• 제목/요약/키워드: Particulate materials

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Physical, Chemical and Optical Properties of Fine Aerosol as a Function of Relative Humidity at Gosan, Korea during ABC-EAREX 2005

  • Moon, Kwang-Joo;Han, Jin-Seok;Cho, Seog-Yeon
    • Asian Journal of Atmospheric Environment
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    • v.7 no.3
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    • pp.129-138
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    • 2013
  • The water uptake by fine aerosol in the atmosphere has been investigated at Gosan, Korea during ABC-EAREX 2005. The concentration of inorganic ion and carbon components, size distribution, and light scattering coefficients in normal and dry conditions were simultaneously measured for $PM_{2.5}$ by using a parallel integrated monitoring system. The result of this study shows that ambient fine particles collected at Gosan were dominated by water-soluble ionic species (35%) and carbonaceous materials (18%). In addition, it shows the large growth of aerosol in the droplet mode when RH is higher than 70%. Size distribution of the particulate surface area in a wider size range ($0.07-17{\mu}m$) shows that the elevation of RH make ambient aerosol grow to be the droplet mode one around $0.6{\mu}m$ or the coarse mode one, larger than $2.5{\mu}m$. Hygroscopic factor data calculated from the ratio of aerosol scattering coefficients at a given ambient RH and a reference RH (25%) show that water uptake began at the intermediate RH range, from 40% to 60%, with the average hygroscopic factor of 1.10 for 40% RH, 1.11 for 50% RH, and 1.17 for 60% RH, respectively. Finally, average chemical composition and the corresponding growth curves were analyzed in order to investigate the relationship between carbonaceous material fraction and hygroscopicity. As a result, the aerosol growth curve shows that inorganic salts such as sulphate and nitrate as well as carbonaceous materials including OC largely contribute to the aerosol water uptake.

A STUDY OF THE EFFECTS OF SEVERAL BONE-ENHANCING AGENTS (수종 골형성 증진재의 골형성능에 관한 조직형태계측학적 연구)

  • Shin, Min-Cheol;Ryu, Dong-Mok
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.29 no.5
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    • pp.282-292
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    • 2003
  • Several agents are in use to promote new bone formation during bone graft procedures in maxillofacial region. Among them, we have used crude BMP, PRP, and P-15 for experimentally created defects with accompanying graft materials in the rabbit model. The aim of this study is to analyze the effect of above mentioned agents on bone formation using histologic and histomorphometrical methods, thus to provide experimental support for clinical application of these agents. Six rabbits were used as experimental animals. Four surgical defects were created on the distal femoral heads of each animal using trephine drill. The defects were filled with each agents with accompaning graft materials as experimental groups and particulate corti-co-cancellous autogenous graft as control. For histomorphometric analysis, fluorescent dye was injected at 2week and 1week before sacrifice. Then, the animals were sacrificed at 2, 4 and 8weeks after surgery and histologic and histomorphometric examinations were achieved. At two weeks after bone graft, bone formation and active remodeling process were examined in all experimental groups and the control. But the intensity of such activities of the experiments were somewhat weaker than that of the control. In BMP group, the amount of newly formed osteoid was increased constantly and the amount was preserved constantly in PRP group. But in P-15 group, the amount of newly formed osteoid was decreased with time to 8week after surgery. Histologic findings showed superior bony quantity and quality in PRP group than that of P-15 group. MAR(Mineralization Apposition Rate) of all experimental groups were slower than that of control group. In P-15 group, constant foreign body reaction was observed at all periods and the graft material showed inwardly destroyed characteristics rather to mature. The data from this study provide the basis for future studies for evaluating the long-term remodeling process and foreign body reactions observed in P-15 group and clinical study for predictable use of these agents.

