• 제목/요약/키워드: Phase I

검색결과 3,930건 처리시간 0.029초

Conformations and Vibrational Frequencies of a Precursor of Benzovesamicol Analogues Studied by Density Functional Theories

  • Park, Jong-Kil;Choe, Sang Joon
    • Bulletin of the Korean Chemical Society
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    • 제35권8호
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    • pp.2311-2316
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    • 2014
  • Conformations and vibrational frequencies of the racemic (2RS,3RS)-5-amino-3-(4-phenylpiperazin-1-yl)-1,2,3,4-tetrahydronaphthalen-2-ol-(I) [(2RS,3RS)-(I)], a precursor of benzovesamicol analogues, have been carried out using various DFT methods (M06-2X, B3LYP, B3PW91, PBEPBE, LSDA, and B3P86) with basis sets of 6-31G(d), 6-31+G(d,p), 6-311+G(d,p), 6-311++G(d,p), cc-pVTZ, and TZVP. The LSDA/6-31G(d) level of theory shows the best performance in reproducing the X-ray powder structure. However, the PBEPBE/cc-pVTZ level of theory is the best method to predict the vibrational frequencies of (2RS,3RS)-(I). The potential energy surfaces of racemic pairs (2RS,3RS)-(I) and -(II) are obtained at the LSDA/6-31G(d) level of theory in the gas phase and in water. The results indicate that (2RS,3RS)-(I) are more stable by ~0.75 kcal/mol in energy than (2RS,3RS)-(II) in water, whereas conformer AIIg and BIIg are more stable by ~0.04 kcal/mol than AIg in gas phase. In particular, the hydrogen bond distances between the N of piperazine and the OH of tetrahydronaphthalen become longer in gas, compared with those in the water phase. Vibrational frequencies calculated at the PBEPBE/cc-pVTZ level of theory in the gas phase are larger than those in water, whereas their intensities in the gas phase are weaker than those in water.

A Novel Control Strategy of Three-phase, Four-wire UPQC for Power Quality Improvement

  • Pal, Yash;Swarup, A.;Singh, Bhim
    • Journal of Electrical Engineering and Technology
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    • 제7권1호
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    • pp.1-8
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    • 2012
  • The current paper presents a novel control strategy of a three-phase, four-wire Unified Power Quality (UPQC) to improve power quality. The UPQC is realized by the integration of series and shunt active power filters (APF) sharing a common dc bus capacitor. The realization of shunt APF is carried out using a three-phase, four-leg Voltage Source Inverter (VSI), and the series APF is realized using a three-phase, three-leg VSI. To extract the fundamental source voltages as reference signals for series APF, a zero-crossing detector and sample-and-hold circuits are used. For the control of shunt APF, a simple scheme based on the real component of fundamental load current (I $Cos{\Phi}$) with reduced numbers of current sensors is applied. The performance of the applied control algorithm is evaluated in terms of power-factor correction, source neutral current mitigation, load balancing, and mitigation of voltage and current harmonics in a three-phase, four-wire distribution system for different combinations of linear and non-linear loads. The reference signals and sensed signals are used in a hysteresis controller to generate switching signals for shunt and series APFs. In this proposed UPQC control scheme, the current/voltage control is applied to the fundamental supply currents/voltages instead of fast-changing APF currents/voltages, thus reducing the computational delay and the required sensors. MATLAB/Simulink-based simulations that support the functionality of the UPQC are obtained.

스쿼트 시 Toe-out 각도 변화에 따른 운동역학적 변인 분석 (Biomechanical Analysis on Change of Toe-out Angle in Squat)

  • Song, Hyeong Kyeong;So, Jae Moo
    • 한국운동역학회지
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    • 제29권3호
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    • pp.185-196
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    • 2019
  • Objective: The aim of this study was to suggest correct and effective way of squat through biomechanical analysis variables on the change of the toe-out angle. Method: 7 high school male weightlifter (age: $17.57{\pm}0.53yrs$, height: $174.0{\pm}3.93cm$, weight: $81.0{\pm}9.17kg$, 1RM: $164.29{\pm}20.7kg$) participated in this study. Results: Angle of the hip joint at E2 was smaller than toe-out angle was in $20^{\circ}$ than in $0^{\circ}$ (p<.05). Angular velocity of the foot joint at E1 and E3 was quicker that in $10^{\circ}$ than in $30^{\circ}$ (p<.05). Anterior-posterior stability index was greater that toe-out angle was in $30^{\circ}$ than in $0^{\circ}$ (p<.05). In average iEMG of flexion phase, VM of right, left leg showed high activity at toe-out angle $30^{\circ}$. In average iEMG of flexion phase, extension phase and in peak iEMG, RF of right leg, VM and VL of left leg showed high activity at all of the toe-out angles. In average iEMG of flexion phase, extension phase and in peak iEMG, all of the muscles activity of right leg showed high in $10^{\circ}$ and low in $0^{\circ}$, $30^{\circ}$. Conclusion: It is judged that setting the toe-out angle $10^{\circ}$ in squat help to efficiently use muscles and ensure stability.

