• 제목/요약/키워드: Percolation model

검색결과 75건 처리시간 0.022초

Modelling of the Electrochemical Performance of Functionally Graded Fuel Cell Electrodes by Discrete Simulations

  • Schneider, L.C.R.;Martin, C.L.;Bultel, Y.;Kapelski, G.;Bouvard, D.
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.916-917
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    • 2006
  • Solid Oxide Fuel Cell technology uses powder processes to produce electrodes with residual porosity by partially sintering a mixture of electronically and ionically conducting particles. We model porous fuel cell electrodes with 3D packings of monosized spherical particles. These packings are created by numerical sintering. Each particle-particle contact is characteristic for an ionic, electronic or electrochemical resistance. The numerical packing is then discretized into a resistor network which is solved by using Kirchhoff's current law to evaluate the electrode's electrochemical performance. We investigate in particular percolation effects in functionally graded electrodes as compared to other types of electrodes.

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CONDUCTIVITY of a-C:H FILMS MODIFIED WITH Ag NANOCLUSTERS

  • Sarsembinov, Sh.Sh.;Mahmoud, F.A.;Prikhodko, O.Yu.;Ryaguzov, A.P.;Maksimova, S.Ya.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.403-404
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    • 2005
  • The conductivity of diamond like carbon films embedded with silver nanoclusters were investigated as a function of silver concentrations in the film. By increasing the concentration of silver in the film from 0 to 20 at% the conductivity varied from $10^{-13}$ to $10^2\;ohm^{-1}\;cm^{-1}$. The data have been discussed within the model of a dielectric matrix containing conductive inclusions. The conductivity data analysis using percolation theory has been showed that percolation threshold occurred at Ag percentage in the film $x_c$ =5 at %.

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Multiphase flow analysis in rock fractures with dynamic MMIP model

  • 지성훈;여인욱;이강근
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 추계학술발표회
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    • pp.32-35
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    • 2002
  • In order to characterize the migration of DNAPL in rock fractures, the dynamic macromodified invasion percolation (DMMIP) model, that is able to reflect the viscous force of groundwater in a fracture network, is suggested. DMMIP simulations are verified against the laboratory expenments, which shows a good qualitative and quantitative agreement.

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지리정보시스템을 이용한 장기유출모형의 개발(I) -장기유출의 격자 모형화- (Development of a Cell-based Long-term Hydrologic Model Using Geographic Information System(I) -Cell-based Long-term Hydrologic Modeling-)

  • 최진용;정하우
    • 한국농공학회지
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    • 제39권1호
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    • pp.64-74
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    • 1997
  • A CELTHYM(CEll-based Long-term HYdrologic Model), a pre-processor and a post-processor that can be integrated with geographic information system(GIS) were developed to predict the stream flow from the small agricultural watershed on the daily basis. The CELTHYM calculates the direct runoff from a grid using SCS curve number method and then sum up all of cells with respect to a sub-catchment area belonged to a stream grid and integrated to an outlet. Base flow of a watershed outlet was computed by integrating of the base flow of each stream grid that was averaged the sub-catchment deep-percolation and calculated with the release rate. Two kind of water budget equation were used to compute the water balance in a grid that was classified into not paddy field and paddy field. One of the two equation is a soil water balance equation to account the soil moisture of the upland, forest and excluding paddy field grid. The other is a paddy water balance equation for the paddy field, calculating the ponding depth, the effective rainfall, the deep percolation and the evapotranspiration.

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DAEM 분석 방법을 통한 국내 수입탄의 탈휘발화 반응특성 비교연구 (Application of a DAEM Method for a Comparison of Devolatilization Kinetics of Imported Coals)

