• Title/Summary/Keyword: Phase Inversion

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Kinematic Analysis of Lower Extremities during Stairs and Ramp Climbing with Older Adults (노인의 계단과 경사로 오르기 동안 하지의 운동학적 분석)

  • Han, Jin-Tae;HwangBo, Gak
    • Korean Journal of Applied Biomechanics
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    • v.19 no.3
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    • pp.435-448
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    • 2009
  • The purpose of this study was to investigate the kinemaitc gait parameter of lower extremities with different gait conditions(level walking, stairs, ramp) in old adults. Fourteen healthy older adults participated in this study and kinematic data were measured using 3D motion analysis system(Vicon, Oxford Metrics, England). Statistical analysis was used one-way ANOVA to know the difference of lower extremities angle at each gait phase with a different gait conditions. In sagittal plane, pelvic anterior tilt increased in stairs and ramp climbing and hip and knee flexion increased in stairs climbing but ankle dorsiflexion increased in ramp climbing. In frontal plane, pelvic was up in stairs and hip abduction and adduction more changed in stairs climbing than level walking. Knee varus and ankle inversion increased in stair climbing. In horizontal plane, pelvic internal rotation increased in stairs and ramp climbing and knee internal rotation increased in stairs climbing but ankle external rotation increased in stairs climbing. This results was shown that the stairs and ramp climbing changed the kinematic gait parameters of lower extremities in healthy old adults.

Preparation and Characterization of Cellulosic Forward Osmosis Membranes (셀룰로오스 계 고분자를 이용한 정삼투막의 제조 및 특성)

  • Jeong, Bo-Reum;Kim, Jong-Hak;Kim, Beom-Sik;Park, Yoo-In;Song, Du-Hyun;Kim, In-Chul
    • Membrane Journal
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    • v.20 no.3
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    • pp.222-227
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    • 2010
  • The purpose of this study is to prepare forward osmosis (FO) membranes using a variety of cellulose-based polymers and to evaluate the performance of difference depending on each of the polymers and additives. Forward osmosis membranes based on cellulose acetate (CA) and cellulose triacetate (CTA) were prepared through phase inversion. The performance of FO membranes developed, such as flux and salt rejection, was compared under the osmotically- and pressure-driven conditions. In CA FO membranes, the execution time of solvent evaporation and membrane annealing induced the change in membrane performance. But the performance of CTA FO membrane was improved by using additives rather than annealing. Moreover, the flux of CTA FO membrane was $4.46\;L/m^2hr$ but that of CA/CTA FO membrane was $8.89\;L/m^2hr$ in FO mode. The CTA FO membrane with blending CA was more efficient to increase FO permeate flow rather than using a single polymer membrane.

A Study on the $SO_2/CO_2/N_2$ Mixed Gas Separation Using Polyetherimide/PEBAX/PEG Composite Hollow Fiber Membrane (Polyetherimide/PEBAX/PEG 복합 중공사막을 이용한 $SO_2/CO_2/N_2$ 혼합기체 분리에 관한 연구)

  • Hyung, Chan-Heui;Park, Chun-Dong;Kim, Kee-Hong;Rhim, Ji-Won;Hwang, Taek-Sung;Lee, Hyung-Keun
    • Membrane Journal
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    • v.22 no.6
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    • pp.404-414
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    • 2012
  • In order to investigate $SO_2$ removal, PEI hollow fiber membranes were produced by a dry-wet phase inversion method. The membrane support layer on surface was coated with PEBAX1657$^{(R)}$ and PEG blending materials. Modules were prepared for the single gas permeation characteristics of composite membrane according to temperature and pressure. As a result, $SO_2$ permeance and $SO_2/N_2$ selectivity were 220~1220 GPU and 100~506 through operating condition, respectively. Moreover, $SO_2/CO_2/N_2$ mixture gas was used to compare the performance of separation properties according to temperature, pressure and retentate flow rate difference. $SO_2$ removal efficiency was increased with pressure and temperature.

Fabrication and Property of Ba0.5Sr0.5Co0.8Fe0.2O3-δ Hollow Fiber Membranes (Ba0.5Sr0.5Co0.8Fe0.2O3-δ 중공사 분리막의 제조 및 물성)

  • Jeon, Sung Il;Park, Jung Hoon;Kim, Jong Pyo;Sim, Woo Jong;Lee, Yong Taek
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.1-5
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    • 2012
  • $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ hollow fiber with o.d. 1.02 mm and i.d. 0.437 mm were fabricated by a phase-inversion spinning technique.The starting $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ precursor was synthesized by the polymerized complex method and then calcined at $900^{\circ}C$. As-prepared powder was dispersed in a polymer solution, and extruded as form of hollow fiber through a spinneret. Finallydense $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$ hollow fiber membrane was obtained by sintering for 2 h at $1,080^{\circ}C$ for the application of oxygen separation. In addition, despite a very thin membrane with 0.58 mm, the BSCF hollow fiber membrane possessed a proper mechanical strength of 602.5 MPa.