Hydrogneation and Electrochemical Characteristics of Gas-atomized Zr-based $AB_2$ Hydride for Ni-MH Secondary Battery (기체분무형 공정으로 제조된 Zr계 금속수소화물의 수소화반응 및 Ni-MH 2차전지 전극 특성에 관한 연구)

  • Kim, Jin-Ho;Hwang, Kwang-Taek;Kim, Byung-Kwan;Han, Jeong-Seb
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.6
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    • pp.505-511
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    • 2009
  • The hydriding and electrochemical characteristics of Zr-based $AB_2$ alloy produced by gas atomization have been extensively examined. For the particle morphology of the as-cast and gas-atomized powders, it can be seen that the mechanically crushed powders are irregular, while the atomized powder particles are spherical. The increase of jet pressure of gas atomization process results in the decrease of hydrogen storage capacity and the slope of plateau pressure significantly increases. TEM and EDS studies showed the increase of jet pressure in the atomization process accelerated the phase separation within grain of the gas-atomized alloy, which brought about a poor hydrogenation property. However, the gas-atomized $AB_2$ alloy powders produced by jet pressure of 50 bar kept up the reversible $H_2$ storage capacity and discharge capacity similar to the mechanically crushed particles. In addition, the electrode of gas-atomized Zr-based $AB_2$ alloy of 50 bar showed improved cyclic stability over that of the cast and crushed particulate, which is attributed to the restriction of crack propagation by grain boundary and dislocation with ch/discharging cycling.

A Study on Combustion and Emission Characteristics of Diesel Generator Fuelled with Coffee Ground Pyrolysis Oil (커피박 열분해유를 연료로 사용하는 디젤 발전기의 연소 및 배출물 특성에 관한 연구)

  • PARK, JUNHA;LEE, SEOKHWAN;KANG, KERNYONG;LEE, JINWOOK
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.6
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    • pp.567-577
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    • 2019
  • Due to the depletion of fossil fuels and environmental pollution, demand for alternative energy is gradually increasing. Among the various methods, a method to convert biomass into alternative fuel has been proposed. The bio-fuel obtained from biomass through pyrolysis process is called pyrolysis oil (PO) or bio-oil. Because PO is difficult to use directly in conventional engines due to its poor fuel properties, various methods have been proposed to upgrade pyrolysis-oil. The simplest approach is to mix it with conventional fossil fuels. However, due to their different polarity of PO and fossil fuel, direct mixing is impossible. To resolve this problem, emulsification of two fuels with a proper surfactant was proposed, but it costs additional time and cost. Alternatively, the use of alcohol fuels as an organic solvent significantly improve the fuel properties such as fuel stability, calorific value and viscosity. In this study, blends of diesel, n-butanol, and coffee ground pyrolysis oil (CGPO) which is one of the promising PO, was applied to diesel generator. Combustion and emissions characteristics of blended fuels were investigated under the entire load range. Experimental results show that ignition delay is similar to that of diesel at high load. Although, hydrocarbon and carbon monoxide emissions are comparable to diesel, significant reduction of nitrogen oxides and particulate matter emissions were observed.

Design simulation of magnetic separator for purification of silica sand (자력선별방식을 이용한 고순도 실리카 정제 최적화를 위한 전산모사)

  • Choi, Hyun-Jin;Jo, Young Min;Lee, Jun Yub;Kim, Sang Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.1
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    • pp.181-187
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    • 2016
  • Silica is an essential material in the electronics industries of LCDs and OLEDs, which particularly require high purity. This study attempted to find the optimal design of a magnetic separator for silica sand containing iron compounds using CFD simulation. Three designs of magnetic separation were prepared and their efficiency was examined. As a result of the evaluation, the sufficient contact of particulate silica with the surface of magnetic emitters improved the magnetic separation effects. In addition, the loss of $SiO_2$ and the removal rate of $Fe_2O_3$ depended strongly on the particle size, flow rate and magnetic flux density. In addition, magnetic separation is quite effective for a particle size of $10{\mu}m$ with a 0.2 m/s flow rate.

