• Title/Summary/Keyword: Permeability characteristics

Search Result 1,118, Processing Time 0.037 seconds

Condensable Gas Separation using Phenol! Alumina Composite Activated Carbon Hollow Fiber Membranes (페놀수지/알루미나 복합 활성탄소중공사막을 이용한 응축성 기체 분리)

  • Shin, Kyung-Yong;Park, You-In;Kim, Beom-Sik;Koo, Kee-Kahb
    • Membrane Journal
    • /
    • v.20 no.4
    • /
    • pp.312-319
    • /
    • 2010
  • Carbon membrane materials have received considerable attention for the gas separation including hydrocarbon mixture of ingredients of the volatile organic compounds(VOCs) because they possess their higher selectivity, permeability, and thermal stability than the polymeric membranes. The use of activated carbon membranes makes it possible to separate continuously the VOCs mixture by the selective adsorption-diffusion mechanism which the condensable components are preferentially adsorbed in to the micropores of the membrane. The activated carbon hollow fiber membranes with uniform adsorptive micropores on the wall of open pores and the surface of the membranes have been fabricated by the carbonization of a thin film of phenolic resin deposited on porous alumina hollow fiber membrane. Oxidation, carbonization, and activation processing variables were controlled under different conditions in order to improve the separation characteristics of the activated carbon membrane. Properties of activated carbon hollow fiber membranes and the characterization of a gas permeation by pyrolysis conditions were studied. As the result, the activated carbon hollow fiber membranes with good separation capabilities by the molecular size mechanism as well as selective adsorption on the pores surface followed by surface diffusion effective in the recovery hydrocarbons have been obtained. Therefore, these activated carbon membranes prepared in this study are shown as promising candidate membrane for separation of VOCs.

Technique for the Measurement of Crack Widths at Notched / Unnotched Regions and Local Strains (콘크리트의 노치 및 비노치 구역에서의 균열폭 및 국부 변형률 정밀 측정기법)

  • Choi, Sok-Hwan;Lim, Bub-Mook;Oh, Chang-Kook;Joh, Chang-Bin
    • Journal of the Korea Concrete Institute
    • /
    • v.24 no.2
    • /
    • pp.205-214
    • /
    • 2012
  • Crack widths play an important role in the serviceability limit state. When crack widths are controlled sufficiently, the reinforcement corrosion can be reduced using only existing concrete cover thickness due to low permeability in the region of finely distributed hair-cracks. Thus, the knowledge about the tensile crack opening is essential in designing more durable concrete structures. Therefore, numerous researches related to the topic have been performed. Nevertheless accurate measurement of a crack width is not a simple task due to several reasons such as unknown potential crack formation location and crack opening damaging strain gages. In order to overcome these difficulties and measure precise crack widths, a displacement measurement system was developed using digital image correlation. Accuracy calibration tests gave an average measurement error of 0.069 pixels and a standard deviation of 0.050 pixels. Direct tensile test was performed using ultra high performance concrete specimens. Crack widths at both notched and unnotched locations were measured and compared with clip-in gages at various loading steps to obtain crack opening profile. Tensile deformation characteristics of concrete were well visualized using displacement vectors and full-field displacement contour maps. The proposed technique made it possible to measure crack widths at arbitrary locations, which is difficult with conventional gages such as clip-in gages or displacement transducers.

Characteristics on Shear Strength and Clogging Phenomenon of Bottom Ash and Rammed Aggregate Mixture Compaction Pile (쇄석과 저회의 혼합다짐말뚝의 전단강도와 Clogging 현상 규명)

