• 한국대기환경학회지
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• 제30권3호
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• pp.261-269
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• 2014

This study focused on the performance of the newly developed hybrid filter system to capture fine particulate matter and mercury compounds in a coal-fired power plant. The hybrid filter system combining bag-filter and electrostatic precipitator had been developed to remove fine particulate matter. However, it would have a good performance to control mercury compounds as well. In Hybrid filter capture system, the total removal efficiency of total mercury compounds consisting of particulate mercury ($Hg_p$), oxidized mercury ($Hg^{2+}$), and elemental mercury ($Hg^0$) was 66.2%. The speciation of mercury compounds at inlet and outlet of Hybrid filter capture system were 1.3% and 0% of $Hg_p$, 85.2% and 68.1% of $Hg^0$, and 13.5% and 31.9% of $Hg^{2+}$, respectively. In hybrid filter capture system injected with 100% of flue-gas, the removal efficiency of total mercury was calculated to increase to 93.5%.

• 한국입자에어로졸학회지
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• 제6권4호
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• pp.173-183
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• 2010

The high temperature pleated filter bags which were used during this study were made of pleated nonwoven fabric of heat and acid resistant polysulfonate fibers which can withstand the heat up to $300^{\circ}C$ and have a filtration area which is 3 to 5 times larger than the conventional round filter bags. Cartridge module packed with 3 kind of the sulfur impregnated activated-carbon based sorbents were inserted in the inner of the pleated filter bag. This type of pleated filter bag was designed to remove not only the particulate matter but also the gaseous elemental mercury. The electrostatic precipitator part can enhance the particulate removal efficiency and reduce the pressure drop of the pleated filter bag by agglomerated particles to form a more porous dust layer on the surface of the pleated bag which is increased the filter bag cleaning efficiency. In addition, the most of particles are separated from the flue gas stream through the cyclone and the electrostatic precipitator part which were installed at the lower part and main body part of the convergence particulate collector, respectively. Thus reduce particulate loading of the high temperature pleated filter bags were applied in this study to analyze the removal characteristics of particulate matter and gaseous elemental mercury.

• Journal of Preventive Medicine and Public Health
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• 제12권1호
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• pp.49-55
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• 1979

In order to investigate air pollution by heavy metals in Seoul city, the suspended particulates in the atmosphere were sampled with high volume air sampler in industrial area(Ku Ro Dong), commerical(Kwang Hwa Moon) and residential(Shin Chon Dong) from January to November, 1977. The sampled suspended particulates were digested and extracted from suspended particulates with the acidic solution by reflux-extraction technique, and were measured by atomic absorption spectrophotometry. And mercury was measured by mercury analyzer applying the reducing sublimation technique. Among heavy metals analyzed, the iron was identified at the highest level in the suspended particulates and the chromium was the least. Through the surveyed area, the concentration of heavy metals of the industrial area was comparatively high among others and the commercial was the second. It was detected that lead was the most concentrated in the suspended particulate of the commercial area, that might be caused of the traffic emissions. The seasonal variations were analyzed and the correlations among heavy metals and total suspended particulate were also calculated. Especially, the iron was highly correlated with total suspended particulate in all the surveyed areas.

• 대한환경공학회지
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• 제33권3호
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• pp.202-211
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• 2011

