• Title/Summary/Keyword: Percolation model

Search Result 75, Processing Time 0.032 seconds

Modelling of the Electrochemical Performance of Functionally Graded Fuel Cell Electrodes by Discrete Simulations

  • Schneider, L.C.R.;Martin, C.L.;Bultel, Y.;Kapelski, G.;Bouvard, D.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09b
    • /
    • pp.916-917
    • /
    • 2006
  • Solid Oxide Fuel Cell technology uses powder processes to produce electrodes with residual porosity by partially sintering a mixture of electronically and ionically conducting particles. We model porous fuel cell electrodes with 3D packings of monosized spherical particles. These packings are created by numerical sintering. Each particle-particle contact is characteristic for an ionic, electronic or electrochemical resistance. The numerical packing is then discretized into a resistor network which is solved by using Kirchhoff's current law to evaluate the electrode's electrochemical performance. We investigate in particular percolation effects in functionally graded electrodes as compared to other types of electrodes.

  • PDF

CONDUCTIVITY of a-C:H FILMS MODIFIED WITH Ag NANOCLUSTERS

  • Sarsembinov, Sh.Sh.;Mahmoud, F.A.;Prikhodko, O.Yu.;Ryaguzov, A.P.;Maksimova, S.Ya.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.07a
    • /
    • pp.403-404
    • /
    • 2005
  • The conductivity of diamond like carbon films embedded with silver nanoclusters were investigated as a function of silver concentrations in the film. By increasing the concentration of silver in the film from 0 to 20 at% the conductivity varied from $10^{-13}$ to $10^2\;ohm^{-1}\;cm^{-1}$. The data have been discussed within the model of a dielectric matrix containing conductive inclusions. The conductivity data analysis using percolation theory has been showed that percolation threshold occurred at Ag percentage in the film $x_c$ =5 at %.

  • PDF

Multiphase flow analysis in rock fractures with dynamic MMIP model

  • 지성훈;여인욱;이강근
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2002.09a
    • /
    • pp.32-35
    • /
    • 2002
  • In order to characterize the migration of DNAPL in rock fractures, the dynamic macromodified invasion percolation (DMMIP) model, that is able to reflect the viscous force of groundwater in a fracture network, is suggested. DMMIP simulations are verified against the laboratory expenments, which shows a good qualitative and quantitative agreement.

  • PDF

Development of a Cell-based Long-term Hydrologic Model Using Geographic Information System(I) -Cell-based Long-term Hydrologic Modeling- (지리정보시스템을 이용한 장기유출모형의 개발(I) -장기유출의 격자 모형화-)

  • 최진용;정하우
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.39 no.1
    • /
    • pp.64-74
    • /
    • 1997
  • A CELTHYM(CEll-based Long-term HYdrologic Model), a pre-processor and a post-processor that can be integrated with geographic information system(GIS) were developed to predict the stream flow from the small agricultural watershed on the daily basis. The CELTHYM calculates the direct runoff from a grid using SCS curve number method and then sum up all of cells with respect to a sub-catchment area belonged to a stream grid and integrated to an outlet. Base flow of a watershed outlet was computed by integrating of the base flow of each stream grid that was averaged the sub-catchment deep-percolation and calculated with the release rate. Two kind of water budget equation were used to compute the water balance in a grid that was classified into not paddy field and paddy field. One of the two equation is a soil water balance equation to account the soil moisture of the upland, forest and excluding paddy field grid. The other is a paddy water balance equation for the paddy field, calculating the ponding depth, the effective rainfall, the deep percolation and the evapotranspiration.

  • PDF

Application of a DAEM Method for a Comparison of Devolatilization Kinetics of Imported Coals (DAEM 분석 방법을 통한 국내 수입탄의 탈휘발화 반응특성 비교연구)

  • Kim, Ryang Gyoon;Song, Ju Hun;Lee, Byoung Hwa;Chang, Young June;Jeon, Chung Hwan
    • Korean Chemical Engineering Research
    • /
    • v.48 no.1
    • /
    • pp.110-115
    • /
    • 2010
  • The experiment was designed to compare pyrolysis kinetics of two different classes of imported coal. The pyrolysis behaviors of the coals were first observed with thermogravimetric analyzer(TGA). The kinetic analysis was further done based on a new distributed activation energy model(New DAEM). During the analysis, weight loss curves measured at three different heating rates were used to obtain the activation energy distribution function curve f(E) of a given coal sample where a mean activation energy is determined by its peak. The results show a significant difference in the mean activation energy between two coals for the pyrolytic reaction. The prediction of a chemical percolation devolatilization(CPD) model where the kinetics obtained from the New DAEM method were incorporated is in much closer agreement with an experimental data of TGA particularly for the bituminous coal.

