• 한국막학회:학술대회논문집
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• 한국막학회 1998년도 춘계 총회 및 학술발표회
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• pp.53-55
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• 1998

1. INTRODUCTION : Since the knowledge of vitrification phenomena can lead to a better understanding of the mechanism of membrane formation, it is desirable to include vitrification line into the phase diagrams. While the final morphology obtained during phase inversion depends upon the kinetics as well as the thermodynamics of the phase separation, the equilibrium phase diagram and vitrification line for amorphous polymers are still a good tool for controlling the morphology and interpreting the membrane structure.

• 지역연구
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• 제13권2호
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• pp.45-54
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• 1997

A regional economy is characterized as a spatial economy. However the literature shows that it has been treated as a point economy since space is little recognized in regional modeling due to mathematical complication. This leads to the fact that regional model does not sufficiently represent regional characteristic. This paper attempts to construct a regional growth model in a partial equilibrium framework specifically taking into consideration land as a primary factor. The model is formulated largely neoclassical. Labor is assumed to move in response to differences in the wage rate, while capital is perfectly mobile across regions. The paper shows that two growth equilibrium points exist, one stable equilibrium point and the other unstable equilibrium point. The unstable growth equilibrium indicates the existence of minimum threshold that a region must overcome the minimum threshold to grow constantly. Consequently, directions of regional growth are characterized by two growth paths depending on the initial condition of a region. That is to say, a region below the minimum threshold is converging toward the lower stable equilibrium point over time. When a regional economy initially lies above the minimum threshold, it will grow forever. A regional economy is not thus necessarily converging a stationary is not thus necessarily converging a stationary equilibrium point through factor movement. Finally, the impacts of the presence of agglomeration economies and diseconomies are analyzed through the phase diagram. The paper also shows that agglomeration economies result in lowering the minimum threshold and in escalating the level of stable equilibrium However, when agglomeration diseconomies prevail, the results are opposite, i.e., rising the minimum threshold of growth and lowering the growth level of stable equilibrium.

• 한국주조공학회지
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• 제15권2호
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• pp.184-193
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• 1995

Effects of process parameters during thixocasting, such as solid volume fraction, mold temperature and extrusion ratio, on the mold filling behaviour and fluidity of Mg alloy(AZ91D) have been investigated. The semi-solid ingot held for 60 minutes at the semi-solid temperature range did not contain the equilibrium volume fraction of solid as expected from the phase diagram. Therefore, in order to obtain the desired solid fractions, and to suppress the exaggerated grain growth during heating, it was required to heat the ingot rapidly up to the temperature $10^{\circ}C$ higher than the semi-solid temperature suggested from the phase diagram for a specific volume fraction of solid. The experimental results show that mold filling behaviour and fluidity can be improved with the use of the higher mold temperature and the lower volume fraction of solid, but remain nearly unaffected by the change of extrusion ratio.

• Macromolecular Research
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• 제10권1호
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• pp.18-23
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• 2002

We theoretically consider blends of two monodisperse one-end-functionalized homopolymers (denoted by A and B) capable of forming clusters between functional groups (stickers) using weak segregation theory. In this model system resulting molecular architectures via clustering resemble star copolymers having many A- and B-arms. Minimizing the total free energy with respect the cluster distribution, the equilibrium distribution of clusters is obtained and used for RPA (Random Phase Approximation) equations as input. For the case that polymers are functionalized by only one kind of sticker, the phase diagrams show that the associations promote the macrophase separation. When there is strong affinity between stickers belonging to the different polymer species, on the other hand, the phase diagram show a suppression of the macrophase separation at the range of high temperature regime, as well as the phase coexistence between a disordered and a mesoscopic phase at the relatively lower temperatures.

• Korea-Australia Rheology Journal
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• 제18권2호
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• pp.99-102
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• 2006

Primitive chain network model for block copolymers is used here to simulate molecular dynamics in the entangled state with acceptable computational cost. It was found that i) the hooking procedure rearranging the topology of the entangled network is critical for the equilibrium structure of the system, and ii) simulations accounting for the different chemistry, i.e., with a biased hooking probability based on interaction parameter ${\chi}$ for selection of the hooked partner, generates a reasonable phase diagram.

• 한국재료학회지
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• 제13권1호
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• pp.24-30
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• 2003

The Raney Ni catalyst was fabricated by mechanochemically process(MC process) in the Al-Ni system. Intermetallic compound obtained by mechanical alloying was leached in an alkaline solution. The characteristics of the mechanically alloyed powder and Raney Ni catalyst were analyzed by XRD, ICP-AES and EXAFS. In Al-50wt.%Ni, the metastable intermetallic compound phase close to AlNi phase was obtained by mechanical alloying unlike Al-Ni equilibrium phase diagram. The metastable intermetallic compound was transformed into $Al_3$$Ni_2$phase via the annealing at $750^{\circ}C$. The microstructure of Raney Ni fabricated by MC process was mainly bcc Ni including fcc Ni.

