• Title/Summary/Keyword: Performance Surface

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Improvement of Bleaching Performance of Photosensitive Electrochromic Device by the Additive of TEMPOL (TEMPOL 첨가제 적용에 의한 광감응형 전기변색 소자 탈색성능 향상)

  • Song, Seung Han;Park, Hee sung;Cho, Churl Hee;Hong, Sungjun;Han, Chi-Hwan
    • Journal of the Korean Chemical Society
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    • v.66 no.3
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    • pp.209-217
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    • 2022
  • We have developed photosensitive electrochromic smart windows that does not require any transparent conducting oxide (TCO) substrate. In our previous study, we demonstrated that a flexible film-type device made with a low temperature curing WO3 sol and TiO2 sol could show a reversible and rapid switching between colored and bleached state via incorporation of platinum catalysts on the surface of WO3 layer. However, when these devices were exposed to sunlight over 4 hour, it was confirmed that they did not return to fully bleached state in the darkened state due to their overcoloring process. In this study, we added 4-hydroxy-(2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPOL) as an additive to the electrolyte of photosensitive electrochromic device to effectively prevent the undesired overcoloring process. The resulting device with TEMPOL indeed did not undergo excessive coloration and showed great reversibility even after being exposed to sunlight for over 4 hours. Various concentrations of TEMPOL were applied to compare changes in the visible transmittance and coloring/bleaching kinetics of devices. In terms of energetic point of view, we proposed a plausible mechanism of TEMPOL to prevent excessive coloration.

A study of the space sterilization device using atmospheric-pressure DBDs plasma (대기압 유전체장벽방전을 적용한 플라즈마오존 공간살균장치에 관한 연구)

  • Oh, Hee-Su;Lee, Kang-yeon;Park, Ju-Hoon;Jeong, Byeong-Ho
    • Journal of the Korea Convergence Society
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    • v.13 no.3
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    • pp.281-289
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    • 2022
  • Plasma ozone is utilized in a variety of applications in the field of sterilization due to its high sterilization performance. Dielectric materials used in DBD(dielectric barrier discharges) are mainly polymer, quartz and ceramics. These dielectric layers have the advantage of limiting the amount of supplied electron charge and allowing plasma to occur evenly on the surface of dielectric. Actually, the target or environment for sterilization is often a complex structure, so research and academic study are needed by utilizing the concept of space sterilization. In this study, the device is applied to generate DBD plasma at atmospheric pressure for disinfection due to the effectiveness in producing radicals and ozone. The generator of plasma ozone is a basic structure of dielectric barrier discharge by placing ceramic tube dielectrics and stainless steel electrical conductors at regular intervals. Various applications can be developed based on the proposed design method. Plasma ozone generation for space sterilization device is recognized as an excellent sterilization device. Through the design and verification of the device, we intend to establish an optimal design of the spatial sterilization device and provide the basis data for sterilization applications.

Effect of Curing Solution and Pre-Rust Process on Rebar Corrosion in the Cement Composite (시멘트 복합체 내부 철근 부식에 양생 용액과 철근 사전 부식이 미치는 영향)

  • Du, Rujun;Jang, Indong;Lee, Hyerin;Yi, Chongku
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.2
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    • pp.1-8
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    • 2022
  • The corrosion of reinforcement is the main reason for the performance degradation of concrete structures. The pre-rusted parts of rebar in concrete structures are vulnerable to the corrosion, especially if the structure is exposed to wet or chlorinated environments. In this study, effects of different curing solution on corrosion behavior of the pre-rusted rebars in the cement composites were investigated. HCl(3%) and CaCl2(10%) solution were utilized to accelerate the pre-rust of the rebar, and each pre-rust condition rebar including reference (RE) were placed in mortar cylinder. Three kinds of samples then were cured in CaCl2 (3%) solution and tap water respectively for 120 days. Electrochemical polarization and half-cell potential measurement were used to monitor the influence of curing water on the corrosion behavior of pre-rusted steel bar in cement composite. The surface morphology and composition of corroded steel bar were analyzed by scanning electron microscope and energy dispersive X-ray diffraction. The results show that the corrosion rates of pre-rusted samples in both curing water are higher than that of non-pre-rusted samples. The corrosion rates of RE, CaCl2 and HCl pre-rusted samples in salt water were 8.14, 4.48, 13.81 times higher than those in tap water respectively, on the 120th day.