A Study on the Assessment of the IAQ during Nightime (공동주택에서 취침 시 실내공기환경 평가에 관한 연구)

  • Kim, Dong-Gyu;Kim, Sam-Uell;Kim, Se-Hwan
    • KIEAE Journal
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    • v.7 no.5
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    • pp.93-98
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    • 2007
  • Effort has been performed for latest 20 years to improve resident's comfort and indoor environment in building. And interest and effort to improve indoor air environment among various indoor environment elements have continuously increased since 1990s, because it is examined scientifically that various contaminants generated indoor affect human body. Specially, indoor air contaminants generated from apartments are those exhausted from resident's indoor environment, closing materials and household. Indoor air environment in buildings is different according to pollution degree, existence availability of pollution source, ventilation amount, and meteorology. It is known that other contaminants more than about 900 kinds generate according to a kind of work or action in a room. Specially, nowadays buildings are well insulated and confidentiality-centered for environment protection and economical side. So indoor air contaminants are generated from indoor air pollution sauces of unprepared ventilation, human body carbon dioxide emissions, and various building materials. when these are accumulated in long term human body, it is harmful to resident's health, but awareness for this is very insufficient. Because bedroom is space that people inhabit for a long time by unconscious state and indoor environment occupies important part for resident's health and quality of life at sleep, the actual condition of air quality is investigated, improvement countermeasure is considered, and ventilation amount is analyzed. In this study, putting case that the most longest stayed time is sleeping time when people inhabit in the apartment, the air quality according to volume of bedroom space at sleep was measured and analyzed, and the data acquired will be the basis for improvement on this.

Effects of Wind Stress Curl, Topography, and Stratification on the Basin-scale Circulations in a Stratified Lake (바람의 회전응력, 지형, 그리고 성층화가 성층 호수의 물 순환에 미치는 영향)

  • Chung, Se-Woong;Schladow, S.G.
    • Proceedings of the Korea Water Resources Association Conference
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    • 2015.05a
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    • pp.53-53
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    • 2015
  • Basin-scale motions in a stratified lake rely on interactions of spatially and temporally varying wind force, bathymetry, density variation, and earth's rotation. These motions provide a major driving force for vertical and horizontal mixing of inorganic and organic materials, dissolved oxygen, storm water and floating debris in stratified lakes. In Lake Tahoe, located between California and Nevada, USA, basin-scale circulations are obviously important because they are directly associated with the fate of the suspended particulate materials that degrade the clarity of the lake. A three-dimensional hydrodynamic model, ELCOM, was applied to Lake Tahoe to investigate the underlying mechanisms that determine the characteristics of basin-scale circulations. Numerical experiments were designed to examine the relative effects of various mechanisms responsible for the horizontal circulations for two different seasons, summer and winter. The unique double gyre, a cyclonic northern gyre and an anti-cyclonic southern gyre, occurred during the winter cooling season when wind stress curl, stratification, and Coriolis effect were all incorporated. The horizontal structure of the upwelling and downwelling formed due to basin-scale internal waves found to be closely related to the rotating direction of each gyre. In the summer, the spatially varying wind field and the Coriolis effect caused a dominant anti-cyclonic gyre to develop in the center of the lake. In the winter, a significant wind event excited internal waves, and a persistent (2 week long) cyclonic gyre formed near the upwelling zone. Mechanism of the persistent cyclonic gyre is explained as a geostrophic circulation ensued by balancing of the baroclinc pressure gradient (or baroclinic instability) and Coriolis effect. Topographic effect, examined by simulating a flat bathymetry with constant depth of 300m, was found to be significant during the winter cooling season but not as significant as the wind curl and baroclinic effects.

