• 제목/요약/키워드: Partition function

검색결과 229건 처리시간 0.023초

Determination and Temperature Dependence of n-Octanol/Water Partition Coefficients for Seven Sulfonamides from (298.15 to 333.15) K

  • Congliang, Zhang;Yan, Wang;Fuan, Wang
    • Bulletin of the Korean Chemical Society
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    • 제28권7호
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    • pp.1183-1186
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    • 2007
  • A shake-flask method was used to determine the n-octanol/water partition coefficients of sulfamethazine, sulfadimethoxine, sulfamethoxydiazine, sulfamonomethoxine, sulfamethoxazole, sulfaquinoxaline and sulfachloropyrazine from (298.15 to 333.15) K. The results showed that the n-octanol/water partition coefficient of each sulfonamide decreased with the increase of temperature. Based on the fluid phase equilibrium theory, the thermodynamic relationship of n-octanol/water partition coefficient depending on the temperature is proposed, and the changes of enthalpy, entropy, and the Gibbs free energy function for sulfonamides partitioning in n-octanol/ water are determined, respectively. Sulfonamides molecules partitioning in n-octanol/water is mainly an enthalpy driving process, during which the order degrees of system increased. The temperature effect coefficient of n-octanol/water partition coefficient is discussed. The results show that its magnitude is the same as that of values in the literature.

퍼지 클러스터링을 이용한 확률분포함수 기반의 다중문턱값 선정법 (Selection Method of Multiple Threshold Based on Probability Distribution function Using Fuzzy Clustering)

  • 김경범;정성종
    • 한국정밀공학회지
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    • 제16권5호통권98호
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    • pp.48-57
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    • 1999
  • Applications of thresholding technique are based on the assumption that object and background pixels in a digital image can be distinguished by their gray level values. For the segmentation of more complex images, it is necessary to resort to multiple threshold selection techniques. This paper describes a new method for multiple threshold selection of gray level images which are not clearly distinguishable from the background. The proposed method consists of three main stages. In the first stage, a probability distribution function for a gray level histogram of an image is derived. Cluster points are defined according to the probability distribution function. In the second stage, fuzzy partition matrix of the probability distribution function is generated through the fuzzy clustering process. Finally, elements of the fuzzy partition matrix are classified as clusters according to gray level values by using max-membership method. Boundary values of classified clusters are selected as multiple threshold. In order to verify the performance of the developed algorithm, automatic inspection process of ball grid array is presented.

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MEASURE INDUCED BY THE PARTITION OF THE GENERAL REGION

  • Chang, Joo Sup;Kim, Byoung Soo
    • Korean Journal of Mathematics
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    • 제21권3호
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    • pp.237-246
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    • 2013
  • In this paper we first consider the partition of the general region made by the monotonically increasing and continuous function and then obtain the measure from the partition of the region. The results obtained here is a little bit different from the previous results in [1, 2, 3] and finally we discuss the difference.

그래프분할문제 (The Graph Partition Problem)

  • 명영수
    • 한국경영과학회지
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    • 제28권4호
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    • pp.131-143
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    • 2003
  • In this paper, we present a survey about the various graph partition problems including the clustering problem, the k-cut problem, the multiterminal cut problem, the multicut problem, the sparsest cut problem, the network attack problem, the network disconnection problem. We compare those problems focusing on the problem characteristics such as the objective function and the conditions that the partitioned clusters should satisfy. We also introduce the mathematical programming formulations, and the solution approaches developed for the problems.

NOTE ON MODULAR RELATIONS FOR THE ROGER-RAMANUJAN TYPE IDENTITIES AND REPRESENTATIONS FOR JACOBIAN IDENTITY

  • CHAUDHARY, M.P.;CHOI, JUNESANG
    • East Asian mathematical journal
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    • 제31권5호
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    • pp.659-665
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    • 2015
  • Combining and specializing some known results, we establish six identities which depict six modular relations for the Roger-Ramanujan type identities and two equivalent representations for Jacobian identity expressed in terms of combinatorial partition identities and Ramanujan-Selberg continued fraction. Two q-product identities are also considered.