Exploratory Study of the Applicability of Kompsat 3/3A Satellite Pan-sharpened Imagery Using Semantic Segmentation Model (아리랑 3/3A호 위성 융합영상의 Semantic Segmentation을 통한 활용 가능성 탐색 연구)

  • Chae, Hanseong;Rhim, Heesoo;Lee, Jaegwan;Choi, Jinmu
    • Korean Journal of Remote Sensing
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    • v.38 no.6_4
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    • pp.1889-1900
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    • 2022
  • Roads are an essential factor in the physical functioning of modern society. The spatial information of the road has much longer update cycle than the traffic situation information, and it is necessary to generate the information faster and more accurately than now. In this study, as a way to achieve that goal, the Pan-sharpening technique was applied to satellite images of Kompsat 3 and 3A to improve spatial resolution. Then, the data were used for road extraction using the semantic segmentation technique, which has been actively researched recently. The acquired Kompsat 3/3A pan-sharpened images were trained by putting it into a U-Net based segmentation model along with Massachusetts road data, and the applicability of the images were evaluated. As a result of training and verification, it was found that the model prediction performance was maintained as long as certain conditions were maintained for the input image. Therefore, it is expected that the possibility of utilizing satellite images such as Kompsat satellite will be even higher if rich training data are constructed by applying a method that minimizes the impact of surrounding environmental conditions affecting models such as shadows and surface conditions.

Analysis of Built and Walking Environment for Coastal Ferry Terminal using IPA -Focusing on Yeosu Coastal Ferry Terminal- (IPA를 이용한 연안여객터미널의 시설 및 보행특성 분석 -여수연안여객터미널을 중심으로-)

  • Song, Tea-Han;Kim, Hwa-Young
    • Journal of Korea Port Economic Association
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    • v.37 no.3
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    • pp.93-104
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    • 2021
  • A coastal ferries, which serve as a mode between mainland and offshore islands, are frequently used by islanders and travelers visiting islands. Therefore, it is located in a place with good accessibility to the downtown so that users can use it conveniently. However, research on the built environment and walking environment of coastal ferry terminals has not been conducted to ensure that elderly islanders and general travelers can use comfortably the coastal ferry terminal. In this study, with a focus on the coastal ferry terminal space, the walking section was set as 1)the accessibility of the coastal ferry terminal, 2)the built environment for using the coastal ferry terminal, and 3)walking environment in the ferry boarding and disembarkation at the coastal ferry terminal, and 4, 5)walking environment in the ferry. An evaluation tool was developed to measure the walking environment for each walking section, and the importance and satisfaction of users were analyzed using the IPA for the Yeosu Coastal Ferry Terminal. As a result, in the process of approaching the ferry terminal, 'convenience of using public transportation by foot' and 'convenience of using signposts guiding the location and direction of the ferry terminal' were investigated as concentrated areas. On the other hand, the built environment inside the ferry terminal and the walking environment showed that the satisfaction of the users was high. Regarding the walking environment from the ferry terminal to the ferry, the 'surface walking environment of the walking path', 'convenience of walking with luggage', 'convenience of walking in the slope section', and 'convenience of walking in the ferry ramp section' showed low satisfaction. This study can be used as basic data for improving the facilities and walking environment of Yeosu Coastal Ferry Terminal and is expected to be used as data for comparative research with other coastal ferry terminals.