  • Lee, Dongyeup;Kang, Hyongnam;Chun, Byungsik
    • Journal of the Korean GEO-environmental Society
    • /
    • v.11 no.3
    • /
    • pp.33-41
    • /
    • 2010
  • The rammed aggregate compaction pile method is widely used as soft ground improvement method because of the installed piles improve not only overall composite capacity but also discharge capacity. But the discharge capacity is declined when the clogging is generated due to the clay penetration into voids of rammed aggregate compaction pile with the time elapsed. The purpose of this study is to reduce the clogging problem occurred in rammed aggregate compaction pile constructed in the soft ground and to minimize voids of rammed aggregate compaction pile. The proper mixing ratio was determined which is based on the results of the large scale direct shear tests conducted to get strength and permeability as optimum mixing ratio of crushed stone and bottom ash. The test results indicated that the highest internal friction angle was obtained at 80:20 mixing ratio of crushed stone and bottom ash. The internal friction angle was declined when the mixing ratio of the bottom ash increased over 20%. The results of the clogging tests, presented that the mixture of 80:20 crushed stone and bottom ash is highest effective of clogging than ratio of pure crushed stone.

A Stochastic Numerical Analysis of Groundwater Fluctuations in Hillside Slopes for Assessing Risk of Landslides (산사태 위험도 추정을 위한 지하수위 변동의 추계론적 수치 해석)

  • 이인모
    • Geotechnical Engineering
    • /
    • v.3 no.4
    • /
    • pp.41-54
    • /
    • 1987
  • A stochastic numerical analysis for predicting the groundswater fluctuations in hillside slopes is performed in this paper to account for the uncertainties associated with the rainfall and site characteristics. The effect of spatial variabilities of aquifer parameters and the effect of temporal variability of recharge on the groundwater fluctuations are studied in depth. The Kriging is used to account for the spatial tariabilities of aquifer parameters. This technique prolevides the best linear unbiased estimator of a parameter and its minimum variance from a litsitem number of measured data. A stochastic one-dimensional numerical model is delreloped b) combining the groundwater flow model, the Kriging, and the first-order second-moment analysis. In addition, a two dimensional detelministic groundwater model is developed to study the change of ground water surfas in the transverse direction as well as in the downslope direction. It is revealed that the undulations of the impervious bedrock in addition to the permeability and the specific yield have an important influence on the fluctuations of the groundwater surface. It is also found that th'e groundwater changes significantly in the transverse direction as well as in the downslope direction. The results obtained in this analysis may be used for evaluation of landslide risks due to high porewater pressure.

  • PDF

Impact Assessment of Turbidity Water caused Clays on Algae Growth (조류성장에 미치는 점토탁수의 영향평가)

  • Park, Chan-Gab;Kang, Mee-A
    • The Journal of Engineering Geology
    • /
    • v.16 no.4 s.50
    • /
    • pp.403-409
    • /
    • 2006
  • This study was performed to assess the clay impact on alga growth which was a primary producer, in view of food chain in ecosystem. As clay minerals caused turbidity, a low sedimentation, high adsorption capacity with organic matter, adsorption - desorption effect with ionic chemicals, clay minerals were supposed to have a significant effect on the aquatic system. In study we tried to turn out NOAEL (No-observed-adverse-effect-level) of clay materials on the algae growth inhibition using such as kaolinite, sericite and montmorillonite. This study was indicated. (1) In both of kaolinite and sericite, the $72hr-EC_{50}$ of them shows 2,752 mg/L and 2,775 mg/L, respectively. (2) On the other hand, in the case of montmorillonite, the $72hr-EC_{50}$ is not shown a significant difference to that of control samples. (3) It can be explained that is also a very important parameter in an alga growth. Because an alga growth was increased when the permeability of W visible radiation was increased in all clay cases. (4) It is demonstrated alga growth was affected by the characteristics of clay materials. Hence we can assess the $\ulcorner$water environmental risk assessment caused clay materials$\lrcorner$ using the alga growth inhibition level indirectly.

