• Title/Summary/Keyword: Partition

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Evaluation of Removal Properties of Cu(II) from Aqueous Solutions by Inflated Vermiculites (팽창질석에 의한 수용액내의 구리 제거능 평가)

  • Song, Jaehong;Lee, Junki;Kim, Seogku;Lee, Taeyoon
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.7
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    • pp.25-32
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    • 2009
  • The main objective of this study was to examine the removal properties of Cu from water by inflated vermiculites. The component of vermiculites was analyzed by XRF and the concentration of Copper ion was measured by UV-VIS. Serial batch Kinetic tests and batch sorption tests were conducted to determine the removal characteristics for Cu in aqueous solutions. The result shows that removal rate, $K_{obs}$, of Cu are 0.73, 1.52, and 1.71 for initial pH 3, pH 4, pH 5, respectively, and are 3.19, 1.90, and 0.73 for the initial concentration of $1mg\;L^{-1}$, $5mg\;L^{-1}$, $10mg\;L^{-1}$, respectively. It leads to the conclusion that the removal rates are inversely proportional to the initial Cu concentration and are increased proportionally to the initial pHs. Finally, Sorption data were correlated with both Langmuir and Freundlich isotherms. As a result, Langmuir and Freundlich models were well fitted to batch isotherm data with good values of the determination coefficient. but the determination coefficient value for the Freundlich model fit was slightly higher than that of Langmuir model (0.965 for the Freundlich model and 0.936 for the Langmuir model). Using the Langmuir model, the maximum sorption capacity ($Q_{max}$), Freundlich partition coefficient, and the numerical value of n wrer estimated as $1,250mg\;kg^{-1}$, $635.1L\;kg^{-1}$ and 1.69, respectively. These results show that the inflated vermiculites could be used as an excellent adsorbent for copper contained in various types of aqueous solutions.

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A Study on CBR Characteristics of National Highway in Yeongnam Region (영남지역 국도에 사용된 흙의 CBR 특성에 관한 연구)

  • Park, Yeong-Mog;Lee, Go-Hyeun;Kim, Nak-Seok;Cho, Gyu-Tae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.3
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    • pp.535-543
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    • 2016
  • This study has been carried out to evaluate the CBR characteristics and the correlations among every soil properties of National road in Yeongnam region. Total of 480 soil samples were collected from 41 administrative districts for more than 30 years. Their physical and mechanical properties such as natural water content, the Atterberg limit, No. 200 sieve passing, the compaction test and the CBR test results were involved. The soils in Yeongnam region, SM, SC, SP and CL by USCS have predominated approximately 79%. The test results show that average CBR values of gravel and sand range from 12.7% to 20.3% and those of silt and clay range from 4.8% to 7.1%. It means that average CBR values of fine grained soils are less than a half of coarse grained one. Natural water content, No. 200 sieve passing, optimum moisture content and maximum dry density of soils are well correlated with CBR values. Especially, it presents that No. 200 sieve passing is the best correlation factor with CBR value. If consider the partition off this region into 6 zones of classified by mother rock, the correlation between CBR value and every soil properties tends to increase. It is suggested that tables, figures and the regressions described in this paper may be available for designers and engineers to understand the characteristics of an embankment materials in Yeongnam region.

Anti-inflammatory and anti-cancer activities of sterol rich fraction of cultured marine microalga Nannochloropsis oculata