Grade Analysis and Two-Stage Evaluation of Beef Carcass Image Using Deep Learning (딥러닝을 이용한 소도체 영상의 등급 분석 및 단계별 평가)

  • Kim, Kyung-Nam;Kim, Seon-Jong
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.2
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    • pp.385-391
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    • 2022
  • Quality evaluation of beef carcasses is an important issue in the livestock industry. Recently, through the AI monitor system based on artificial intelligence, the quality manager can receive help in making accurate decisions based on the analysis of beef carcass images or result information. This artificial intelligence dataset is an important factor in judging performance. Existing datasets may have different surface orientation or resolution. In this paper, we proposed a two-stage classification model that can efficiently manage the grades of beef carcass image using deep learning. And to overcome the problem of the various conditions of the image, a new dataset of 1,300 images was constructed. The recognition rate of deep network for 5-grade classification using the new dataset was 72.5%. Two-stage evaluation is a method to increase reliability by taking advantage of the large difference between grades 1++, 1+, and grades 1 and 2 and 3. With two experiments using the proposed two stage model, the recognition rates of 73.7% and 77.2% were obtained. As this, The proposed method will be an efficient method if we have a dataset with 100% recognition rate in the first stage.

Analysis of Electrochemical Properties of Sulfide All-Solid-State Lithium Ion Battery Anode Material Using Amorphous Carbon-Removed Graphite (비정질 탄소가 제거된 흑연을 이용한 황화물계 전고체 리튬이온전지 음극소재 전기화학적 특성 분석)

  • Choi, Jae Hong;Oh, Pilgun
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.58-63
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    • 2022
  • Graphite has been used as an anode material for lithium-ion batteries for the past 30 years due to its low de-/lithiation voltage, high theoretical capacity of 372 mAh/g, low price, and long life properties. Recently, all-solid-state lithium-ion batteries (ASSLB), which are composed of inorganic solid materials with high stability, have received great attention as electric vehicles and next-generation energy storage devices, but research works on graphite that works well for ASSLB systems are insufficient. Therefore, we induced the performance improvement of ASSLB anode electrode graphite material by removing the amorphous carbon present in the carbon material surface, acting as a resistive layer from the graphite. As a result of X-ray diffraction (XRD) analysis using heat treated graphite in air at 400, 500, and 600 ℃, the full width at half maximum (FWHM) at (002) peak was reduced compared to that of bare graphite, indicating that the crystallinity of graphite was improved after heat treatment. In addition, the discharge capacity, initial coulombic efficiency (ICE) and cycle stability increased as the crystallinity of graphite increased after heat treatment. In the case of graphite annealed in air at 500 ℃, the high capacity retention rate of 331.1 mAh/g and ICE of 86.2% and capacity retention of 92.7% after 10-cycle measurement were shown.

Control of the flow past a sphere in a turbulent boundary layer using O-ring

  • Okbaz, Abdulkerim;Ozgoren, Muammer;Canpolat, Cetin;Sahin, Besir;Akilli, Huseyin
    • Wind and Structures
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    • v.35 no.1
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    • pp.1-20
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    • 2022
  • This research work presents an experimental study's outcomes to reveal the impact of an O-ring on the flow control over a sphere placed in a turbulent boundary layer. The investigation is performed quantitatively and qualitatively using particle image velocimetry (PIV) and dye visualization. The sphere model having a diamater of 42.5 mm is located in a turbulent boundary layer flow over a smooth plate for gap ratios of 0≤G/D≤1.5 at Reynolds number of 5 × 103. Flow characteristics, including patterns of instantaneous vorticity, streaklines, time-averaged streamlines, velocity vectors, velocity fluctuations, Reynolds stress correlations, and turbulence kinetic energy (), are compared and discussed for a naked sphere and spheres having O-rings. The boundary layer velocity gradient and proximity of the sphere to the flat plate profoundly influence the flow dynamics. At proximity ratios of G/D=0.1 and 0.25, a wall jet is formed between lower side of the sphere and flat plate, and velocity fluctuations increase in regions close to the wall. At G/D=0.25, the jet flow also induces local flow separations on the flat plate. At higher proximity ratios, the velocity gradient of the boundary layer causes asymmetries in the mean flow characteristics and turbulence values in the wake region. It is observed that the O-ring with various placement angles (𝜃) on the sphere has a considerable alteration in the flow structure and turbulence statistics on the wake. At lower placement angles, where the O-ring is closer to the forward stagnation point of the sphere, the flow control performance of the O-ring is limited; however, its impact on the flow separation becomes pronounced as it is moved away from the forward stagnation point. At G/D=1.50 for O-ring diameters of 4.7 (2 mm) and 7 (3 mm) percent of the sphere diameter, the -ring exhibits remarkable flow control at 𝜃=50° and 𝜃=55° before laminar flow separation occurrence on the sphere surface, respectively. This conclusion is yielded from narrowed wakes and reductions in turbulence statistics compared to the naked sphere model. The O-ring with a diameter of 3 mm and placement angle of 50° exhibits the most effective flow control. It decreases, in sequence, streamwise velocity fluctuations and length of wake recovery region by 45% and 40%, respectively, which can be evaluated as source of decrement in drag force.

