• 제목/요약/키워드: Particle-free

검색결과 608건 처리시간 0.028초

PFOA Free 불소 고분자 및 실리카 나노졸을 이용한 self cleaning 표면 가공에 관한 연구 (A Study on the Self-cleaning Surface Finishing Using PFOA Free Fluoric Polymer and Silica Nano-sol)

  • 박성민;권일준;김란;염정현;윤남식;이경남
    • 한국염색가공학회지
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    • 제21권6호
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    • pp.1-11
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    • 2009
  • Super-hydrophobic surface, with a water contact angle greater than $150^{\circ}$, has a self cleaning effect termed 'lotus effect'. We introduced super-hydrophobicity onto aramid/rayon mixture fabric with dual-scale structure by assembling silica nano-sol. Mixture fabric was treated with silica nano-sol, fluoric polymer using various parameters such as particle size, concentration. Silica nano-sol size were measured using particle size analyzer. Morphological changes by particle size were observed using field emission scanning electron microscopy(FE-SEM), contact angle measurement equipment. The contact angle of water was about $134.0^{\circ}$, $137.0^{\circ}$, $143.0^{\circ}$, $139.5^{\circ}$ and $139.0^{\circ}$ for mixture fabric coated with 100.2nm, 313.7nm, 558.2nm, 628.5nm and 965.4nm silica nano-sol, compared with about $120.0^{\circ}$ for mixture fabric coated with fluoric polymer. When we mixed particle sizes of 100.2nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $146.2^{\circ}$. And we mixed particle sizes of 313.7nm and 558.2nm by 7:3 volume ratio, the contact angle of water was about $141.8^{\circ}$. Also we mixed particle sizes of 558.2nm and 965.4nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated the water-repellent surfaces with various surface structures by using four types of silica nano-sol, and we found that the dual-scale structure was very important for the super-hydrophobicity.

우리나라 상토의 물리적 표준분석법 설정 연구 1. 입자밀도 및 용적밀도 (Development of Standard Analysis Methods for Physical Properties on Korean bedsoil 1. Particle density and Bulk density)

  • 김이열;조희기
    • 한국토양비료학회지
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    • 제35권6호
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    • pp.327-334
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    • 2002
  • 우리나라 유통상토에 대한 물리적 표준분석법을 설정하기 위한 연구를 실시하였다. 국내 시중에 유통되고 있는 53개 품목의 원예용 상토와 9개 품목의 수도용 상토를 대상으로 설정된 분석법을 적용하여 실험하였다. 입자밀도의 측정은 가스형 피크노메타 (Micromeritics Co. Model 1305)를 사용하면 속도와 정확성 면에서 매우 유리 하였다. 용적밀도는 구미에서 Sandbox법에 의한 용적밀도를 기본으로 하기 때문에 이와 유사한 성적을 얻을 수 있는 다양한 실험을 한 결과, 추다짐법 (Plunger compaction method)이 가장 유의성 있는 측정 방법으로 밝혀졌다. 한편 가스형 피크노메타법에 의한 우리나라 유통상토의 입자밀도는 원예용이 1.93, 수도용이 $2.43Mg\;m^{-3}$로 나타났으며, 추다짐법에 의한 용적밀도는 원예용이 0.22, 수도용이 $1.01Mg\;m^{-3}$로 각각 나타났다.

Controlling Size and Distribution for Nano-sized Polystyrene Spheres

  • Yun, Dong-Shin;Lee, Hyeong-Seok;Jang, Ho-Gyeom;Yoo, Jung-Whan
    • Bulletin of the Korean Chemical Society
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    • 제31권5호
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    • pp.1345-1348
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    • 2010
  • Highly monodisperse polystyrene (PS) nanospheres were fabricated by surfactant-free emulsion polymerization in water using styrene, 2,2'-azobis(2-methyl propionamidine) dihydrochloride (AIBA), and poly(vinyl pyrrolidone) (PVP). The size and distribution of the PS nanospheres were systematically investigated in terms of initiator concentration, stabilizer concentration, reaction temperature, reaction time, and reactant concentration. With increasing AIBA initiator concentration, PS particle sizes are raised proportionally, and can be controlled from 120 to 380 nm. Particle sizes were reduced with increasing PVP concentration. This decrease occurs because a high PVP concentration leads to a large number of primary nuclei in the early stage of polymerization. When the reaction temperature increased, the sizes of the PS particles decrease slightly. The particles grew quickly during the initial reaction stage (1-3 h) and the growth rate became steady-state after 6 h. The PS sizes approximately doubled when the reactant (styrene, PVP, azo-initiator) concentrations were increased by a factor of eight.