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Particle loading as a design parameter for composite radiation shielding

  • Baumann, N.;Diaz, K. Marquez;Simmons-Potter, K.;Potter, B.G. Jr.;Bucay, J.
    • Nuclear Engineering and Technology
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    • v.54 no.10
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    • pp.3855-3863
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    • 2022
  • An evaluation of the radiation shielding performance of high-Z-particle-loaded polylactic acid (PLA) composite materials was pursued. Specimens were produced via fused deposition modeling (FDM) using copper-PLA, steel-PLA, and BaSO4-PLA composite filaments containing 82.7, 75.2, and 44.6 wt% particulate phase contents, respectively, and were tested under broad-band flash x-ray conditions at the Sandia National Laboratories HERMES III facility. The experimental results for the mass attenuation coefficients of the composites were found to be in good agreement with GEANT4 simulations carried out using the same exposure conditions and an atomistic mixture as a model for the composite materials. Further simulation studies, focusing on the Cu-PLA composite system, were used to explore a shield design parameter space (in this case, defined by Cu-particle loading and shield areal density) to assess performance under both high-energy photon and electron fluxes over an incident energy range of 0.5-15 MeV. Based on these results, a method is proposed that can assist in the visualization and isolation of shield parameter coordinate sets that optimize performance under targeted radiation characteristics (type, energy). For electron flux shielding, an empirical relationship was found between areal density (AD), electron energy (E), composition and performance. In cases where ${\frac{E}{AD}}{\geq}2MeV{\bullet}cm{\bullet}g^{-1}$, a shield composed of >85 wt% Cu results in optimal performance. In contrast, a shield composed of <10 wt% Cu is anticipated to perform best against electron irradiation when ${\frac{E}{AD}}<2MeV{\bullet}cm{\bullet}g^{-1}$.

Physical Properties of Flame Retardant Particulate Reinforced Thermoplastic Polymer Composites for Cold-Resistant Cable (내한성 케이블 적용을 위한 난연 입자 강화 열가소성 고분자복합재료의 기계적 특성평가)

  • Lee, Jinwoo;Shim, Seung Bo;Park, Jae Hyung;Lee, Ji Eun
    • Composites Research
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    • v.35 no.5
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    • pp.309-316
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    • 2022
  • The demand for cold-resistant cable material is increasing due to the rapid increase in the development of devices that operate in a low temperature environment. Cold tolerance of a thermoplastic polymer largely depends on the type and content of about 20 or more additives used to make the polymer. The phenomenon of polymer hardening at low temperature can be classified into hardening by simple temperature effect, embrittlement at the glass transition temperature, and hardening by crystallization of polymers that tend to crystallize. In this study, a thermoplastic polymer having a low glass transition temperature, a flame retardant, and an additive were mixed to evaluate the mechanical properties of a thermoplastic polymer composite material for electric wires. It has been confirmed that mechanical properties and processability are determined depending on the additives and compatibilizers added, and this study is considered to be useful as basic data for optimization to meet the performance requirements of wires developed for low-temperature use.

Sediment Material Contents and Settling Velocity of Particle Material in the Constructed Wetland in Sookcheon in the Cachment of Daecheong Reservoir (대청호 유역 소옥천 인공습지에서 부유물질 침강속도 및 퇴적물의 물질함량)

  • Je-Chul Park;Dong-Sup Kim;Kwang-Soon Choi
    • Korean Journal of Ecology and Environment
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    • v.55 no.3
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    • pp.244-250
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    • 2022
  • The changes in COD, TOC, T-P, and T-N concentrations were investigated for 2 years in the constructed wetland of Sookcheon, which was installed to improve the water quality of Daecheong reservoir in South Korea. In order to evaluate the pollution level of sediments in the wetland, settling velocity of particulate material (4 times) and sedimet material contents (6 times) were measured. COD and TOC concentrations increased slightly as they passed through wetlands, and T-N and T-P concentration tended to decrease. The material content (COD, T-P, T-N) of aquatic plants was higher in floating-leaved and free-floating macrophytes than emergent macrophytes. As a result of measuring the sedimentation rate of suspended materials, most of the suspended materials introduced into constructed wetlands were sedimented at a rapid rate in the first sedimentation site. In addition, sediment pollution of T-P and T-N in constructed wetland was in severe pollution. The sediments containing a large amount of T-P and T-N were eluted by physical and chemical environmental changes, which is likely to act as internal pollution sources in wetlands.