공급 전압 변화에 둔감한 Gbps급 저전력 LVDS I/O회로 (Power Supply-Insensitive Gbps Low Power LVDS I/O Circuits)

  • 김재곤;김삼동;황인석
    • 대한전자공학회논문지SD
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    • 제44권6호
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    • pp.19-27
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    • 2007
  • 본 논문에서는 공급전압 변화에 둔감한 Gbps급 저전력 LVDS I/O회로를 설계하였다. 제안된 LVDS I/O는 1.8 V, $0.18\;{\mu}m$ TSMC 공정을 이용하여 설계, 시뮬레이션 및 검증하였다. 설계된 LVDS I/O회로는 송신단과 수신단을 포함한다. 제안하는 송신단은 phase splitter와 SC-CMFB를 이용한 출력버퍼로 구성된다. phase splitter의 출력은 공급 전압이 변화하여도 $50{\pm}2%$의 duty cycle을 가지며 $180{\pm}0.2^{\circ}$의 위상차를 가진다. 출력 버퍼는 SC-CMFB를 이용하여 허용 가능한 $V_{CM}$ 전압 값인 $1.2{\pm}0.1V$을 유지하도록 설계하였다. $V_{OD}$전압 또한 허용범위에서 최소값인 250 mV를 갖도록 설계하여 저전력 동작이 가능하도록 구성하였다 수신단은 38 mV의 히스테리시스 전압값을 가지면서 DC옵셋 전압값이 $0.2{\pm}2.6 V$로 넓은 공통 모드전압 범위가 가능하도록 설계하였고 공급전압 변화에도 rail-to-rail로 복원할 수 있는 기능을 가지고 있다. 또한, 수신단은 1 GHz에서 38.9 dB의 높은 전압 이득을 갖도록 설계하였다.

Effects of supplemented culture media from solid-state fermented Isaria cicadae on performance, serum biochemical parameters, serum immune indexes, antioxidant capacity and meat quality of broiler chickens

  • Liu, Shaoshuai;Yan, Wenjuan;Ma, Chang;Liu, Yajing;Gong, Limin;Levesque, Crystal;Dong, Bing
    • Asian-Australasian Journal of Animal Sciences
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    • 제33권4호
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    • pp.568-578
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    • 2020
  • Objective: The objective of this study was to investigate effects of supplementation of culture media from solid-state fermented Isaria cicadae (I. cicadae) on performance, serum biochemical parameters, serum immune indexes, antioxidant capacity and meat quality of broiler chickens. Methods: A total of 648 Arbor Acres male broiler chickens(1 d; average body weight, 42.93±0.47 g) were randomly assigned to 6 treatments, each with six replicates and 18 broiler chickens per replicate. Broiler chickens were fed phase I (d 1 to 21) and phase II (d 22 to 42) diets. The phase I diets were corn and soybean-meal based diets supplemented with 0%, 2%, 4%, 6%, 8%, or 10% culture media from solid-state fermented I. cicadae respectively. The phase II diets were corn and soybean-meal based diets supplemented with 0%, 1.33%, 2.67%, 4.00%, 5.32%, or 6.67% culture media from solid-state fermented I. cicadae respectively. Results: In phase I, the broiler chickens with the supplementation of culture media had increased body weight gain and feed intake (linear and quadratic, p<0.05) with increasing inclusion of culture media. The levels of serum total antioxidant capacity (T-AOC), glutathione (GSH) and superoxide dismutase (SOD) increased linearly (p<0.05). In phase II, levels of serum T-AOC and interleukin-1β increased linearly (p<0.05), and GSH increased (p<0.05). In the kidney, GSH and glutathione peroxidase (GSH-Px) concentrations increased (linear and quadratic, p<0.05) and SOD concentration increased linearly (p<0.05). Compared to the control, shear force and drip loss of breast muscle decreased (linear and quadratic, p<0.05). Drip loss of leg muscle decreased linearly and quadratically (p<0.05). Conclusion: Dietary supplementation of culture media from solid-state fermented I.cicadae which was enriched in both wheat and residual bioactive components of I. cicadae enhanced the growth performance of broiler chickens. It also improved body anti-oxidative status and contributed to improve broiler meat quality.

Competitive Phase Separation in a Crystallizable Polymer Solution

  • Lee, Hwan-Kwang
    • 한국막학회:학술대회논문집
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    • 한국막학회 1996년도 추계 총회 및 학술발표회
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    • pp.12-17
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    • 1996
  • The structure formation by liquid-liquid(L-L) phase separation coupled with crystallization in isotactic polypropylene(i-PP). solutioos was investigated by a temperature jump experiment. A series of dialkyl phthalates with a different number of carbon atoms in the alkyl chain was used to control the interaction between polymer and solvent. Various thermal quench conditions were applied to the i-PP solutions to control systematically L-L phase separation and crystallization. A slow crystallizatina elongates the liquid droplets in the radial direction of a spherulite. A rapid crystallization under the deep quench locks-in the growth of L-L phase separation. These results indicate that the extent of L-L phase separation which exists below melting point can be successfully controlled through the proper selection of solvent and thermal conditions.

