• 제목/요약/키워드: Particle-In-Binder

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플라스틱 페라이트 자석의 레올로지와 자기특성 (Rheological and Magnetic Properties of Plastic Ferrite Magnets)

  • 이석희;최준환;문탁진;정원용
    • 한국자기학회지
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    • 제8권3호
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    • pp.150-155
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    • 1998
  • 플라스틱 이방성 페라이트 자석에서 페라이트 분말함량 변화에 레올로지와 자기특성의 변화를 조사하였다. 분말함량 변화에 따른 상대점도의 측정값과 이론식을 비교하였다. 분말함량 증가에 따른 혼합물의 상대점도 증가경향과 플라스틱자석의 분말배향도의 감소경향은 정확히 일치하였다. 일정한 자장하에서 사출성형된 플라스틱 이방성 페라이트 자석에서 잔류자속밀도와 최대자기에너지적은 분말함량 증가에 따라 적선적으로 증가하다가 다시 감소하여 극대값을 나타냈으며, 극대값 이후의 자기특성 가소는 분말배향도의 급격한 감소에 기안하였다. 자기특성 극대값을 나타내는 분말한량은 사출형성시 자장의 세기와 결합체의 용융점도에 의존하며, 높은 자기특성을 위해서는 낮은 용융점도의 결합제 사용이 필요하다.

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고분자 분쇄 기술을 활용한 고체 알칼리연료전지용 이오노머 바인더 용액 개발 (Development of Ionomer Binder Solutions Using Polymer Grinding for Solid Alkaline Fuel Cells)

  • 신문식;김도형;강문성;박진수
    • 전기화학회지
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    • 제19권3호
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    • pp.107-113
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    • 2016
  • 본 연구에서는 고체알칼리 연료전지용 이오노머 바인더 용액 제조를 위하여 poly(2,6-dimethyl-1,4-phenylene oxide)(PPO)를 동결 분쇄하고 4급 암모늄화 반응을 진행하여 음이온 전도성 이오노머(quaternized PPO, QPPO) 용액을 제조하였다. QPPO 이오노머 바인더 용액의 종류를 고분자의 분쇄 시간을 통하여 제조하였고, 이에 따른 분산도, 입자의 크기 및 전기화학적 성능 등을 분석하였다. 이를 통해 기존의 비 분쇄 고분자를 활용하여 제조한 이오노머 바인더 용액보다 분쇄 고분자를 활용한 이오노머 바인더 용액이 높은 고분자 분산도와 낮은 입자 크기를 확보하였다. 제조한 이오노머 바인더 용액(BPPO-G120s)의 최대 이온전도도는 $0.025S\;cm^{-1}$이었으며, 이온교환용량은 $1.26meq\;g^{-1}$을 보였다.

입자 크기별 가공부산물로 제조된 벌크흑연의 기계적 성질 (Mechanical Properties of Bulk Graphite using Artificial Graphite Scrap as a Function of Particle Size)

  • 이상혜;이상민;장원표;노재승
    • 한국분말재료학회지
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    • 제28권1호
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    • pp.13-19
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    • 2021
  • Bulk graphite is manufactured using graphite scrap as the filler and phenolic resin as the binder. Graphite scrap, which is the by-product of processing the final graphite product, is pulverized and sieved by particle size. The relationship between the density and porosity is analyzed by measuring the mechanical properties of bulk graphite. The filler materials are sieved into mean particle sizes of 10.62, 23.38, 54.09, 84.29, and 126.64 ㎛. The bulk graphite density using the filler powder with a particle size of 54.09 ㎛ is 1.38 g/㎤, which is the highest value in this study. The compressive strength tends to increase as the bulk graphite density increases. The highest compressive strength of 43.14 MPa is achieved with the 54.09 ㎛ powder. The highest flexural strength of 23.08 MPa is achieved using the 10.62 ㎛ powder, having the smallest average particle size. The compressive strength is affected by the density of bulk graphite, and the flexural strength is affected by the filler particle size of bulk graphite.