Phyto-restoration Potential of Soil Properties using Secale cereale for Recycle of Soils with Residual TPHs (Total Petroleum Hydrocarbons) after Off-site Treatment (잔류유분 함유 반출처리토 재활용을 위한 호밀 식재 식물상 토성회복 가능성)

  • Park, Jieun;Bae, Bumhan;Joo, Wanho;Bae, Seidal;Bae, Enjoo
    • Journal of Soil and Groundwater Environment
    • /
    • v.19 no.3
    • /
    • pp.25-32
    • /
    • 2014
  • The amount of TPH contaminated soil treated at off-site remediation facilities is ever increasing. For the recycle of the treated-soil on farmlands, it is necessary to restore biological and physico-chemical soil characteristics and to remove residual TPH in the soil by an economic polishing treatment method such as phytoremediation. In this study, a series of experiments was performed to select suitable plant species and to devise a proper planting method for the phyto-restoration of TPH-treated soil. Rye (Secale cereale) was selected as test species through a germination test, among 5 other plants. Five 7-day-old rye seedlings were planted in a plastic pot, 20 cm in height and 15 cm in diameter. The pot was filled with TPH-treated soil (residual TPH of 1,118 mg/kg) up to 15 cm, and upper 5 cm was filled with horticulture soil to prevent TPH toxic effects and to act as root growth zone. The planted pot was cultivated in a greenhouse for 38 days along with the control that rye planted in a normal soil and the blank with no plants. After 38 days, the above-ground biomass of rye in the TPH-treated soil was 30.6% less than that in the control, however, the photosynthetic activity of the leaf remained equal on both treatments. Soil DHA (dehydrogenase activity) increased 186 times in the rye treatment compared to 10.8 times in the blank. The gross TPH removal (%) in the planted soil and the blank soil was 34.5% and 18.4%, respectively, resulting in 16.1% increase of net TPH removal. Promotion of microbial activity by root exudate, increase in soil permeability and air ventilation as well as direct uptake and degradation by planted rye may have contributed to the higher TPH removal rate. Therefore, planting rye on the TPH-treated soil with the root growth zone method showed both the potential of restoring biological soil properties and the possibility of residual TPH removal that may allow the recycle of the treated soil to farmlands.

Characteristics of Flux Decline in Microfiltration Capillary Membrane of Bentonite Colloidal Suspensions (정밀여과 모세관 막을 이용한 벤토나이트 콜로이드 현탁액의 투과유속 감소특성)

  • Nam Suk-Tae;Han Myeong-Jin
    • Membrane Journal
    • /
    • v.15 no.1
    • /
    • pp.52-61
    • /
    • 2005
  • Permeate flux decline in a microfiltration was analyzed by measuring the permeability of bentonite colloidal solution through polyethylene capillary membranes. The flux decline with time was due to the growth of cake layer on the membrane surface and to the pore blocking by particles. As the time approaches to steady state, the permeate flux is almost controlled by the cake filtration model. Faster flux decline at high trans-membrane pressure was attributed to the formation of denser packed cake layer and pore blocking. The ratio of permeate flux to the initial permeate flux, J/J₁, decreased with increasing the trans-membrane pressure, from 45% for 0.5 kg/sub f//㎠ to 38% for 2.0 kg/sub f//㎠. In comparing the ratio of each fouling component to the total fouling for the 0.5 kg/sub f//㎠ TMP condition, complete blocking was 23.4%, standard blocking was about 14.6% and cake filtration was 62.0%, respectively. Permeate flux through the membrane increases with cross flow velocity, and the effect of the variation of velocity is more significant at 1.0 kg/sub f//㎠ rather than at 2.0 kg/sub f//㎠ of the operation pressure. Permeate flux for the membrane having the average pore diameter of 0.34 ㎛ was higher than that for the membrane of 0.24 ㎛ pore size, with the higher flux with the low concentration of feed. On the operation using the membrane of 0.34 ㎛ pore, the pore blocking in the low concentration of 200 ppm is negligible relative to the pore blocking in the 1000 ppm feed.