A Study on Field Seismic Data Processing using Migration Velocity Analysis (MVA) for Depth-domain Velocity Model Building (심도영역 속도모델 구축을 위한 구조보정 속도분석(MVA) 기술의 탄성파 현장자료 적용성 연구)

  • Son, Woohyun;Kim, Byoung-yeop
    • Geophysics and Geophysical Exploration
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    • v.22 no.4
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    • pp.225-238
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    • 2019
  • Migration velocity analysis (MVA) for creating optimum depth-domain velocities in seismic imaging was applied to marine long-offset multi-channel data, and the effectiveness of the MVA approach was demonstrated by the combinations of conventional data processing procedures. The time-domain images generated by conventional time-processing scheme has been considered to be sufficient so far for the seismic stratigraphic interpretation. However, when the purpose of the seismic imaging moves to the hydrocarbon exploration, especially in the geologic modeling of the oil and gas play or lead area, drilling prognosis, in-place hydrocarbon volume estimation, the seismic images should be converted into depth domain or depth processing should be applied in the processing phase. CMP-based velocity analysis, which is mainly based on several approximations in the data domain, inherently contains errors and thus has high uncertainties. On the other hand, the MVA provides efficient and somewhat real-scale (in depth) images even if there are no logging data available. In this study, marine long-offset multi-channel seismic data were optimally processed in time domain to establish the most qualified dataset for the usage of the iterative MVA. Then, the depth-domain velocity profile was updated several times and the final velocity-in-depth was used for generating depth images (CRP gather and stack) and compared with the images obtained from the velocity-in-time. From the results, we were able to confirm the depth-domain results are more reasonable than the time-domain results. The spurious local minima, which can be occurred during the implementation of full waveform inversion, can be reduced when the result of MVA is used as an initial velocity model.

The Effects of Solvent and Nonsolvent on Asymmetric Membrane Structure of 6FDA-p-TeMPD Polyimide (6FDA-p-TeMPD 폴리이미드 비대칭막 제조에서 용매와 비용매가 막구조에 미치는 영향)

  • 박노춘;김건중;남세종
    • Membrane Journal
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    • v.8 no.3
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    • pp.157-169
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    • 1998
  • The effects of solvents (DMAc, NMP, 1,4-dioxane) and nonsolvents ($H_2O$, Methanol, n-hexane) on the morphology of 6FDA-p-TeMPD polyimide membrane, prepared by the wet phase inversion method, were studied. In the polymer/solvent/nonsolvent ternary system, the binodal curve, the coagulation value and the relative light transmission were measured, and the solubility parameter difference was calculated. The onset state and rate of liquid-liquid alemixing were predicted and the morphology of membrane was analyzed. It is found that the finger-like pores are formed within discontinuous polymer nodules when the binoclal curve is close to the polymer-solvent (P-S) axis, the coagulation value is small, the reduction of light transmission is easy to occur and the order of solubility parameter difference ($\Delta \delta_{i-j}$) is $\Delta \delta_{S-NS} > \Delta \delta_{P-NS} > \Delta \delta_{P-S}$. The dense skin with small nodules and the sponge type sublayer with macrovoid are formed in the case that the binodal curve is distant from the P-S axis, the onset time of liquid-liquid demixing is long and the order of $\Delta \delta_{i-j}$ is $\Delta \delta_{P-NS} >(\Delta \delta_{S-NS} < > \Delta \delta_{P-S})$. The thick layer of fine nodule coagulation and loosely grown sublayer of nodules appear when the binodal curve is distant from the P-S axis, the onset time of liquid-liquid demixing is very long and the order of $\Delta \delta_{i-j}$$\Delta \delta_{S-NS} > (\Delta \delta_{P-NS}$\lessgtr$ > (\Delta \delta_{P-NS} < >)\Delta \delta_{P-S}$ ).

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Effect of Non-ionic Additive on Morphology and Gas Permeation Properties of Polysulfone Hollow Fiber Membrane (비이온계 첨가제에 의한 폴리술폰계 중공사 막의 모폴로지 조절과 기체투과 특성)

  • Lee, Hye Jin;Koh, Mi Jin;Kim, Duek Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.224-233
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    • 2012
  • To improve permeation performance of gas separation membrane, polysulfone hollow fiber membrane was prepared by wet-dry phase inversion method using Triton X-100 as non-ionic additive. And variation of gas permeation behavior by additive was investigated. Various spinning conditions such as air gap, concentration of polymer, dope tank temperature were controlled and these effects were studied. The morphology and gas permeation property of hollow fiber membranes were investigated using scanning electron microscope (SEM) and bubble flow meter respectively. We confirmed that the membranes added with Triton X-100 had a smooth external skin at various air gap length conditions. The macrovoids of these hollow fiber membranes were more developed with increase of air-gap from 4 to 90 cm and that induced higher permeance. The permeance of polysulfone membranes has the higher value at comparatively lower concentration polymer (30 wt% polysulfone) and lower concentration of additive (15 wt% Triton X-100). When temperature in dope tank was controlled, the membranes prepared at $100^{\circ}C$ showed low permeance because of volatilization of additive and solvent.