  • 김량균;송주헌;이병화;장영준;전충환
    • Korean Chemical Engineering Research
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    • 제48권1호
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    • pp.110-115
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    • 2010
  • 본 연구 목적은 두가지 종류의 국내 수입탄에 대한 열분해 반응율을 구하고 이를 비교하는 것이다. 이를 위해 TGA를 통하여 열분해 실험을 수행하였으며, 반응상수 분석은 New DAEM 방법을 이용하였다. 서로 다른 가열속도에서 각각 얻어진 TGA 질량변화 곡선으로부터, 활성화 에너지의 분포함수를 구한 후 최고빈도를 나타내는 활성화 에너지를 평균 활성화 에너지로 결정하였다. 그 결과 석탄의 종류에 따라 상기 반응에 대한 반응속도상수가 확실한 차이를 보였다. 이 같은 New DAEM 분석기법을 통해 얻은 반응상수를 적용시킨 CPD 모델을 가지고 예측한 결과가 TGA 실험치와 비교할 때보다 더 잘 일치함도 확인할 수 있었다.

연료전지 촉매층 내 촉매활성도에 대한 탄소지지 백금 촉매의 기하학적 비등방성 효과에 관한 연구 (Geometrically Inhomogeneous Random Configuration Effects of Pt/C Catalysts on Catalyst Utilization in PEM Fuel Cells)

  • 신승호;김아름;정혜미;엄석기
    • 한국정밀공학회지
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    • 제31권10호
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    • pp.955-965
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    • 2014
  • Transport phenomena of reactant and product are directly linked to intrinsic inhomogeneous random configurations of catalyst layer (CL) that consist of ionomer, carbon-supported catalyst (Pt/C), and pores. Hence, electrochemically active surface area (ECSA) of Pt/C is dominated by geometrical morphology of mass transport path. Undoubtedly these ECSAs are key factor of total fuel cell efficiency. In this study, non-deterministic micro-scale CLs were randomly generated by Monte Carlo method and implemented with the percolation process. To ensure valid inference about Pt/C catalyst utilization, 600 samples were chosen as the number of necessary samples with 95% confidence level. Statistic results of 600 samples generated under particular condition (20vol% Pt/C, 30vol% ionomer, 50vol% pore, and 20nm particle diameter) reveal only 18.2%~81.0% of Pt/C can construct ECSAs with mean value of 53.8%. This study indicates that the catalyst utilization in fuel cell CLs cannot be identical notwithstanding the same design condition.

답토양(沓土壤)에 있어서 물 이동(移動)이 복합(複合)된 일차원(一次元) 열이동방정식(熱移動方程式)에 관(關)하여 I. 분석해(分析解)와 투수속도(透水速度)가 다른 두 답토양(沓土壤)에 대(對)한 적용(適用) (One Dimensional Heat Flow Equation Incorporated with the Vertical Water Flow in Paddy Soils I. An Analytical Solution and It's Application to Tow Different Paddy Soils with Different Percolation Rates)

  • 정영상;김리열;임정남
    • 한국토양비료학회지
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    • 제14권4호
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    • pp.179-184
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    • 1982
  • 담수(湛水)된 논 토양(土壤)에서 열전달(熱傳達)은 전도(傳導)에 의(依)한 과정(過程)과 물 이동(移動)에 의(依)한 과정(過程)이 복합(複合)되어 있다. 이 열전달(熱傳達) 과정(過程)을 방정식(方程式)으로 나타내고 그 분석해(分析解)를 구(求)하였다. 분석해(分析解)는 1) 온도(溫度)의 일교차(日較差)(또는 연교차(年較差))는 Sine 함수식(含數式)에 따르며 2) 무한(無限)한 깊이에서의 온도(溫度)는 변(變)하지 않고 3) 일정(一定) 깊이에서의 수온(水溫)과 지온(地溫)은 동일(同一)하다는 가정하(假定下)에서 이루어졌다. 토양(土壤)의 열보유능(熱保有能), 용적밀도(容積密度), 공극율(孔隙率)과 투수속도(透水速度) 및 두지점(地點)에서의 최고(最高) 최저온도(最低溫度)를 알면 본해(本解)를 이용(利用)하여 토양(土壤)의 열광산계수 D; Thermal Diffusity, $cm^2/hr$)를 계산(計算)할 수 있다. 본(本) 연구(硏究)에서 얻어진 열광산 계수(係數)는 투수계수(透水係數)가 0.88cm/day인 양토(壤土)에서 $9.5cm^2/hr$, 투수계수(透水係數)가 2.64cm/day인 사양토(砂壤土)에서 $13.9cm^2/hr$이었다.