글로우플러그를 이용한 충돌분무의 미립화특성에 관한 연구 (A Study on Atomization Characteristics of Gasoline Impinging Spray Using Glow plug)

  • 문영호;오영택
    • 한국자동차공학회논문집
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    • 제9권5호
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    • pp.54-61
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    • 2001
  • It is reported that during the cold starting, especially in gasoline engine, the engine response and the effect of HC emission can be improved by prompting atomization and reducing the quantity of fuel adhered to the range of injector tip, inlet port, and inlet valve. The purposes of this study are to promote atomization of fuel before air-fuel mixture in the inlet port. In order to achieve its goal, the glow plug is to evaluate the feasibility of for the early fuel evaporator and the spray behavior characteristics of gasoline, injected on the surface of glow plug with room temperature(2$0^{\circ}C$) and high temperature(25$0^{\circ}C$) is to examine. Particle motion analysis system(PMAS) was used to measure the SMD and the dropsize distribution of impinging spray and free spray. The results of this experiment, evaporation rate of impinging spray was higher than that of free spray, and the higher evaporation rate win, the smaller peak dropsize was. Especially, during early spray SMD of impinging spray was still smaller than that of fee spray.

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다이아몬드 배열 무전해 니켈 도금층/무산소동 기판의 열전도도 특성 (Thermal Properties of Diamond Aligned Electroless Ni Plating Layer/Oxygen Free Cu Substrates)

  • 정다운;김송이;박경태;서석준;김택수;김범성
    • 한국분말재료학회지
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    • 제22권2호
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    • pp.134-137
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    • 2015
  • The monolayer engineering diamond particles are aligned on the oxygen free Cu plates with electroless Ni plating layer. The mean diamond particle sizes of 15, 23 and $50{\mu}m$ are used as thermal conductivity pathway for fabricating metal/carbon multi-layer composite material systems. Interconnected void structure of irregular shaped diamond particles allow dense electroless Ni plating layer on Cu plate and fixing them with 37-43% Ni thickness of their mean diameter. The thermal conductivity decrease with increasing measurement temperature up to $150^{\circ}C$ in all diamond size conditions. When the diamond particle size is increased from $15{\mu}m$ to $50{\mu}m$ (Max. 304 W/mK at room temperature) tended to increase thermal conductivity, because the volume fraction of diamond is increased inside plating layer.

해양 원형 규조류 Cyclotella meneghiniana 성장 연관 미생물 군집구조 분석: 배양단계에 따른 증거 (Associated Bacterial Community Structures with the Growth of the Marine Centric Diatom Cyclotella meneghiniana: Evidence in Culture Stages)

  • 최원지;박범수;곽야옥;기장서
    • Ocean and Polar Research
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    • 제39권4호
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    • pp.245-255
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    • 2017
  • There are a number of pieces of evidences that suggest a link between marine diatoms and microorganisms, but knowledge about related microbial communities is greatly lacking. The present study investigated the microbial community structures related to the growth of the marine diatom Cyclotella meneghiniana. We collected free-living bacteria (FLB) and particle-associated bacteria (PAB) at each growth stage (e.g., lag, exponential, stationary and death) of the diatom, and analyzed their bacterial 16S rDNA using pyrosequencing. Metagenomics analysis showed that community structures of FLB and PAB differed considerably with the progress of growth stages. FLB showed higher diversity than PAB, but variation in the different growth stages of C. meneghiniana was more evident in PAB. The proportion of the genus Hoeflea, belonging to the order Rhizobiales, was dominant in both FLB and PAB, and it gradually increased with the growth of C. meneghiniana. However, Enhydrobacter clade tended to considerably decrease in PAB. In addition, Marinobacter decreased steadily in FLB, but first increased and then decreased in PAB. These results suggest that Hoeflea, Enhydrobacter, and Marinobacter may be closely related to the growth of diatom C. meneghiniana.