  • Sanjeewa, Kalu Kapuge Asanka;Fernando, Ilekuttige Priyan Shanura;Samarakoon, Kalpa W.;Lakmal, Hetti Handi Chaminda;Kim, Eun-A;Kwon, O-Nam;Dilshara, Matharage Gayani;Lee, Joon-Baek;Jeon, You-Jin
    • ALGAE
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    • v.31 no.3
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    • pp.277-287
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    • 2016
  • Five fractions separated from Nannochloropsis oculata using solvent-solvent partition chromatography of 80% methanolic extract of N. oculata (NOM) followed by the open silica column chromatography of its hexane fraction (NOMH) for the anti-inflammatory on RAW 264.7 cells and anti-cancer activities on HL-60, A-549, HEP-3B, HCT-116, and SW-480 cancer cells. All the five fractions showed potential anti-inflammatory activities against lipopolysaccharide-stimulated RAW 264.7 macrophages cells with IC50 values less than 6.25 μg mL−1. Moreover, 90% n-hexane column elution of NOMH (NOMH90) down-regulated lipopolysaccharide-stimulated protein levels of inducible nitric oxide synthase and cyclooxygenase-2. Furthermore, NOMH90 showed marked cytotoxic effect on the HL-60 cells with IC50 value of 23.58 ± 0.09 μg mL−1. In addition, Hoechst 33342 cell permeable dye used to visualize the apoptosis nucleus and cell cycle analysis measured Sub-G1 DNA contents to confirm reduction of the cell viability in NOMH90 treated cells due to induction of apoptosis in HL60. These results are quite related to the phytosterol contents of the NOMH fractions and the results suggest N. oculata extracts might be useful as potential sources of natural anti-inflammatory and anti-cancer compounds. In conclusion, the sterol content in N. oculata might provide a promising role in future medicines in anti-inflammatory and anti-cancer.

Design on the large section of station tunnel under shallow overburden (저토피고 대단면 정거장터널의 설계)

  • Jeong, Yun-Young;Choi, Hae-Joon;Kim, Byung-Ju;Yu, Bong-Won;Kim, Yong-Il;Oh, Sung-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.2
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    • pp.171-182
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    • 2007
  • For minimizing the effect on the focus of civil traffic and environment conditions related to the excavation at the traffic jamming points, an underground station tunnel was planned with 35.5 m in length and bigger area than $200\;m^2$ in sedimentary rock mass. It faced the case that the overburden was just under 13 m. Not based on a pattern design but on the case histories of similar projects and arching effect, the design of large section tunnel under shallow overburden was investigated on three design subjects which are shape effect on the section area, application method of support pressure, and supporting and tunnel safety. According to the mechanical effect from section shape, a basic design and a preliminary design was obtained, and then supporting method of large section was planned by the supporting of NATM and a pipe roof method for subsidence prevention and mechanical stability. From the comparative study between both designs, it was found that the basic design was suitable and acceptable for the steel alignment of tunnel lining, safety and the design parameter restricted by the limit considered as partition of the excavation facilities. Through the analysis result of preliminary design showing the mechanical stability without stress concentration in tunnel arch level, it also was induced that shape effect of the large section area and yielding load obtained from deformation zone in the surrounding rock mass of tunnel have to be considered as major topics for the further development of design technique on the large section tunnel.

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The Stereospecific Analysis of the Triacylglycerols of Ginkgo Nut Oils by High-Performace Liquid Chromatography(HPLC) in the Silver Ion and Reversed Phase Modes (銀Ion 및 역상(逆相) HPLC를 이용(利用)한 입체이성체적(立體異性體的) 분석(分析)에 의한 은행종실유(銀杏種實油)의 트리글리세리드의 분자종(分子種)에 관한 연구(硏究))

