• 공업화학
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• 제23권1호
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• pp.8-13
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• 2012

본 연구에서는 프린터 토너의 대전량 제어제로 사용되는 아연 착화합물 제조시 금속염과 다가알코올을 첨가함에 따라 변화되는 입자 형태와 평균 입도에 대해 고찰하였다. 아연 착화합물을 제조하기 위해 염화아연과 3,5-di-tert-butyl salicylic acid를 사용하였다. 다가알코올을 첨가함에 따른 입자형태 변화를 확인하기 위해 아연 착화합물 제조시 polyethylene glycol (PEG-300), glycerin 및 ethylene glycol을 첨가하였고, 금속염인 지르코늄 옥시클로라이드를 첨가함으로써 변화되는 입자크기를 확인하였다. 또한 금속염과 다가알코올을 동시에 첨가하여 입도변화를 확인한 결과, 각각 단독으로 첨가했을 때보다 아연 착화합물의 평균 입도가 더 많이 감소하는 것을 확인할 수 있었다. 특히, 지르코늄 착화합물의 함유량이 30 wt%이고 염화아연에 대한 PEG-300의 몰비를 3으로 하였을 때 아연 착화합물의 평균 입도가 1.84 ${\mu}m$로 순수한 아연 착화합물의 평균 입도(5.28 ${\mu}m$)의 34.9%로 가장 많이 감소한 것을 알 수 있었다.

• 소성∙가공
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• 제11권8호
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• pp.682-690
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• 2002

The formation of adiabatic shearband in tungsten heavy alloys(WHA) was studied in this investigation. Five prismatic specimens were loaded by high velocity impacts and treated as plane strain problems. To find out the effect of particle's volume ratio, specimens containing 81%, 93% and 97% volume percents of tungsten particles were used. Also the effects of particle's geometry and size on the formation of shearband were studied for 81% volume percent alloys by small size particle model, large size particle model and undulated particle models, and the results were discussed.be used to diagnose the causes of necking and fracture in industrial practice and to investigate whether these defects were caused by material property variation, changes in lubrication, or incorrect press settings. In non-axisymmetric deep drawing, three modes of forming regimes are found: draw, stretch, plane strain. The stretch mode for non-axisymmetric deep drawing could be defined when the major and minor strains are positive. The draw mode could be defined when the major strain is positive and minor strain is negative, and plane strain mode could be defined when the major strain is positive and minor strain is zero. Through experiments the draw mode was shown on the wall and flange are one of a drawn cup, while the plane strain and the stretch mode were on the punch head and the punch corner area respectively, We observed that the punch load of elliptical deep drawing was decreased according to increase of die corner radius and the thickness deformation of minor side was more large than major side.

• 한국세라믹학회지
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• 제34권8호
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• pp.854-860
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• 1997

The tribological property of ceramics is very important for use in seal rings, pump parts, thread guides and mechanical seal, etc. In the present study, which RBSC/graphite composites were manufactured by adding graphite powders with different particle sizes to mixtures of SiC powder, metallic silicon, carbon black and alumina, effects on the tribological property of each RBSC/graphite composite was investigated in accordance with the particle size of the added graphite powder. The water absorption, the bending strength and the resistance for the friction and wear were measured, and the crystalline phase and the microstructure were respectively examined by using XRD and SEM. In case that the particle size of the graphite powder was fine(2${\mu}{\textrm}{m}$), the formation of $\beta$-SiC was accelerated, thereby making the increase of the bending strength and the decrease of the water absorption, but no improvement for the tribological properties. Furthermore, in case that the particle size of the graphite powder was some large(88~149${\mu}{\textrm}{m}$), the formation of $\beta$-SiC was not accelerated, to thereby make the decrease of the bending strength and the increase of the water absorption, but the improvement for the tribological property of only the composite having the graphite powder of 20 vol%. In addition, in case that the particle size distribution of the graphite powder was large (under 53 ${\mu}{\textrm}{m}$), there was no improvement for every properties. However, the composites, which the graphite powder with the particle size of 53~88 ${\mu}{\textrm}{m}$ was added in 10~15 vol%, had the most increased resistance for the friction and wear which show the worn out amount of 0.4~0.6$\times$10-3 $\textrm{cm}^2$, and the value of the bending strength is 380~520 kg/$\textrm{cm}^2$.

