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    • 2011
  • In this paper, we have compared amorphous InGaZnO (a-IGZO) thin-film transistor (TFT) with the nano-crystalline embedded-IGZO ($N_c$-embedded-IGZO) TFT fabricated by solid-phase crystallization (SPC) technique. The field effect mobility (${\mu}_{FE}$) of $N_c$-embedded-IGZO TFT was 2.37 $cm^2/Vs$ and the subthreshold slope (S-factor) was 0.83 V/decade, which showed lower performance than those of a-IGZO TFT (${\mu}_{FE}$ of a-IGZO was 9.67 $cm^2/Vs$ and S-factor was 0.19 V/decade). This results originated from generation of oxygen vacancies in oxide semiconductor and interface between gate insulator and semiconductor due to high temperature annealing process. However, the threshold voltage shift (${\Delta}V_{TH}$) of $N_c$-embedded-IGZO TFT was 0.5 V, which showed 1 V less shift than that of a-IGZO TFT under constant current stress during $10^5$ s. This was because there were additionally less increase of interface trap charges in Nc-embedded-IGZO TFT than a-IGZO TFT.

보행 시 지지 기반 급변에 대한 하지 근신경의 반응 (Leg Muscle Activity from the Perturbation of the Support during Gait)

  • 신인식;천영진;서정석;최치선;남기정
    • 한국운동역학회지
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    • 제17권3호
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    • pp.147-154
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    • 2007
  • This study's purpose is to investigate the effects on leg muscle activity caused by perturbation, using a trapdoor system during the support phase of gait for healthy adults (n = 6, height $177.5{\pm}5.5cm$, weight $81.0{\pm}9.5kg$, age $30.0{\pm}3.3yrs$). The trapdoor had the functional ability of causing inversion or eversion. The release time for the trapdoor was specified for two times, 0.3 and 0.5 seconds after heel contact. While altering these variables, EMG was recorded for the leg muscles (rectus femoris, biceps femoris, vastus lateralis, tibialis anterior, gastrocnemius, soleus). The following conclusions were derived. The steptime was longer for the 0.5s eversion than 0.3s inversion condition. So in order to regain stability after the perturbation the unsupporting leg reached forward rapidly. This quick reflex can be observed through the center of pressure (COP) and its rapid change in direction. The gastrocnemius was activated throughout the total experiment. There was a low amount of activity recorded in the rectus femoris, vastus lateralis and tibialis anterior except for the condition of inversion 0.3s. For most of the conditions, the highest average EMG peak values were recorded during the condition of inversion 0.3s. The iEMG patterns were similar for the conditions of inversion 0.3s and eversion 0.3s. To cope with the rapid change in these conditions, the biceps femoris was activated. During the experiment except for the condition of normal gait, the activity of the soleus and gastrocnemius was relatively high. Therefore, to prevent injury from perturbation of the lower leg strengthening of the soleus and gastrocnemius is required. Likewise to prevent injury to the thigh strengthening for the biceps femoris.

초음파가 조사되는 용융 혼합에 의한 폴리카보네이트/스티렌-아크릴로니트릴 혼합물의 상용화 (Compatibilization of PC/SAN Blends via Ultrasound-irradiated Melt Mixing)

  • 김형수
    • 폴리머
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    • 제28권3호
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    • pp.225-231
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    • 2004
  • 폴리 카보네이트와 스티렌-아크릴로니트릴 공중합체, 그리고 이들의 혼합물이 혼합기에서 용융 가공되는 동안 고강도 초음파를 조사하였다. 순수한 고분자의 경우에 용융상태에서 가해진 초음파 에너지에 의하여 용융점도가 감소되었으며, 혼합물에서는 분산상의 크기가 감소하는 것으로 확인되었다. 초음파 조사에 따른 성분 고분자의 용융점도 저하는 가공 중에 거대 라디칼이 생성된 것과 관련이 있으며, 이들의 상호 결합으로 말미암아 폴리 카보네이트/스티렌-아크릴로니트릴 혼합물의 상용화가 진행됨을 알 수 있었다. 전체적인 상용화의 효과는 혼합물의 형태학과 기계적 성질을 측정함으로 평가하였다. 총 조사 시간 5분 중에서 약 3분을 전후하여 분산상의 크기가 현저하게 감소하였고 혼합이 끝난 시료를 20$0^{\circ}C$에서 약 10분간 방치한 후의 형태학은 초음파로 처리된 경우에 매우 안정한 상 구조를 유지하였다. 아울러 파단 신율과 인장강도와 같은 기계적 성질이 현저하게 향상되는 결과를 바탕으로, 고강도 초음파를 이용한 용융 혼합은 별도의 상용화제의 투입 없이 비상용계 고분자 혼합물을 상용화할 수 있는 효과적인 방법으로 판단되었다.