• 자원리싸이클링
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• 제17권3호
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• pp.29-34
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• 2008

이온강도가 센 염산용액에서 Alamine336과 TBP에 의한 염화 제 2철의 용매추출거동을 MaCabe-Thiele도를 이용하여 비교하였다. 초기 추출조건으로부터 수상과 유기상에서 철의 평형농도를 계산하여 두 추출제에 의한 철 추출의 등온추출곡선을 구했다. 평형농도 계산시 수상에서 착물형성반응과 물질수지 및 추출반응을 고려하였다. 1M의 Aalmine336으로 0.5M의 철을 3M의 염산용액에서 수상과 유기상의 부피비가 6/5인 조건에서 추출시 2단에 철의 대부분이 유기상으로 추출되는 것을 MaCabe-Thiele도에서 알 수 있었다. 1M의 Alamine336은 염산용액에서 철의 추출능력면에서 TBP 2-3M과 비슷하였다. MaCabe-Thiele도와 두 추출제의 물리적 특성으로부터 Alamine336이 TBP보다 염산용액에서 철의 추출특성이 우수한 것을 알 수 있었다.

• 한국결정성장학회지
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• 제12권2호
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• pp.101-109
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• 2002

Hot-wall CVD법으로 SiC/C 경사기능재료를 증착시키는 공정을 열역학적으로 해석하였다. Si-C-H-Cl계에 대한 열역학적 계산을 통해 공정변수(증착온도, 반응기 압력 원료 기체의 C/[Si+C]비와 H/[Si+C]비)가 증착층의 조성과 증착 수율에 미치는 영향을 조사하였고, 이를 통해 SiC/C 경사기능재료 증착에 있어서의 CVD 상평형도와 최적 공정 조건의 범위를 예측할 수 있었다.

• 한국해양공학회지
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• 제25권4호
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• pp.7-11
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• 2011

The installation phase for a topside module suggested can be divided into 9 stages, which include start, pre-lifting, lifting, lifted, rotating, positioning, lowering, mating, and end of installation. The transfer of the topside module from a transport barge to a crane vessel takes place in the first three stages, from start to lifting, while the transfer of the module onto a floating spar hull occurs in the last three stages, from lowering to the end. The coupled multi-body motions are calculated in both calm water and in irregular waves with significant wave height (1.52m), with suggested force equilibrium diagrams. The effects of the hydrodynamic interactions between the crane vessel and barge during the lifting stage have been considered. The internal forces caused by the load transfer and ballasting are derived for the lifting phases. The results of these internal forces for the calm water condition are compared with those in the irregular sea condition. Although the effect of pitch motion on the relative vertical motion between the deck of the floating structure and the topside module is significant in the lifting phases, the internal force induced pitch motion is too small to show its influence. However, the effect of the internal force on the wave-induced heave responses in the lifting phases is noticeable in the irregular sea condition because the transfer mass-induced draught changes in the floating structure are observed to have higher amplitudes than the external force induced responses.

• 열처리공학회지
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• 제9권2호
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• pp.79-90
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• 1996

Transmission electron microscopy(TEM) investigation on the phase decomposition of B2-ordered (Ni,Co)Al supersaturated with Ni and Co has revealed the precipitation of $(Ni,Co)_2Al$ which has not been expected from the reported equilibrium phase diagram. The $(Ni,Co)_2Al$ phase has a hexagonal struture and takes a rod-like shape with the long axis of the rod parallel to the <111> directions of the B2 matrix. By aging at temperatures below 873 K, a long period Superlattice Structure appears in the hexagonal $(Ni,Co)_2Al$ Phase. The orientation relationship between the $(Ni,Co)_2Al$ Precipitates and the B2-(Ni,Co)Al matrix is found to be$(0001)_p$ // $(111)_{B2}$ and $[\bar{1}2\bar{1}0]_P$ // $[\bar{1}10]_{B2}$, Where the suffix p and B2 denote the $(Ni,Co)_2Al$ precipitate and the B2-(Ni,Co)Al matrix, respectively. (Ni,Co)Al hardens appreciably by the fine precipitation of the $(Ni,Co)_2Al$ phase. Energy dispersive spectroscopy was used to analyze the compositions of each phase formed in B2-(Ni,Co)Al.