액체 할로겐의 구조에 관하여 (The Significant Structures of Liquid Halogens)

  • 박형석;장세헌
    • 대한화학회지
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    • 제7권2호
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    • pp.179-181
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    • 1963
  • The partition function of liquid halogens is developed applying the significant liquid structure theory proposed by H. Eyring and co-workers. The parameters in the partition function are determined by triple point technique which was proposed by the authors in the previous paper, and also the thermodynamic properties and the surface tension are calculated by the method therein.

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액체의 구조에 관하여 -새로운 Parameter 결정법- (The Theory of Significant Structure of Liquids : A New Method of Fixing Parameters)

  • 박형석;장세헌
    • 대한화학회지
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    • 제7권2호
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    • pp.174-178
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    • 1963
  • The new method to determine the parameters in the liquid partition function of H. Eyring and co-workers is proposed, in which method the equilibrium condition of the three phases and the boundary condition of the liquid partition function at the triple point are used. The calculated thermodynamic properties using the new determined parameters are agreed well with the observed values.

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Calculation of Thermodynamic Properties Through the Use of two New Analytical Expressions for the Partition Function of the Morse Oscillator

  • Glossman, Daniel M.;Castro, Eduardo A.;Fernandez, Francisco M.
    • Bulletin of the Korean Chemical Society
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    • 제5권4호
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    • pp.145-149
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    • 1984
  • The entropy and heat capacity are calculated for the Morse oscillator model in order to test the quality of the partition function recently deduced by two of us. It is found that these analytical expressions are more reliable than the usually accepted one and give better results in the calculation of thermodynamic properties.

정사각형 밀폐공간내에서 수평격판에 의한 자연대류의 진동현상 (Oscillatory Motion of Natural Convection in a Square Enclosure with a Horizontal Partition)

  • 김점수;정인기;송동주
    • 설비공학논문집
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    • 제5권4호
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    • pp.285-294
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    • 1993
  • An oscillatory motion of natural convection in a two-dimensional square enclosure fitted with a horizontal partition is investigated numerically. The enclosure was composed of the lower hot and the upper cold horizontal walls and the adiabatic vertical walls, and a partition was positioned perpendicularly at the mid-height of one vertical insulated wall. The governing equations are solved by using the finite element method with Galerkin method. The computations were carried out with the variations of the partition length and Rayleigh number based on the temperature difference between two horizontal walls and the enclosure height with water(Pr=4.95). As the results, an oscillatory motion of natural convection has perfectly shown the periodicity with the decrease of Rayleigh number, and the stability was reduced to a chaotic state with the increase of Rayleigh number. The period of oscillation gets shorten with the decrease of the partition length and the increase of Rayleigh number. The frequency of oscillation obtained by the variations of stream function is more similar to the experimental results than that of the average Nusselt number. The stability of oscillation grows worse with the increase of Rayleigh number. The transition Rayleigh number for the chaos is gradually decreased with the increase of the partition length.

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이중 공동의 고유 주파수 최대/최소화를 위한 위상 최적화 기반 격벽 설계 (Topology-optimization-based Partition Design for Maximizing or Minimizing the Eigenfrequency of a Double Cavity)

  • 이진우;김윤영
    • 한국소음진동공학회논문집
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    • 제18권11호
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    • pp.1118-1127
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    • 2008
  • The position and size of holes in the partition of a double cavity are known to strongly affect the eigenfrequency of the longitudinal eigenmodes of the double cavity. To maximize or minimize the eigenfrequency of the hole-partitioned double cavity, two acoustical topology optimization problems are formulated and solved. While two sub-cavities are filled with air, a partition between them is assumed to consist of sub-partitions of variable acoustical properties. One design variable is assigned to each sub-partition, whose material properties are interpolated as those of an intermediate material between air and a rigid body. The penalty parameter of the used interpolation function is adjusted to obtain a distinct air and rigid body distribution at the converged stage in each acoustical topology optimization problem. A special attention is paid to the selection of initial values of design variables to obtain solutions as close to global optimum and symmetric as possible. To show numerical characteristics of these optimization problems, the formulated problems are first solved for the one-dimensional partition design domain and then for the two-dimensional partition design domain.