본 연구는 소양호를 대상으로 장기간 동안 다매체 내 수은 농도 분포를 조사하였으며 소양호 총수은(TM; total mercury) 농도는 $1.17{\pm}1.09ng/L$ 나타났다. 표층수 총 수은 농도를 보면 시간적 및 공간적 변이에 대한 통계적 유의성을 찾아볼 수 없었으나, 탁도 및 입자성 유기탄소(particulate organic carbon; POC)의 농도와 뚜렷한 양의 상관성(P-value<0.01)이 있는 것으로 관측되었다. 또한 소양호의 경우 수은 유입원이 선행연구에서 언급된 대기 침적보다는 장마철 runoff로 인한 유입이 더 중요하다는 것을 나타낸다. 어류 내 수은은 한강과 소양호에서 총 22종의 어류를 채취하였으며, 어류 내 평균 총수은 농도는 0.073 ppm(습중량)으로 나타나, 우리나라의 기준치(0.5 ppm) 및 미국 EPA의 기준치(0.3 ppm)에 비해 낮은 농도를 보였다. 그러나 미국 EPA의 RfD(reference dose)를 바탕으로 본 연구에서 계산된 적정 기준치인 0.07 ppm을 상회하는 어류가 전체의 42%를 차지해 우리나라만의 어류섭취 관리대책이 필요하다. 어류를 채취한 세 지점, 한강, 신이리, 양구는 동일한 종에서 뚜렷하게 다른 농도 분포를 보였는데, 상류일수록 더 높은 농도를 나타냈다. 이는 호수의 부영양화 차이로 인한 지점별 어류 성장 속도의 차이가 원인인 것으로 생각된다. 소양호 저서퇴적물의 수은 농도 분포는 $69.9{\sim}98.3{\mu}g/kg$으로 나타나 미국 미네소타 주의 Voyageurs National Park에서의 연구 결과($102{\sim}364{\mu}g/kg$)보다 약간 낮게 나타났다.

• 한국대기환경학회지
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• 제24권6호
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• pp.693-703
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• 2008

The important source of the mercury in water-column is the influx of atmosphere mercury, via dry and wet deposition. In this study, wet deposition of mercury was estimated to be $14.56{\mu}g/m^2$ during 15 months at the Lake Soyang, which is a little higher than those observed in the several rural US Mercury Deposition Network (MDN) sites with similar precipitation depth. The mercury concentration in precipitation did not show a positive correlation with atmospheric RGM (reactive gaseous mercury) concentration, while maintaining good correlation with atmospheric $PM_{2.5}$ at Soyang Dam. This result suggests that the contribution of particulate Hg to the total Hg wet deposition should be more significant than that of RGM. In this study, both precipitation depth and precipitation type affected the amount of wet deposition and the concurrent mercury levels in precipitation. There was generally an inverse relationship between precipitation depth and Hg concentration in precipitation. Precipitation type was another factor that exerted controls on the Hg concentration in precipitation. As a result, the highest concentration of Hg was observed in snow, followed by in mixture (snow+rain) and in rain.

• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1932-1936
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• 2008

A new analytical method using 1-(2-pyridylazo)-2-naphthol modified $SiO_2$ nanoparticles as solid-phase extractant has been developed for the preconcentration of trace amounts of mercury(II) in different water samples. Conditions of the analysis such as preconcentration time, effect of pH, sample volumes, shaking time, elution conditions and effects of interfering ions for the recovery of analyte were investigated. The adsorption capacity of nanometer $SiO_2$-PAN was found to be 260 ${\mu}molg^{-1}$ at optimum pH and the detection limit (3$\sigma$) was 0.48 ${\mu}gL^{-1}$. The extractant showed rapid kinetic sorption. The adsorption equilibrium of mercury(II) on nanometer $SiO_2$-PAN was achieved just in 5 mins. Adsorbed mercury(II) was easily eluted with 5 mL of 6 M hydrochloric acid. The maximum preconcentration factor was 50. The method was applied for the determination of trace amounts of mercury(II) in various water samples and industrial effluents.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2010년도 춘계학술대회 논문집
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• pp.397-398
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• 2010

• 한국대기환경학회지
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• 제20권2호
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• pp.205-213
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• 2004