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논에서의 영양물질 배출량 추정 (II) - 모형의 적용 - (Prediction of Nutrient Loading from Paddy Fields (II) - Model Application -)

  • 김현수;정상옥;김진수;오승영
    • 한국농공학회지
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    • 제44권5호
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    • pp.106-115
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    • 2002
  • The objective of this study was to evaluate the GLEAMS-PADDY model by applying it to estimate nutrients loading from paddy-field areas. Field data from Soro region of Chungbuk province during May to September 1999 were used for model application. Field data collected include the amounts of rainfall, irrigation water, drainage water, ET, and Percolation in hydrology Part. T-N and T-P concentrations in the rain water, irrigation water, ponded water, drainage water and percolated water were measured. The comparisons of observed and simulated water balance components and nutrient concentrations showed reasonably good agreements and the GLEAMS-PADDY model may be used to simulate nutrients loading from paddy fields. Futher research was suggested to include the erosion submodel in the GLEAMS-PADDY model to better simulate the nutrient behavior. In addition, the pesticide submodel also recommended to be included in order to simulate the various pesticide applied in paddy fields.

HELP 모형과 SWAT 모형의 지하수 함양량 비교 (Comparison of Groundwater Recharge between HELP Model and SWAT Model)

  • 이도훈;김남원;정일문
    • 한국수자원학회논문집
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    • 제43권4호
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    • pp.383-391
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    • 2010
  • 본 연구에서는 SWAT 모형과 HELP 모형을 이용하여 보청천 유역의 지하수 함양량을 산정하였다. SWAT 모형은 지표수 및 지하수 성분을 모두 고려할 수 있는 물순환 모형이지만, 토양층에 대한 침루과정의 물리적 해석이 미흡하다. 반면에 HELP 모형은 중간유출 및 지하수 유출성분을 모의하지 못하지만, 토양층에서의 비포화흐름을 고려하여 침루과정을 해석할 수 있다. 국내유역에서 함양량 산정을 위해 SWAT 모형은 여러 유역에서 성공적으로 적용되어 왔지만, HELP 모형의 국내유역에 대한 적용은 매우 미흡하였다. HELP 모형의 적용을 위하여 중간유출계수를 제안하였고, 수정된 지수형감쇠 가중함수를 이용하여 지하수 함양량을 산정하였다. HELP 모형의 함양량은 중간유출계수 값에 따라서 많은 차이를 나타내었다. 중간유출계수 값이 0.6인 경우에 HELP 모형과 SWAT 모형사이의 함양량 오차가 가장 작았으며 일, 월, 연단위 등 다양한 시간규모에 대하여 두 모형사이의 함양량은 비교적 잘 일치하였다. HELP 모형은 SWAT모형에 비하여 모형구조가 비교적 간단하고 입력변수가 적게 요구되므로 지하수 함양량 산정에 유용하게 적용될 수 있으며, SWAT 모형과 HELP 모형을 병행하여 적용하면 지하수 함양량 산정의 신뢰도가 향상될 것으로 판단된다.

Herd behavior and volatility in financial markets

  • Park, Beum-Jo
    • Journal of the Korean Data and Information Science Society
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    • 제22권6호
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    • pp.1199-1215
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    • 2011
  • Relaxing an unrealistic assumption of a representative percolation model, this paper demonstrates that herd behavior leads to a high increase in volatility but not trading volume, in contrast with information flows that give rise to increases in both volatility and trading volume. Although detecting herd behavior has posed a great challenge due to its empirical difficulty, this paper proposes a new methodology for detecting trading days with herding. Furthermore, this paper suggests a herd-behavior-stochastic-volatility model, which accounts for herding in financial markets. Strong evidence in favor of the model specification over the standard stochastic volatility model is based on empirical application with high frequency data in the Korean equity market, strongly supporting the intuition that herd behavior causes excess volatility. In addition, this research indicates that strong persistence in volatility, which is a prevalent feature in financial markets, is likely attributed to herd behavior rather than news.