The Characterization of V Based Self-Forming Barriers on Low-k Samples with or Without UV Curing Treatment

  • 박재형;한동석;강유진;신소라;박종완
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
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    • pp.214.2-214.2
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    • 2013
  • Device performance for the 45 and 32 nm node CMOS technology requires the integration of ultralow-k materials. To lower the dielectric constant for PECVD and spin-on materials, partial replacement of the solid network with air (k=1.01) appears to be more intuitive and direct option. This can be achieved introducting of second "labile" phase during depositoin that is removed during a subsequent UV curing and annealing step. Besides, with shrinking line dimensions the resistivity of barrier films cannot meet the International Technology Roadmap for Semiconductors (ITRS) requirements. To solve this issue self-forming diffusion barriers have drawn attention for great potential technique in meeting all ITRS requirments. In this present work, we report a Cu-V alloy as a materials for the self-forming barrier process. And we investigated diffusion barrier properties of self-formed layer on low-k dielectrics with or without UV curing treatment. Cu alloy films were directly deposited onto low-k dielectrics by co-sputtering, followed by annealing at various temperatures. X-ray diffraction revealed Cu (111), Cu (200) and Cu (220) peaks for both of Cu alloys. The self-formed layers were investigated by transmission electron microscopy. In order to compare barrier properties between V-based interlayer on low-k dielectric with UV curing and interlayer on low-k dielectric without UV curing, thermal stability was measured with various heat treatment temperature. X-ray photoelectron spectroscopy analysis showed that chemical compositions of self-formed layer. The compositions of the V based self-formed barriers after annealing were strongly dominated by the O concentration in the dielectric layers.

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MH전지용 $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves합금의 결정구조 (Crystal Structure of $\textrm{ZrV}_{x}\textrm{Mn}_{1-x-y}\textrm{Ni}_{1+y}$ Laves Phase Alloys for MH Battery Application)

  • 김원백;서창열;최국선;김인곤
    • 한국재료학회지
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    • 제7권3호
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    • pp.234-243
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    • 1997
  • 아크용해로와 진공유도로를 사용하여 니켈-수소 전지의 음극용으로 주목받고 있는 AB2 타입의 ZrV /sub x/Mn/sub 1-x/Ni/sub 1.0/, ZrV/sub x/Mn/sub 0.8-x/Ni/sub 1.2/, ZrV/sub x/Mn/sub 0.6-x/Ni/sub 1.4/합금을 용해하였다. 이들 합금은 용해한 상태에서 C14과 C15의 혼합상을 갖는 것으로 나타났으며 합금조성 및 열처리에 따라 혼합상분율이 크게 변화하였다. 이들의 결정상 및 상분율은 합금원소들의 평균원자반경비(r/sub A//r/sub B)에 따라 결정되는 것으로 밝혀졌으며 특히 열처리한 합금의 경우에는 평균원자반경비가 1.254일때를 경계로 하여 두 상의 명확간 안정구역이 설정되었다. 가압한 분위기에서 아크용해한 경우 합금성분의 손실은 미미하였으나 진공유도로를 사용하여 용해한 경우 Mn이 다량 휘발감소하여 조성이 크게 변화하였다.

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직접Quenching 열간 단조용 비조질강의 기계적 성질에 미치는 Quenching온도 및 냉각속도의 영향 (Effect of Quenching Temperature and Cooling Rate on the Mechanical Properties of Direct Quenched Micro-Alloyed Steel for Hot Forging)