  • Joh, Yong-Goe;Woo, Hyo-Kyeng;Kim, Hoon-Sook
    • Journal of the Korean Applied Science and Technology
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    • v.14 no.1
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    • pp.61-76
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    • 1997
  • Triacylglycerols of the seeds of Ginkgo biloba have been resolved by high-performace liquid chromatography(HPLC} in the silver-ion and reverse-phase modes. The fatty acids were identified by a combination of capillary gas chromatography and gas-chromatography /mass spectrometry as the methyl and /or picolinyl ester. The main components are $C_{18:2{\omega}6}$(39.0mol%), $C_{18:1{\omega}7}$(asclepic acid 21.5mol%), and $C_{18:1{\omega}9}$(oleic acid, 13.8mol%). Considerable amounts of unusual acid such as $C_{20:3{\Delta}^{5,11,14}$ (5.7mol%), $C_{18:2{\Delta}^{5,9}$(2.8mol%), and $C_{18:3}{\Delta}^{5,9,12}$(1.6mol%), were checked. In addition, an anteiso-branched fatty acid, 14-methylhexadecanoic acid, was also present as a minor component(0.9 mol%). The triacylglycerols were separated into 17 fractions by reverse-phase HPLC, and the fractionation was achieved according to the partition numnber(PN) in which a ${\Delta}^5$-non methylene interrupted double bond($^5$-NMDB) showed different behaviour from a methylene interrupted double bond in a molecule with a given cahinlength. Silver-ion HPLC exhibited excellent resolution in which fractions(23 fractions) were resolved on the basis of the number and configuration of double bonds. In this instance, the strength of interaction of a ${\Delta}^5$-NMDB system with silver ions seemed to be weaker than a methylene interrupted double bond system. The principal triacylglycerol species are as follows ; $(C_{18:2{\omega}6)2}/C_{18:1{\omega}7}$, $C_{18:1{\omega}9}/C_{18:1{\omega}7}/C_{18:2{\omega}6}$, $(C_{18:1{\omega}7)2}/C_{18:2{\omega}6}$, $C_{16:1{\omega}7}/C_{18:1{\omega}9}/C_{20:3}{\Delta}^{5,11,14}$, $C_{16:1{\omega}7}/C_{18:1{\omega}7}/C_{20:3}{\Delta}^{5,11,14}$, $C_{18:1{\omega}9}/C_{18:1{\omega}7}/C_{18:2{\omega}6}$, $C_{18:1{\omega}9}/C_{18:2}{\Delta}^{5,5}/C_{20:3}{\Delta}^{5,11,14}$, $(C_{18:1{\omega}7)2}/C_{18:2{\omega}6}$ and $(C_{18:1{\omega}9)2}/C_{18:2{\omega}6}$, while simple triacylglycerols without $C_{18:2{\omega}6})_3$ were not present. Stereospecific analysis showed that fatty acids with ${\Delta}^5$-NMDB system and saturated chains were predominantly located at the site of sn-3 carbon of glycerol backbones. It is evident that there is asymmetry in the distribution of fatty acids in the TG molecules of Ginkgo nut oils.

Use of Artificial Nest Boxes of Tits in Coniferous and Deciduous Forests (침엽수림과 활엽수림 지역에서 박새류의 입공새집 이용)

  • Rhim, Shin-Jae;Son, Seung Hun;Kim, Min-Jin;Kang, Jeong-Hoon
    • Journal of Korean Society of Forest Science
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    • v.97 no.1
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    • pp.83-87
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    • 2008
  • This study was conducted to clarify the use of artificial nest boxes of tits in coniferous and deciduous forests from March to June 2006 and 2007. Tree species richness, tree species diversity and total basal area were higher in deciduous forest than in coniferous forest. Except the bush-ground layer (<1 m), the other vertical layers were more developed in deciduous forest. Varied tit Parus varius, marsh tit P. palustris, coal tit P. ater and major tit P. major used the artificial nest boxes in this study. Number of breeding pairs of tits were higher in deciduous than in coniferous forest. Clutch size, brood size and breeding success of coal tits were higher in coniferous forest. Brood size and breeding success of major tits were higher in deciduous forest. Characteristics of habitat and niche partition would be influenced on tits' use of artificial nest boxes. The more detailed researches on artificial nest boxes would be needed for management and conservation of birds.

The Growth Inhibitory Effects of Atrina Pecitinata Fractions on Cancer Cell Lines (암세포주 성장 억제에 미치는 키조개 분획물의 영향)

  • Park Soune-Young;Shin Mi-Ok;Lee Sang Hyun;Bae Song-Ja
    • Journal of Nutrition and Health
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    • v.38 no.4
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    • pp.307-312
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    • 2005
  • We investigated the growth inhibitory effects of Atrina pecitinata (AP) on the proliferation in human cancer cell lines in vitro. AP was extracted with methanol which was further fractionated into four different types: methanol (APMM), haxane (APMH), butanol (APMB), and aquous layers (APMA). Among various partition layers, the APMM showed the strongest cytotoxic effects on all cancer cell lines which we used. In the MTT assay of AP fractions, the growth inhibitory effects was increased in proportion to its concentration. We observed quinone reductase (QR) induced effects in all fraction layers of AP on HepG2 cells. The QR induced effects of APMM on HepG2 cell at 80 $\mu$g/mL concentration indicated 2.0 with a control value of 1.0.