• 한국세라믹학회지
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• 제51권1호
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• pp.11-18
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• 2014

Onggi, which is described as a breathing pottery, has strongly influenced the traditional food culture in Korea. In this study Onggi is compared to porcelains including celadon and white porcelain to analyze the sources of pore formation. The differences in starting materials are examined for chemical and mineralogical compositions, particle size and distribution. The gas permeability of the fired samples is correlated to the matrix microstructure. The broad particle size distribution and high iron oxide content of Onggi are revealed as the major cause for the pore formation. Open pores are formed with large particles in the Onggi body while closed pores have a high iron oxide concentration. The Onggi body with increased open pores leads to the high gas permeability.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 1992년도 가을학술발표회 논문집
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• pp.65-68
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• 1992

In characterizing a suspension, heterogenety is included onto the previous characterization using solids concentrations and flocculent characteristics, because of its importance in hydrodynamics. The mechanism of interface formation during the sedimentation of concentrated suspension (thickening) is investigated from a microcosm consisting of four particles in a same plane and a smaller particle below. The critical distances after shich interface forms are calculated as a function of particle size ratio when the small particle is located in the middle of the squre datermined by the large particles. The results shows that the critical separation distance increase as the size ratio approaches to one (homogeneous suspension). This conforms to the trend of existing observations that homogeneous suspensions create the solid-liquid interface at much lower concentration (at al larger separation distance) that the heterogeneous suspensions.

• 한국입자에어로졸학회지
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• 제7권1호
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• pp.1-8
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• 2011

In this study, the formation of nanoparticles by a reaction of ozone with the volatile organic compounds(VOCs) emitted from a commercial home cleaner liquid was investigated using a $1-m^3$ reaction chamber($1{\times}1{\times}1m$). The home cleaner liquid was found to contain many VOCs, particularly terpenes. Some of these VOCs are known to readily react with ozone, forming indoor secondary pollutants. The correlation of particle concentration and reacted ozone concentration was examined with injections of three different ozone concentrations; 50, 100 and 200 ppb. The secondary nanoparticles were formed faster, with their numbers and mass concentrations becoming higher on increasing the concentration of ozone injected.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.673-674
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• 2006

The influence of several experimental parameters on the formation of stable Alloy 625 nanoparticles dispersion in ethanol was investigated. Several analyzing methods were applied, like transmission profiles measured by Turbiscan, transmission electron microscopy, X-ray diffraction, gas chromatography, and particle size analyzer. The correlation among the increase of particle sizes, caused by nanoparticle coalescence and collision, concentration of dispersant and time was presented and discussed. The optimum conditions for the formation of stable dispersion are evaluated.

• Bulletin of the Korean Chemical Society
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• 제19권10호
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• pp.1054-1059
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• 1998

Fluorescence and dynamic light scattering measurements were applied to the study of formation and structure of aggregated colloidal particles in modified poly(ethylene-co-methylacrylate) ionomers in aqueous solution. Both 8-anillino-l-naphthalene-sulfonic acid (ANS) and pyrene were used as fluorescence probe to obtain the information on the structure of particle surface and inside, respectively. Three different ionomers used in this study started to aggregate at very dilute concentration, 3-8 x 10-6 g/mL. In this study, we demonstrate that the polyethylene ionomers can form stable nanoparticles. The hydrophobic core made of the polyethylene backbone chains is stabilized by the ionic groups on the particle surface. Such a formed stable nanoparticles have a relatively narrow size distribution with an average radius in the range of 27-48 nm, depending on the kind of ionic groups. Once the stable particles are formed, the particle size distributions were nearly constant. This study shows another way to prepare surfactant-free polyethylene nanoparticles.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.418-418
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• 2012

Synthesis of nanocrystalline diamond powder was investigated via a gas-to-particle scheme using the hot filament chemical vapor deposition. Effect of substrate surface seeding by nano diamond powder, and that of the electrical conductance of the substrate were studied. The substrate temperature, methane content in the precursor gas, filament-substrate distance and filament temperature were $670^{\circ}C$, 5% methane in hydrogen, 10 mm and $2400^{\circ}C$, respectively. The powder formation by gas-to-particle mechanism were greatly enhanced by the substrate seeding by the nano diamond powder. It was attributed to the removal of the electrostatic force between the substrate and the seeded nano diamond particle by the thermal electron shower from the hot filament, via the depolarization of the substrate surface or the attached diamond powder and subsequent levitation into the gas phase to serve as the gas-phase nucleation site. The powder formation was greatly favoured by the conducting substrate relative to the insulating substrate, which proved the actual effect of the electric static force in the powder formation.

• 한국응용과학기술학회지
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• 제21권3호
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• pp.259-266
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• 2004

Film properties of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. Tensile strength and tensile elongation at break of final films were evaluated. Those properties can be interpreted in terms of PBA/PMMA phase ratio and their morphology. The interfacial adhesion strength was also evaluated using $180^{\circ}$ peel strength measurement and cross hatch cutting test.