Preparation and Properties of Chlorine-Resistance Loose Reverse Osmosis Hollow-fiber Membrane (내염소성 중공사형 역삼투막(Loose RO)의 제조 및 특성)

  • Kim, Se-Jong;Woo, Seung-Moon;Hwang, Hae-Yong;Koh, Hyung-Chul;Ha, Seong-Yong;Choi, Ho-Sang;Nam, Sang-Yong
    • Membrane Journal
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    • v.20 no.4
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    • pp.304-311
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    • 2010
  • In this study, loose RO hollow fiber membranes using CTA polymer were prepared by phase inversion method and their water purification properties were tested. 1,4-dioxane and LiCl was used as a skin layer formation agent and pore formation agent, respectively. Water flux, salt rejection, chlorine resistance, MWCO and membrane morphology were evaluated as a function of the dope composition. When the membrane prepared using the dope solution of CTA/NMP/1,4-dioxane = 18/72/10 (wt%) with air gap of 30 cm, it shows improved RO performance such as $20.5L/m^2hr$ of water flux, 60% of NaCl rejection, 10,000 ppm/hr of chlorine-resistance and around 5,000 Da of MWCO.

Preparation of Forward Osmosis Membranes with Low Internal Concentration Polarization (농도 분극이 저감된 정삼투 분리막 제조)

  • Kim, Nowon;Jung, Boram
    • Membrane Journal
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    • v.24 no.6
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    • pp.453-462
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    • 2014
  • Thin film composite (TFC) polyamide (PA) membranes were prepared on polyester (PET) nonwoven reinforced polysulfone supports for forward osmosis (FO) processes. PSF (polysulfone) supports were prepared via the phase inversion process from PSF casting solutions in dimethyl formamide (DMF) solvents (19 wt%) by using a PET nonwoven (thickness of $100{\mu}m$) as a mechanical reinforcing material for reverse osmosis (RO) membrane. The PSF support from 19 wt% of DMF/PSF casting solution showed sponge-like morphology and asymmetric internal structure. To reduce the internal concentration polarization in FO operation, thin ($20{\mu}m$ of thickness) nonwoven-supported PSF supports were prepared by using PSF/DMF casting solution (9~19 wt%). A desirable support structure with a highly porous sponge-like morphology were achieved from the thin nonwoven-supported PSF layer prepared with 9~12 wt% casting solution. A crosslinked aromatic polyamide layer was fabricated on top of each support to form a TFC PA membrane. The tested sample from 12 wt% of DMF/PSF casting solution presented outstanding FO performance, almost 5.5 times higher water flux (24.3 LMH) with low reverse salt flux (RDF, 1.5 GMH) compared to a thick nonwoven rainforced membrane (4.5 LMH of flux and 3.47 GMH of RSF). By reducing the thickness of the nonwoven and optimizing PSF concentration of casting solution, the morphology of the prepared membranes were changed from a dense structure to a porous sponge structure in the boundary area between nonwoven and PET support layer.

Electrochemical Characteristics of Microporous Polymer Electrolytes Based on Poly(vinylidene-co-hexafluoropropylene) (PVdF계 미세기공 고분자 전해질의 전기화학적 특성)

  • Jung Kang-Kook;Kim Jong-Uk;Ahn Jou-Hyeon;Kim Ki-Won;Ahn Hyo-Jun
    • Journal of the Korean Electrochemical Society
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    • v.7 no.4
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    • pp.183-188
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    • 2004
  • In order to develop polymer electrolyte for lithium/sulfur batteries, highly microporous P(VdF-HFP) membranes were prepared by phase inversion method. Porous structure was controlled by extracting NMP with mixture of deionized water and methanol. Porous structure of the membranes was observed with SEM. Polymer electrolytes were prepared by soaking the porous membranes in 1M $LiCF_3SO_3-TEGDME/EC$. The ionic conductivity of polymer electrolyte was found to be at high as $2\times10^{-3}S/cm$ when the polymer membrane extracted by $80\%$ methanol was used. The microporous polymer electrolyte optimized in this work displayed high ionic conductivity, uniform pore size, low interfacial resistance and stable ionic conductivity with storage time. The ionic conductivity of polymer electrolytes was measured with various lithium salts, and the conductivity showed $3.3\times10^{-3}S/cm$ at room temperature when $LiPF_6$ was used as a lithium salt.