기체발생기용 복합고체추진제의 조성 및 성능특성 연구 (A Formulation and Performance Characteristics of Composite Solid Propellant for an Application to Gas Generators)

  • 김정수;박정
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2009년도 제33회 추계학술대회논문집
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    • pp.181-184
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    • 2009
  • 로켓시스템의 에너지원으로 적용할 수 있는 기체발생기용 복합 고체추진제의 개발과정을 기술한다. 80%의 고체입자 부하율과 양호한 유동성, 그리고 $-50^{\circ}C{\sim}70^{\circ}C$에서 경화에 적절한 추진제 물성을 갖는 HTPB를 바인더로 하여, 낮은 화염온도, 적은 고체입자 잔사, 무독성 생성물의 추진제 제조가 가능한 AN을 제1종 산화제로, 탄도특성 제어에 필요한 AP를 제2종 산화제로 추진제 주요 조성이 구성된다. 기본조성을 근거로 하여 일련의 물성개선 시험이 수행되었으며 최대응력 8 bar 및 최대응력점 변형율 30%, 그리고 탄성계수 1000 psi 수준의 물성을 갖는 추진제 조성을 얻을 수 있었다.

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전자선을 이용한 PVDF-HFP/Silylated Al2O3가 코팅된 리튬 이차 전지용 폴리에틸렌 분리막의 전기화학적 특성 연구 (Electrochemical Study on PVDF-HFP/Silylated Al2O3-coated PE Separators using the Electron Beam Irradiation for Lithium Secondary Battery)

  • 손준용;신준화;노영창
    • 방사선산업학회지
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    • 제4권4호
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    • pp.359-364
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    • 2010
  • PVDF-HFP (binder)/silylated alumina (inorganic particle)-coated PE (polyethylene) separators were with various compositions of binder and inorganic particle were prepared by a dip-coating process with humidity control (R.H. 25% and 50%) using electron beam irradiation. The morphology of the coated PVDF-$HFP/Al_2O_3$ layer with various compositions of PVDF-HFP and $Al_2O_3$, and humidity condition was found to be an important factor in determining ionic conductivity of the prepared separators. The PVDF-$HFP/Al_2O_3$ (5/5)-coated PE separator prepared at R.H. 50% followed by electron beam irradiation at 200 kGy was applied for lithium-ion polymer battery and the cell test results showed improved high-rate discharge performance and better cyclic stability compared to the cells with the bare PE and the PVDF-HFP-coated PE separators.

바인더젯 3D 프린팅을 위한 TiO2 입자를 함유한 시멘트 기반 재료의 기계적 성능 및 광촉매 특성 분석 (Characterization of mechanical and photocatalytic performance on cement-based materials with TiO2 particles for binder jet 3D printing)

  • 유준성;리패기;배성철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 가을학술발표대회논문집
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    • pp.69-70
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    • 2023
  • The development of advanced 3D printing technologies has opened up new opportunities for customized digital designs in the construction industry. Using nano- and micro-scale additives is expected to improve the performance of cement-based materials in 3D printing. TiO2 particles have been widely used as reinforcing additives in cement-based materials. Therefore, this study aims to investigate the application of cement-based materials containing multi-size TiO2 particles in binder jet 3D printing and the effect of different-size TiO2 particles on the performance of printed samples. TiO2 particles exhibit an excellent filling effect, which increases the density of the printed samples and promotes hydration, thereby improving the compressive strength of the samples. In addition, larger TiO2 particles exert more pronounced filling and photocatalytic effects on the resulting samples.

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고전압 LiNi0.5Mn1.5O4 양극 고성능 바인더 개발 연구 (Development of Advanced Polymeric Binders for High Voltage LiNi0.5Mn1.5O4 cathodes in Lithium-ion batteries)

  • 윤대희;최성훈
    • 산업기술연구
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    • 제43권1호
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    • pp.43-48
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    • 2023
  • Spinel LiNi0.5Mn1.5O4 (LNMO) has been considered as one of most promising cathode material, because of its low-cost and competitive energy density. However, 4.7V vs. Li/Li+ of high operating potential facilitates electrolyte degradation on cathode-electrolyte interface during charge-discharge process. In particular, commercial polyvinylidene fluoride (PVDF) is not sutaible for LNMO cathode binder because its weak van der waals force induces thick and non-uniform coverage on the cathode surface. In this review, we study high performance binders for LNMO cathode, which forms uniform coating layer to prevent direct contact between electrolyte and LNMO particle as well as modifying high quality cathode electrolyte interphase, improved cell performace.