$CO_2$/NOx-free 50kW 매체순환식 가스연소기 산화-환원 연속반응 실증 (Continuous Operation of $CO_2$/NOx-free 50kW Checmial-Looping Combustor)

  • 류호정;진경태;이창근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.227-234
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    • 2004
  • For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to $CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent $CO_2$ separation and no NOx emission and to confirm high $CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and $CH_4$ and air were used as reacting gases for reduction and oxidation respectively.

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Experimental Study on Nonlinearity Characteristics Near the Free Surface in the Regular Wave Condition

  • Choi, Hae-Jin;Jung, Kwang-Hyo;Suh, Sung-Bu;Jo, Hyo-Jae;Choi, Han-Suk
    • 한국해양공학회지
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    • 제24권1호
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    • pp.1-9
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    • 2010
  • A series of experiments employing particle image velocimetry (PIV) technique was conducted to produce benchmark wave kinematics data for regular waves having four different wave slopes in 2-D wave tank. Water velocities and accelerations near the free surface of regular waves were computed from image pair obtained by PIV systems. With the measured wave velocity field, the wave accelerations were computed using a centered finite difference scheme. Both local and convective components of the total accelerations are obtained from experimental data. With increasing the wave slope, the horizontal velocity and the vertical accelerations near the wave crest obtained by PIV technique became larger than theoretical results, which are well-known phenomena of the wave nonlinearity. It is noted that the relative magnitude of convective acceleration to the local acceleration became larger with increasing wave slope.

Chitin의 효소적 가수분해 특성에 대한 속도론적 연구 (Kinetics on the Specificity of Enzymatic Hydrolysis of Chitin)

  • 이은영;김광
    • KSBB Journal
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    • 제13권1호
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    • pp.44-51
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    • 1998
  • Hydrolysis and adsorption reversibility experiments were run for initial enzyme activity of 4.48, 9.65, 11.19 and 17.14U/mL at a temperature 30$^\circ C$. The chitin particle size corresponded to a mean particle diameter of 0.127mm, and the initial concentration of chitin was 10mg/mL. After approximately 2hrs, the enzyme activity remained constant in a speudo-steady state. The amounts in the bulk [E] and the amounts of enzyme adsorbed on the chitin surface [E] are plotted on Lineweaver-Burk plot to yield a linear relationship with a correlation coefficient of 0.99, a slope of 2.79cm$^-1$ and an intercept of 0.08$\textrm{cm}^2$/U. From this parameters, the values of [E$_T$] and $K_E$ were calculated to be 12.5U/cm$^2$ and 34.88U/mL. respectively, Adsorption isotherm of the enzyme on the particles showed a well developed plateau of 1.35$\times$10$^-3$, 4.72$\times$10$^-3$, 4.42$\times$10$^-3$, 8.58$\times$10$^-3$U/cm$^2$ at 30$^\circ C$. To determine the specificity of chitinase for crystalline chitin, the free energy of adsorption was measured, and its was determined as about -14.62~-18.8kJ/mol.

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GIS 감시진단용 다양한 센서를 적용한 PD 검출 및 패턴분석 결과 비교연구 (A Comparate Study for the PD Pattern Analysis using Different Type of Sensors Applicable to the On-line Monitoring of GIS)

  • 구자윤;장용무;최재옥;연만승;이지철
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권5호
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    • pp.198-205
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    • 2005
  • Many precedent investigations hate been made for the reliable assessment of the insulation state of large power apparatus for which partial discharge detection is one of tile plausible way. In this work, experimental investigations have been carried out to make the comparison on the PD(partial discharge) pattern analysis related to the five different types of artificial defects such as SFMP (Single Free Moving Particle), MFMP (Multi Free Moving Particle), Void, CFP (Conductor-Fixed Protrusion), EP (Enclosure Protrusion). For each PD pattern, PD detection has been done by tee different types of PD sensors such as HFCT(High Frequency Current Transformer), AE(Acoustic Emission) and UHF(Ultra High Frequency). And, in addition, frequency spectrum by the UHF sensor has been also made for each defect respectively. As a result, it is observed that the possibility of obtaining PD pattern based on PRPD(Phase Resolved Partial Discharge) in connection with the defects tinder investigation is dependant on the type of the sensor while the spectrum analysis is always successful to be achieved for every defect. Therefore, it could be suggested that the nature of PD source can be identified more distinctively when the conventional PRPDA is combined with spectrum analysis.