  • 신정호;류영주;김병옥;고인용;이오연
    • 한국재료학회지
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    • 제22권10호
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    • pp.513-518
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    • 2012
  • Recently, automobile parts have been required to have high strength and toughness to allow for weight lightening or improved stability. But, traditional micro-alloyed steel cannot be applied in automobile parts. In this study, we considered the influence of quenching temperature and cooling rate for specimens fabricated by vacuum induction furnace. Directly quenched micro-alloyed steel for hot forging can be controlled according to its micro structure and the heat-treatment process. Low carbon steel, as well as alloying elements for improvement of strength and toughness, was used to obtain optimized conditions. After hot forging at $1,200^{\circ}C$, the ideal mechanical properties (tensile strength ${\geq}$ 1,000 MPa, Charpy impact value ${\geq}\;100\;J/cm^2$) can be achieved by using optimized conditions (quenching temperature : 925 to $1,050^{\circ}C$, cooling rate : ${\geq}\;5^{\circ}C/sec$). The difference of impact value according to cooling rate can be influenced by the microstructure. A fine lath martensite micro structure is formed at a cooling rate of over $5^{\circ}C/sec$. On the other hand, the second phase of the M-A constituent microstructure is the cause of crack initiation under the cooling rate of $5^{\circ}C/sec$.

화학공장의 염소 누출에 의한 피해 영향 모델링 (Damage Effects Modeling by Chlorine Leaks of Chemical Plants)

  • 정경삼;백은선
    • 한국화재소방학회논문지
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    • 제32권3호
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    • pp.76-87
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    • 2018
  • 본 연구는 화학공장에서 원료 및 중간재로 많이 사용되는 Heavy Gas인 염소를 화학설비의 가압 염소포화액체 저장탱크에서 2상 흐름 연속누출에 대한 유해위험거리를 정량적으로 예측하기 위한 피해영향 모델링이다. 피해예측을 위한 평가방법과 사고영향평가모델들을 기준으로 액체염소 저장용기의 누출사고에서 사고결과에 미치는 최적의 변수를 나타나기 위해 조업조건을 표준조건으로 하였다. 장외영향평가의 위험성 평가에 사용되는 것으로 USEPA와 NOAA에서 공동 개발된 대기확산 모델인 ALOHA (V5.4.4) 모델을 사용하였다. 화학물질을 대량으로 제조 및 취급하고 있는 여수 국가산업단지를 연구 대상지역으로하여, 기상변수와 공정변수들을 설정하여 시나리오별로 모델링을 하여 누출사고에 대한 특성을 도출하였다. 가우시안 확산모델에 따른 관심지점의 농도 추정치를 산출하였고, ALOHA 모델링 결과 염소 확산에 의한 유해위험거리는 대기온도가 높고 풍속의 감소와 대기 안정도가 안정할수록 증가 하는 것으로 분석되었다.

ATM에서 가상 스위치를 이용한 흐름 제어 방식의 성능 분석 (Performance Analysis of Flow Control Method Using Virtual Switchs on ATM)

  • 조미령;양성현;이상훈
    • 한국컴퓨터산업학회논문지
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    • 제3권1호
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    • pp.85-94
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    • 2002
  • ATM(Asychronous Transfer Mode) 표준에서 제안된 EMRCA(Explicit Max_min Rate Control Algorithm) 스위치 방식은 ATM 네트워크에서 ABR(Available Bit Rate) 서비스 트래픽을 제어한다. ATM 네트워크의 ABR 서비스 분류는 다양한 링크 용량에 적용하기 위하여 피드백 제어 방식을 사용한다. VS/VD(Virtual Source/Virtual Destination) 기법은 다른 종단간 ABR 제어 루프를 격리된 루프들로부터 분리할 수 있도록 해준다. 피드백 지연과 내부적으로 폐쇄된 구간을 갖는 ABR 트래픽 제어는 처리량, 지연 그리고 지터 등을 고려한 ABR 접속에 있어서 보다 나은 성능과 QoS(Quality of Service)를 제공한다. 본 논문은 ABR VS/VD 흐름 제어 방식에 관한 연구이다. 매개변수를 정확하게 선택하고 시스템의 안정성과 같은 성능을 평가하는 수단을 제공하기 위하여 선형 제어 이론을 사용하여 모델링 하였다. 성능 개선의 목적은 높은 링크 이용율과 공정한 대역폭 분배 그리고 안정된 동작등이며 이는 이산 사건 시뮬레이션을 하였다. 본 논문에서는 VS/VD 스위치의 특수한 레이아웃에 맞춘 ABR 흐름 제어 방식의 설계에 선형 제어 이론을 사용한 것이며 시뮬레이션을 하여 기존의 폭주 제어 방식보다 우수함을 보였다.

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