Evaluation of Extractants for Bio-butanol Extraction Fermentation Using Organic Solvents and Ionic Liquids (유기용매와 이온성액체를 이용한 바이오 부탄올 추출발효 용매 선정 평가)

  • Cho, Min-Ok;Lee, Sun-Mi;Sang, Byoung-In;Um, Young-Soon
    • KSBB Journal
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    • v.24 no.5
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    • pp.446-452
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    • 2009
  • Oleyl alcohol, butyl butyrate, and two different ionic liquids were evaluated for the extraction of butanol from culture broth without toxic effect to cells. The tested solvents showed more than 50% extraction efficiency, and oleyl alcohol was chosen as the best extractant for butanol among the used extractants with a partition coefficient of 2.89. When oleyl alcohol was used as an extractant, more than 80% of butanol was extracted in the wide range of butanol concentrations (1-20 g/L) and pH values (pH 4-5.5). In extractive fermentation using oleyl alcohol only, there was 11% more butanol production and glucose consumption when compared to that without extractive fermentation, implicating a reduced inhibitory effect of butanol due to butanol removal to the oleyl alcohol phase. In addition, oleyl alcohol did not inhibit cell growth, while a mixture of oleyl alcohol and butyl butyrate with the volume ratio of 9:1~7:3 inhibited either butanol production or cell growth significantly due to the toxicity of butyl butyrate to cells. In conclusion, oleyl alcohol can be used as an efficient and non-toxic solvent for extractive fermentation for butanol production.

A Survey on the Consumer Preferences for Korean Rice Cake Packaging in the Seoul Metropolitan Area (떡 포장 개선을 위한 국내 수도권 지역 소비자의 기호도 조사)

  • Choi, Woo-Suk;Park, Sang-Kyu;Lee, Youn-Suk
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.3
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    • pp.418-429
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    • 2012
  • In this study we surveyed the packaging preferences of consumers for Korean rice cakes as current commercial products in Korea. The questionnaire was developed from a preliminary investigation of typical rice cake packaging patterns and sent to 2332 residents in Korea by random sampling mail. The questionnaire contained questions on the preferences of interior design in packaging, opening methods, individually separated types, printing position, packaging methods, and packaging materials such as paper and plastic. There were responses from 304 residents. The collected data was analyzed by an SPSS package program. Most of the packaging used for Korean rice cakes was plastic (58.9%) which was used for packaging materials and stretch wrap (42.9%) as packing methods. The results showed the preference was the perforated line type used by hand for opening a packaging and interior packaging design with 2~3 partitions. Most respondents expressed an interest in using individual packaging and having printing directly on the packaging. Also, the respondents preferred the packaging design that let them see the contents of a package. Based on the results of the questionnaire, this paper suggested that most consumers would prefer to choose a packaging system with a partition design in a plastic container, individually separated products, and a transparent container for Korean rice cakes. The results of packaging preferences could provide important information for suitable packaging development for Korean rice cakes. Further research should be conducted to improve the shelf life of Korean rice cakes with functional packaging systems such as modified atmosphere packaging or anti-microbial packaging.

A Load Balancing Method using Partition Tuning for Pipelined Multi-way Hash Join (다중 해시 조인의 파이프라인 처리에서 분할 조율을 통한 부하 균형 유지 방법)

  • Mun, Jin-Gyu;Jin, Seong-Il;Jo, Seong-Hyeon
    • Journal of KIISE:Databases
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    • v.29 no.3
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    • pp.180-192
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    • 2002
  • We investigate the effect of the data skew of join attributes on the performance of a pipelined multi-way hash join method, and propose two new harsh join methods in the shared-nothing multiprocessor environment. The first proposed method allocates buckets statically by round-robin fashion, and the second one allocates buckets dynamically via a frequency distribution. Using harsh-based joins, multiple joins can be pipelined to that the early results from a join, before the whole join is completed, are sent to the next join processing without staying in disks. Shared nothing multiprocessor architecture is known to be more scalable to support very large databases. However, this hardware structure is very sensitive to the data skew. Unless the pipelining execution of multiple hash joins includes some dynamic load balancing mechanism, the skew effect can severely deteriorate the system performance. In this parer, we derive an execution model of the pipeline segment and a cost model, and develop a simulator for the study. As shown by our simulation with a wide range of parameters, join selectivities and sizes of relations deteriorate the system performance as the degree of data skew is larger. But the proposed method using a large number of buckets and a tuning technique can offer substantial robustness against a wide range of skew conditions.