수축율 조절에 의한 적층 칩 LC Filter의 동시 소성에 관한 연구 (A Study on Co-Firing of Multilayer Chip LC Filter by Control of Shrinkage)

  • 김경용;이종규;김왕섭;최환
    • 한국세라믹학회지
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    • 제28권9호
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    • pp.675-682
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    • 1991
  • Among many problems that need to be solved in the process of preparing multilayer chip LC filters, we studied the control of shrinkage in order to prevent the crack, warpage, and/or delamination which occurs at the interface between the inductance (L part) and the capacitance (C part). Shrinkage was controlled by compositions, powder size, calcining temperature and amount of organic binder. Capacitance sheet was prepared by mixing 65 wt% binder with the composition of 96 wt% TiO2 having an average particle size of 0.5 $\mu\textrm{m}$, 3 wt% CuO. After small amount of MnO2 and SiO2 added, it was calcined at 750$^{\circ}C$ for 2 hr. Inductance sheet was prepared by mixing 60 wt% binder with the composition of 49.5% mol% Fe2O3, 20.5 mol% ZnO, 20 mol% NiO and 10 mol% CuO which was calcined at 775$^{\circ}C$ for 2 hr. These sheets was laminated at 250 kg/$\textrm{cm}^2$, and cofired at 900$^{\circ}C$ for 2 hr to give rise to a multilayer chip LC filter without any warpage.

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분말사출성형으로 제조된 다극 이방성 Sr-페라이트 소결자석 (Multi-pole anisotropic Sr-ferrite sintered magnets fabricated by powder injection molding)

  • 조태식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.284-287
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    • 2001
  • Multi-pole anisotropic Sr-ferrite sintered magnets has been studied by powder injection molding under applied magnetic field. The orientation of anisotropic Sr-ferrite powders higher than 80% during injection molding is achieved at the following conditions; apparent viscosity lower then 2500 poise in 1000 $sec^{-1}$ shear rate and applied magnetic field higher then 4 kOe. For the high fluidity and strength of injection molded compact, and the effective binder removal without defects during solvent extraction and thermal debinding, the optimum multi-binder composition is paraffin wax(PW)/carnauba wax(CW)/HDPE = 50/25/25 wt%. The rate of binder removal is proportional to the mean particle size of Sr-ferrite powders whereas it is inversely proportional to the content of Sr-ferrite powders and the sample thickness. The high magnetic properties of Sr-ferrite sintered magnets are; 3.8 kG of remanent flux density, 3.4 kOe of intrinsic coercivity, and 1.2 kG of surface flux density (l-mm-thick) in the direction of applied magnetic field.

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분말사출성형으로 제조된 다극 이방성 SF-폐라이트 소결자석 (Mu7i-pole anisotropic Sr-ferrite sintered magnets fabricated by powder injection molding)

  • 조태식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
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    • pp.284-287
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    • 2001
  • Multi-pole anisotropic Sr-fertile sintered magnets has been studied by powder injection molding under applied magnetic field. The orientation of anisotropic Sr-ferrite powders higher than 80% during injection molding is achieved at the following conditions; apparent viscosity lower then 2500 poise in 1000 sec$\^$-1/ shear rate and applied magnetic field higher then 4 kOe. For the high fluidity and strength of injection molded compact, and the effective binder removal without defects during solvent extraction and thermal debinding, the optimum multi-binder composition is paraffin wax(PW)/carnauba wax(CW)/HDPE = 50/25/25 wt%. The rate of binder removal is proportional to the mean particle size of Sr-ferrite powders whereas it is inversely proportional to the content of Sr-ferrite powders and the sample thickness. The high magnetic properties of Sr-ferrite sintered magnets are; 3.8 kG of remanent flux density, 3.4 kOe of intrinsic coercivity, and 1.2 kG of surface flux density (1-mm-thick) in the direction of applied magnetic field.

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