• Title/Summary/Keyword: Phase Inversion Temperature

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Fractional order generalized thermoelastic study in orthotropic medium of type GN-III

  • Lata, Parveen;Zakhmi, Himanshi
    • Geomechanics and Engineering
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    • v.19 no.4
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    • pp.295-305
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    • 2019
  • The present paper is concerned with the investigation of disturbances in orthotropic thermoelastic medium by using fractional order heat conduction equation with three phase lags due to thermomechanical sources. Laplace and Fourier transform techniques are used to solve the problem. The expressions for displacement components, stress components and temperature change are derived in transformed domain and further in physical domain using numerical inversion techniques. The effect of fractional parameter based on its conductivity i.e., ($0<{\alpha}<1$ for weak, ${\alpha}=1$ for normal, $1<{\alpha}{\leq}2$ for strong conductivity) is depicted graphically on various components.

Quasi Phase-Matched Second Harmonic-Wave Generation based on Nonlinear-Optic Effect Utilizing Ti:PPLN Optical Waveguides (Ti:PPLN 광도파로를 이용한 비선형광학 기반의 의사 위상정합 2차 조화파 발생)

  • Jung, Hong-Sik;Jung, Young-Sik
    • Korean Journal of Optics and Photonics
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    • v.19 no.6
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    • pp.408-415
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    • 2008
  • The characteristics of a ferroelectric-domain inverted grating fabricated by applying a high-voltage pulse at room temperature in Ti-diffused channel waveguides in z-cut $LiNbO_3$ (Ti:PPLN) were examined for channel waveguide quasi phase-matched secondharmonic generation devices. The fabrication conditions of uniform periodic domain-inversion were examined. Ti:PPLN with period ${\Lambda}=16.6{\mu}m$ for SHG were fabricated and the performances were measured. A normalized SHG efficiency as high as 473 (%/W) was obtained with 49 mm interaction length.

Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor (희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구)

  • Lee, Jong-Ho;Kim, Dae-Hyun;Jeon, Hung-Hwan;Chang, Young-June
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.4
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    • pp.425-432
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    • 2004
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence(OH$\^$*/) image and its Abel inverted image to investigate the flame structure at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure and NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ∼341.8㎐, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between OH$\^$*/ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

Rheology and morphology of concentrated immiscible polymer blends

  • Mewis, Jan;Jansseune, Thomas;Moldenaers, Paula
    • Korea-Australia Rheology Journal
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    • v.13 no.4
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    • pp.189-196
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    • 2001
  • The phase morphology is an important factor in the rheology of immiscible polymer blends. Through its size and shape, the interface between the two phases determines how the components and the interface itself will contribute to the global stresses. Rheological measurements have been used successfully in the past to probe the morphological changes in model blends, particularly for dilute systems. For more concentrated blends only a limited amount of systematic rheological data is available. Here, viscosities and first normal stress differences are presented for a system with nearly Newtonian components, the whole concentration range is covered. The constituent polymers are PDMS and PIB, their viscosity ratio can be changed by varying the temperature. The data reported here have been obtained at 287 K where the viscosities of the two components are identical. By means of relaxation experiments the measured stresses are decomposed into component and interfacial contributions. The concentration dependence is quite different for the two types of contribution. Except for the component contributions to the shear stresses there is no clear indication of the phase inversion. Plotting either the interfacial shear or normal stresses as a function of composition produces in some cases two maxima. The relaxation times of these stresses display a similar concentration dependence. Although the components have the same viscosity, the stress-component curves are not symmetrical with respect to the 50/50 blend. A slight elasticity of one of the components seems to be the cause of this effect. The data for the more concentrated blends at higher shear rates are associated with a fibrillar morphology.

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Reactions of Gas-Phase Atomic Hydrogen with Chemisorbed Hydrogen on a Graphite Surface

  • Ree, Jong-Baik;Kim, Yoo-Hang;Shin, Hyung-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.635-646
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    • 2007
  • The reaction of gas-phase hydrogen atoms H with H atoms chemisorbed on a graphite surface has been studied by the classical dynamics. The graphite surface is composed of the surface and 10 inner layers at various gas and surface temperatures (Tg, Ts). Three chains in the surface layer and 13 chains through the inner layers are considered to surround the adatom site. Four reaction pathways are found: H2 formation, H-H exchange, H desorption, and H adsorption. At (1500 K, 300 K), the probabilities of H2 formation and H desorption are 0.28 and 0.24, respectively, whereas those of the other two pathways are in the order of 10-2. Half the reaction energy deposits in the vibrational motion of H2, thus leading to a highly excited state. The majority of the H2 formation results from the chemisorption-type H(g)-surface interaction. Vibrational excitation is found to be strong for H2 formed on a cold surface (~10 K), exhibiting a pronounced vibrational population inversion. Over the temperature range (10-100 K, 10 K), the probabilities of H2 formation and H-H exchange vary from 0 to ~0.1, but the other two probabilities are in the order of 10-3.

Synthesis of O/W Emulsion of Alkyd Resin for Reducing of VOC (VOC 절감을 위한 알키드 수지의 O/W 에멀젼 제조)

  • Lee, Young Sang;Lee, Euy Soo;Ha, Jin Kuk
    • Journal of Adhesion and Interface
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    • v.11 no.1
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    • pp.9-14
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    • 2010
  • O/W emulsions were prepared with the phase inversion emulsification methods. The emulsifiers were used the UNIQ-1 (isopropylamine alkyl aryl sulphonate) and UNIQ-2 (alkoxylated glycol ether). Investigated effect that HLB value, agitator velocity and manufacture temperature get in mean particle size of emulsions. Mean particle size receives much effect of HLB value. Also, estimated stability about storage temperature and light. Emulsion's mean particle size was 193 nm lastly, reduced VOC amount used 90% than existing alkyd resin.