Crossplot Interpretation of Electrical Resistivity and Seismic Velocity Values for Mapping Weak Zones in Levees (제방의 취약구간 파악을 위한 전기비저항과 탄성파속도의 교차출력 해석)

  • Cho, Kyoung-Seo;Kim, Jeong-In;Kim, Jong-Woo;Kim, Ji-Soo
    • The Journal of Engineering Geology
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    • v.31 no.4
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    • pp.507-522
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    • 2021
  • Specific survey objectives often cannot be met using only one geophysical method, as each method's results are influenced by the specific physical properties of subsurface materials. In particular, areas susceptible to geological hazards require investigation using more than one method in order to reduce risks to life and property. Instead of analyzing the results from each method separately, this work develops a four-quadrant criterion for classifying areas of levees as safe or weak. The assessment is based on statistically determined thresholds of seismic velocity (P-wave velocity from seismic refraction and S-wave velocity from multichannel analysis of surface waves) and electrical resistivity. Thresholds are determined by subtracting the standard deviation from the mean during performance testing of this correlation technique applied to model data of four horizontal and inclined fracture zones. Compared with results from the crossplot of resistivity and P-wave velocity, crossplot analysis using resistivity and S-wave velocity data provides more reliable information on the soil type, ground stiffness, and lithological characteristics of the levee system. A loose and sandy zone (represented by low S-wave velocity and high resistivity) falling within the second quadrant is interpreted to be a weak zone. This interpretation is well supported by the N values from standard penetrating test for the central core.

Estimation and Evaluation of Reanalysis Air Temperature based on Mountain Meteorological Observation (산악기상정보 융합 기반 재분석 기온 데이터의 추정 및 검증)

  • Sunghyun, Min;Sukhee, Yoon;Myongsoo, Won;Junghwa, Chun;Keunchang, Jang
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.24 no.4
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    • pp.244-255
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    • 2022
  • This study estimated and evaluated the high resolution (1km) gridded mountain meteorology data of daily mean, maximum and minimum temperature based on ASOS (Automated Surface Observing System), AWS (Automatic Weather Stations) and AMOS (Automatic Mountain Meteorology Observation System) in South Korea. The ASOS, AWS, and AMOS meteorology data which were located above 200m was classified as mountainous area. And the ASOS, AWS, and AMOS meteorology data which were located under 200m was classified as non-mountainous area. The bias-correction method was used for correct air temperature over complex mountainous area and the performance of enhanced daily coefficients based on the AMOS and mountainous area observing meteorology data was evaluated using the observed daily mean, maximum and minimum temperature. As a result, the evaluation results show that RMSE (Root Mean Square Error) of air temperature using the enhanced coefficients based on the mountainous area observed meteorology data is smaller as 30% (mean), 50% (minimum), and 37% (maximum) than that of using non-mountainous area observed meteorology data. It indicates that the enhanced weather coefficients based on the AMOS and mountain ASOS can estimate mean, maximum, and minimum temperature data reasonably and the temperature results can provide useful input data on several climatological and forest disaster prediction studies.