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반송파 위상 복원을 결합한 새로운 이중모드 블라인드 등화 알고리즘 (A new dual-mode blind equalization algorithm combining carrier phase recovery)

  • 오길남;진용옥
    • 전자공학회논문지A
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    • 제32A권5호
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    • pp.14-23
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    • 1995
  • A new dual-mode algorithm for blind equalization of quadrature amplitude modulation (QAM) signals is proposed. To solve the problem that the constant modulus algorithm (CMA) converges to the constellation with the arbitrary phase rotation, with the modification of the CMA, the proposed algorithm accomplishes blind equalization and carrier phase recovery simultaneously. In addition, the dual-mode algorithm combining the modified constant modulus algorithm (MCMA) with decision-directed (DD) algorithm achieves the performance enhancement of blind convergence speed and steady-state residual ISI. So we can refer the proposed algorithm to as a scheme for joint blind equalization and carrier phase recovery. Simulation results for i.i.d. input signals confirm that the dual-mode algorithm results in faster convergence speed, samller residual ISI, and better carrier phase recovery than those of the CMA and DD algorithm without any significant increase in computational complexity.

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설비용량을 고려한 계층적 네트워크의 설계 및 분석 (Designing hierarchical ring-star networks under node capacity constraints)

  • 이창호;윤종화;정한욱
    • 한국경영과학회지
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    • 제19권1호
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    • pp.69-83
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    • 1994
  • This paper deals with a capacitated ring-star network design problem (CRSNDP) with node capacity constraints. The CRSNDP is formulated as a mixed 0-1 integer problem, and a 2-phase heuristic solution procedure, ADD & VAM and RING, is developed, in which the CRSNDP is decomposed into two subproblems : the capacitated facility location problem (CFLP) and the traveling sales man problem (TSP). To solve the CFLP in phase I the ADD & VAM procedure selects hub nodes and their appropriate capacity from a candidate set and then assigns them user nodes under node capacity constraints. In phase II the RING procedure solves the TSP to interconnect the selected hubs to form a ring. Finally a solution of the CRSNDP can be achieved through combining two solution of phase I & II, thus a final design of the capacitated ring-star network is determined. The analysis of computational results on various random problems has shown that the 2-phase heuristic procedure produces a solution very fast even with large-scale problems.

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CARS를 이용한 희박 예혼합 가스터빈 연소기내 온도 측정 (I) -연료/공기 혼합정도가 위상별 온도에 미치는 영향- (Phase-Resolved CARS Temperature Measurement in a Lean Premixed Gas Turbine Combustor (I) -Effect of Equivalence Ratio on Phase-Resolved Gas Temperature-)

  • 이종호;전충환;박철웅;한재원;장영준
    • 대한기계학회논문집B
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    • 제28권10호
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    • pp.1184-1192
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    • 2004
  • Experimental investigations were carried out in an atmospheric pressure, optically accessible and laboratory-scale dump combustor operating on methane gas. The objective of this study was to obtain the phase-resolved gas temperatures at different phases of the oscillating pressure cycle during unstable combustion. CARS temperature measurements were made at several spatial locations under lean premixed conditions to get the information on temperature field within the combustor. Also the effect of incomplete fuel-air mixing on phase-resolved temperature fluctuation was investigated. Results including phase-resolved averaged temperature, normalized standard deviation and temperature probability distribution functions (PDFs) were provided in this paper. Temperature PDFs gave an insight on the flame behavior. And strong correlation between phase-resolved temperature profile and pressure cycle was observed. Results of the phase-resolved high temperature gave an additional information on the perturbation of equivalence ratio at flame as well as the effect of mixing quality on NOx emission characteristics.

패션 명품(名品) 복제품(複製品) 소비자(消費者)의 위험지각(危險知覺)에 관(關)한 질적(質的) 연구(硏究) (I) - 지각(知覺)된 위험유형(危險類型)을 중심(中心)으로 - (A Qualitative Study on the Consumers' Risk Perception for the Counterfeit of Fashion luxury Brands (I) - Focused on Perceived Risk Types -)

  • 김일
    • 패션비즈니스
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    • 제9권1호
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    • pp.120-136
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    • 2005
  • The purpose of this study is to analyze consumers' perceived risk which is shown in the process of purchase phase and consumption phase for the counterfeits of fashion luxury brands and to analyze the interrelationship of each type of perceived risk. The research method of the study used a qualitative approach. 6 informants were selected and then an in-depth interview was held with them. Through this process the data on the perceived risk for counterfeits were collected and analyzed. The results of the study are as follows; The perceived level of psychological risk including counterfeits exposure was extremely high; besides, economic risk and performance risk were also perceived. On the contrary, the perceived level of social risk and fashionability loss were relatively low. The risk perception for counterfeits appeared not only on the purchase phase but also on the consumption phase, and when perceived risk existed on the consumption phase, it had an influence on the level of perceived risk on the next purchase phase. However the psychological risk was continuously perceived on both purchase and consumption phase, even if it did not exist on the consumption phase. Psychological risk, economic risk and performance risk were not independent but interdependent. Moreover, the entire level of perceived risk could be controlled by reducing the level of other perceived risks when a certain type of risk was highly perceived.