Flexural Properties and Thermal Stability of Bifunctional/Tetrafunctional Epoxy Blends (2 -관능성 에폭시 수지 블렌드의 굴곡 특성과 열 안전성)

  • Yu, Hui-Yeol;Lee, Jae-Rak;Lee, Jong-Mun
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.75-80
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    • 1994
  • Flexural properties and thermal stability have been studied as a function of blend composition in bifunctional DGERA (diglycidyl ether of hisphenol A)/tetrafunctional TGDDM(tetrag1ycidyl diamino diphenyl methane) cured with DDM(4, 4'-diamino diphenyl methane). The flexural modulus and the glass transition temperature increase with an increase of TGDDM and show discontinuous dependence on blend composition around the composition range of 80/20~60/40(L)GEBA/TGDDM). This can be explained with a structural phase inversion (ductile-to-brittle) in crosslinking networks. With increasing TGDDM, the maximum decomposition temperature(Ts) increases, whereas the activation energy during thermal degradation decreases.

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Preparation of PVDF/PEI double-layer composite hollow fiber membranes for enhancing tensile strength of PVDF membranes

  • Yuan, Jun-Gui;Shi, Bao-Li;Ji, Ling-Yun
    • Membrane and Water Treatment
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    • v.5 no.2
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    • pp.109-122
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    • 2014
  • Polyvinylidene fluoride (PVDF) hollow fiber membrane is widely used for water treatment. However, the weak mechanical strength of PVDF limits its application. To enhance its tensile strength, a double-layer composite hollow fiber membrane, with PVDF and polyetherimide as the external and inner layers, respectively, was successfully prepared through phase inversion technique. The effects of additive content, air gap distance, N,N-dimethyl-acetamide content in the inner core liquid, and the temperature of external coagulation bath on the membrane structure, permeation flux, rejection, tensile strength, and porosity were determined. Experimental results showed that the optimum preparation conditions for the double-layer composite hollow fiber membrane were as follows: PEG-400 and PEG-600, 5 wt%; air gap distance, 10 cm; inner core liquid and the external coagulation bath should be water; and temperature of the external coagulation bath, 40 C. A single layer PVDF hollow fiber membrane (without PEI layer) was also prepared under optimum conditions. The double-layer composite membrane remarkably improved the tensile strength compared with the single-layer PVDF hollow fiber membrane. The permeation flux, rejection, and porosity were also slightly enhanced. High-tensile strength hollow fiber PVDF ultrafiltration membrane can be fabricated using the proposed technique.

The Study on the Temperature Compensation of Ultrasonic Motor for Robot Actuator Using Fuzzy Controller (퍼지제어기를 이용한 로보트 액츄에이터용 초음파 모터의 온도 보상에 관한 연구)

  • 차인수;유권종;백형래;김영동
    • The Transactions of the Korean Institute of Power Electronics
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    • v.3 no.3
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    • pp.165-172
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    • 1998
  • The electromechanical energy conversion conditioning and processing implementation in USM direct motion control system is generally divided into two power stages: the two-phase high-frequency ac power inversion stage for driving piezoelectric ceramic PZT transducer array off the USM stator and the mechanical thrust power conversion stage based on the frictional force between the piezo electric stator array and the rotary slider of the USM. However, the dynamic and steady-state mathematical modeling of the USM is extremely default from a theoretical point of view because it contains many complicated an nonlinear characteristics dependant on operation temperature. In +2$0^{\circ}C$~3$0^{\circ}C$, the operating characteristics of the USM has represented normal condition. But the other temperature, it has abnormal condition so that driving frequency, current and motor speed will be down. The recent USM has controller without temperature compensation. This study represents the fuzzy controller for speed compensation according to operating temperature by driving frequency.

Behaviour of Nanoemulsions Containing Ceramide IIIB and Stratum Corneum Lipids (세라마이드 IIIB와 각질층 지질을 함유한 나노에멀젼의 거동)

  • Cho, Wan Goo;Kim, Kyung Ah;Jang, Seon Il;Cho, Byoung Ok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.44 no.1
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    • pp.31-37
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    • 2018
  • Oil/water (O/W) nanoemulsions are effective vehicles to change the permeability of the skin. In this study, we focused on the preparation and characterization of nanoemulsion which serve as colloidal carriers for the dermal application of ceramide IIIB (CIIIB) and stratum corneum (SC) lipids such as cholesterol, and palmitic acid. In order to optimize the nanoemulsions, emulsification process conditions were conducted with regard to droplet size, nanoemulsion stability, and solubility of CIIIB. A decrease in droplet size was observed through emulsification temperature of $80^{\circ}C$ and phase inversion composition (PIC) method. CIIIB has low solubility in oil and water. When the concentration of CIIIB was increased, the droplet size of nanoemulsion was increased. When Lipoid S75-3 was added to the oil phase, the solubility of CIIIB increased, indicating some interactions shown in DSC measurements. CIIIB and SC lipids could be successfully incorporated in nanoemulsions without crystallization or physical instability. In conclusion, a stable nanoemulsion containing the SC lipids could be effective as an efficient moisturizing system for skin.