The emission characteristics of mercury in waste incinerators were investigated to get basic data for the policy development on the emission reduction of mercury (Hg). For the study several important factors were analysed from 4 incinerators such as mercury concentration, emission factors and removal rate for control devices. The results are listed below. Mercury concentrations in the flue gas were 0.39～5.96 $\mu\textrm{g}$/S㎥ in MWI and 2.5～8.8 $\mu\textrm{g}$/S㎥ in IWI. The distributions of gaseous and particulate mercury in flue gas were above 99% and below 1 %, respectively. Therefore, in order to remove mercury effectively, it is important to control the gaseous mercury. Mercury concentrations in fly ash collected from control device were found as 16.2～35.6 mg/kg- ash in FF of MWI. Also mercury concentrations at the front and back point of control device of MWI were 33.45～62.65 $\mu\textrm{g}$/S㎥ and 0.88～3.49 $\mu\textrm{g}$/S㎥, respectively. Emission factors were estimated as 3.67～11.67 mg/ton in FF, 2.6～24.5 mg/ton in MWI with SNCR, SDR and FF, 54.9～192.7 mg/ton in IWI with Cyclone and FF. Emissions from Municipal Waste Incinerator were found both in minimum and maximum ranges. Annual mercury emissions emitted from MWI was estimated as 20.0 kg (6.0～33.9 kg).

• Korean Chemical Engineering Research
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• 제48권2호
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• pp.268-274
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• 2010

유해대기오염물질인 중금속의 배출은 그 위해성으로 인해 엄격한 법적 규제를 하는 등 지대한 관심이 기우려지고 있다. 무연탄을 사용하는 상용 화력발전시설로부터 배출되는 중금속의 농도 및 배출특성에 대한 연구를 실시하였다. 대상 발전시설은 순환 유동층 연소로, 싸이클론, 보일러, 전기집진기 설비로 구성되었고 가스상 수은을 포함한 주요 중금속의 농도를 측정하기 위해 분진과 가스상 시료를 전기집진기(ESP) 전단과 연돌에서 측정하였다. 총 먼지량(TPM), PM-10, PM-2.5와 같은 입자상 물질의 배출량은 ESP 전단에서 각각 23,274, 9,555, $7,790mg/Sm^3$로 매우 높았으며, 이는 예측했던 바와 같이 미분탄 화력발전소보다 높은 수치였다. 그러나 ESP에 의한 먼지의 제거효율이 높기 때문에 연돌에서의 총 먼지량은 $0.16mg/Sm^3$ 정도였다. 마찬가지로 중금속 배출량 또한 ESP에서 높은 제거효율을 보였다. 입도분포와 입경 범위 별 중금속 농축 정도에 대한 데이터를 살펴볼 때 일부 금속의 농도는 작은 입경 범위에서 더 농축된 것을 보여 입자의 크기와 상관관계를 지어 볼 수 있었다. 수은의 경우 다른 금속들과 다르게 높은 휘발성 때문에 대부분이 가스 상태로 배출되며 그로 인하여 수은의 제거효율은 68% 정도로 다른 중금속들에 대한 제거효율보다 낮았다. ESP를 지나면서 수은 화학종이 원소수은에서 산화수은으로 변하는 것이 확인되었으며, 그로 인하여 습식세정탑이 설비된 다른 석탄 화력발전소에서는 원소 수은이 지배적인 데 반해 본 시설의 경우 연돌에서 총 수은의 절반 정도만 원소수은이었다.

• Asian Journal of Atmospheric Environment
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• 제10권3호
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• pp.146-155
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• 2016

Spatial and temporal variations of mercury, including dry and wet deposition fluxes, were assessed over Northeast Asia, targeting the Yellow Sea, using meteorology and chemistry models. Four modeling periods, each representative of one of the four seasons, were selected. Modeling results captured general patterns and behaviors, and fell within similar ranges with respect to observations. However, temporal variations of mercury were not closely matched, possibly owing to the effects of localized emissions. Modeling results indicated that dry deposition is correlated with wind speed, while wet deposition is correlated with precipitation amount. Overall, the wet deposition flux of $66ng/m^2-day$ was about twice as large as the dry deposition flux of $32ng/m^2-day$, when averaged over the four modeling periods. Dry deposition occurred predominantly in the form of reactive gaseous mercury (RGM). In contrast, RGM accounted for only about two-thirds of wet deposition, while particulate mercury accounted for the remainder.