Carbon Molecular Sieve Membranes Derived from Thermally Labile Polymer Containing Polyimide and Their Gas Separation Properties (열분해성 고분자 도입에 따른 탄소분자체막의 기체 투과 특성)

  • Young Moo Lee;Youn Kook Kim;Ji Min Lee;Ho Bum Park
    • Membrane Journal
    • /
    • v.13 no.3
    • /
    • pp.182-190
    • /
    • 2003
  • Carbon molecular sieve (CMS) membranes were prepared by the pyrolysis of polyvinylpyrrolidone containing polyimide precursors. We have prepared the polymer precursors, pyrolyzed polymer and investigated the effect of pyrolyzing polymer on the characteristics of carbon structures and gas separation properties of the CMS membranes. Thermogravimetric analysis (TGA) showed the two-step decomposition of polymer precursor. First decomposition of the pyrolyzing polymer began around $400^{\circ}C$ while carbonizing polymer showed the decomposition around $550^{\circ}C$. The gas permeabilities through the CMS membranes were enhanced by the introduction of the pyrolyzing polymer and decreased with increased final pyrolysis temperature. The CMS membrane pyrolyzed at $550^{\circ}C$. derived from precursor containing 5wt% PVP as a pyrolyzing polymer showed gas permeability for $O_2$ of 808 Barrers [$10^{-10}cm^3 (STP)cm/cm^2scmHg]$ and $O_2/N_2$ selectivity of 7.

Improvement of Grouting by Short-period Vibration Energy (단주기 진동에너지에 의한 그라우팅 보강효과)

  • Seo, Moonbok;Kwon, Sanghoon;Lee, Bongjik
    • Journal of the Korean GEO-environmental Society
    • /
    • v.16 no.7
    • /
    • pp.35-42
    • /
    • 2015
  • Grouting method has been widely used for the ground improvement and stabilization: mostly to block or control the ground water in the early years and to improve the ground, repair the structure in recent years, ever increasing its use. Despite many advantages so far, the existing grouting method also has some shortcomings including uncertain permeation of grouting with gravity type if the voids between the soil particles are narrow, and problems due to the relaxation of the neighboring ground when injected using injection pressure. As an alternative, a vibration injection method with constant amplitude and frequency has been developed in recent years, with the vibration grouting being reported to have a permeability increasing effect of grout material compared with the positive pressure injection type. Accordingly, the purpose of this study is to investigate the improvement effect of the vibration grouting that applies short-period vibration energy by varying vibration cycle, vibration time and ground conditions to evaluate the strength enhancing effect of grouting materials, expansion effect of grouting body, ground improvement effect of the grouting and the penetration characteristics of the rock joint. The findings of this study show the improved compressive strength of grout, expansion of grouting body and increased penetration rate, according to the vibration compared with non-vibration under the loose soil condition.

Characteristics of short term changes of groundwater level and stream flow rate during 2017 Pohang earthquakes (2017 포항 지진시 단기간 지하수위 변동 및 하천 유량 변화 특성)

  • Choi, Myoung-Rak;Lee, Ho-Jeong;Kim, Gyoo-Bum
    • Journal of the Geological Society of Korea
    • /
    • v.54 no.5
    • /
    • pp.557-566
    • /
    • 2018
  • Pohang earthquake (Main shock magnitude = 5.4) occurred in Southeastern region of South Korea in November 15, 2017. Groundwater levels of 6 monitoring wells with 5 minutes interval measurements located in that region and stream water levels of 4 stations located along the Hyeongsan-gang stream are used for the analysis of earthquake induced effects. Four groundwater monitoring wells show a short-term decrease of groundwater level after a main shock and one well does an increase and the maximum change is about 42.0 cm. Especially, groundwater levels at two monitoring wells near the epicenter are consistently maintained after a decrease. There is little relationship between earthquake magnitude or a distance to epicenter and changing amount of groundwater level and it may be due to the inhomogeneity of geologic material and unconsolidated sediments distribution. The changes in permeability of fractured zone and groundwater levels occasionally cause changes in stream flow rate, and water level of the Hyeongsan-gang stream in the study area decreases just after the earthquake and increases again up to the normal level and next shows an more gentle decreasing slope. Total increasing flow rates at S1 (upstream site) and S4 (downstream site) stations are about $12,096m^3$ and $116,640m^3$, respectively, during the increasing period.