Geometrically Inhomogeneous Random Configuration Effects of Pt/C Catalysts on Catalyst Utilization in PEM Fuel Cells (연료전지 촉매층 내 촉매활성도에 대한 탄소지지 백금 촉매의 기하학적 비등방성 효과에 관한 연구)

  • Shin, Seungho;Kim, Ah-Reum;Jung, Hye-Mi;Um, Sukkee
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.31 no.10
    • /
    • pp.955-965
    • /
    • 2014
  • Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

One Dimensional Heat Flow Equation Incorporated with the Vertical Water Flow in Paddy Soils I. An Analytical Solution and It's Application to Tow Different Paddy Soils with Different Percolation Rates (답토양(沓土壤)에 있어서 물 이동(移動)이 복합(複合)된 일차원(一次元) 열이동방정식(熱移動方程式)에 관(關)하여 I. 분석해(分析解)와 투수속도(透水速度)가 다른 두 답토양(沓土壤)에 대(對)한 적용(適用))

  • Jung, Yeong-Sang;Kim, Lee-Yul;Im, Jeong-Nam
    • Korean Journal of Soil Science and Fertilizer
    • /
    • v.14 no.4
    • /
    • pp.179-184
    • /
    • 1982
  • To describe a mathematical heat transfer model in saturated paddy soils, an analytical solution of the heat flow equation incorporated with the heat transfer by mass flow of water was obtained under the assumptions: 1) the diurnal (or annual) changes in temperature at a depth follow harmonic curves, 2) the temperature at the infinite depth be constant and 3) the temperatures of soil and water at the one depth be identical. The calculation of thermal diffusivities of the soil is possible with the known values of the physical parameters of each component in the soil matrix (heat capacity, density and porosity), percolation rate and the minimum and maximum temperatures at two different depths. The calculated thermal diffusivities using the solution were $9.5cm^2/hr$ for the loam soil with the percolation rate of 0.88cm/day and $13.9cm^2/hr$ for the sandy loam soil with the percolation rate of 2.64 cm/day.

  • PDF

Prediction of Nutrient Loading from Paddy Fields (II) - Model Application - (논에서의 영양물질 배출량 추정 (II) - 모형의 적용 -)

  • 김현수;정상옥;김진수;오승영
    • Magazine of the Korean Society of Agricultural Engineers
    • /
    • v.44 no.5
    • /
    • pp.106-115
    • /
    • 2002
  • The objective of this study was to evaluate the GLEAMS-PADDY model by applying it to estimate nutrients loading from paddy-field areas. Field data from Soro region of Chungbuk province during May to September 1999 were used for model application. Field data collected include the amounts of rainfall, irrigation water, drainage water, ET, and Percolation in hydrology Part. T-N and T-P concentrations in the rain water, irrigation water, ponded water, drainage water and percolated water were measured. The comparisons of observed and simulated water balance components and nutrient concentrations showed reasonably good agreements and the GLEAMS-PADDY model may be used to simulate nutrients loading from paddy fields. Futher research was suggested to include the erosion submodel in the GLEAMS-PADDY model to better simulate the nutrient behavior. In addition, the pesticide submodel also recommended to be included in order to simulate the various pesticide applied in paddy fields.

Comparison of Groundwater Recharge between HELP Model and SWAT Model (HELP 모형과 SWAT 모형의 지하수 함양량 비교)

  • Lee, Do-Hun;Kim, Nam-Won;Chung, Il-Moon
    • Journal of Korea Water Resources Association
    • /
    • v.43 no.4
    • /
    • pp.383-391
    • /
    • 2010
  • The groundwater recharge was assessed by using both SWAT and HELP models in Bocheong-cheon watershed. The SWAT model is a comprehensive surface and subsurface model, but it lacks the physical basis for simulating a soil water percolation process. The HELP model which has a drawback in simulating subsurface lateral flow and groundwater flow component can simulate soil water percolation process by considering the unsaturated flow effect of soil layers. The SWAT model has been successfully applied for estimating groundwater recharge in a number of watersheds in Korea, while the application of HELP model has been very limited. The subsurface lateral flow parameter was proposed in order to consider the subsurface lateral flow effect in HELP model and the groundwater recharge was simulated by the modified exponential decay weighting function in HELP model. The simulation results indicate that the recharge of HELP model significantly depends on the values of lateral flow parameter. The recharge errors between SWAT and HELP are the smallest when the lateral flow parameter is about 0.6 and the recharge rates between two models are shown to be reasonably comparable for daily, monthly, and yearly time scales. The HELP model is useful for estimating groundwater recharge at watershed scale because the model structure and input parameters of HELP model are simpler than that of SWAT model. The accuracy of assessing the groundwater recharge might be improved by the concurrent application of SWAT model and HELP model.

Herd behavior and volatility in financial markets

  • Park, Beum-Jo
    • Journal of the Korean Data and Information Science Society
    • /
    • v.22 no.6
    • /
    • pp.1199-1215
    • /
    • 2011
  • Relaxing an unrealistic assumption of a representative percolation model, this paper demonstrates that herd behavior leads to a high increase in volatility but not trading volume, in contrast with information flows that give rise to increases in both volatility and trading volume. Although detecting herd behavior has posed a great challenge due to its empirical difficulty, this paper proposes a new methodology for detecting trading days with herding. Furthermore, this paper suggests a herd-behavior-stochastic-volatility model, which accounts for herding in financial markets. Strong evidence in favor of the model specification over the standard stochastic volatility model is based on empirical application with high frequency data in the Korean equity market, strongly supporting the intuition that herd behavior causes excess volatility. In addition, this research indicates that strong persistence in volatility, which is a prevalent feature in financial markets, is likely attributed to herd behavior rather than news.