• Journal of Electrochemical Science and Technology
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• 제6권4호
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• pp.111-115
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• 2015

In this work electrochemical oxidation of Ascorbic acid (AA) on the surface of Cobalt nano particle modified carbon paste electrode (CoNPsMCPE) was studied in alkaline media. CoNPs were green synthesized using Piper longum and a mixture of 5% (w/w) of it were made with carbon paste. CoNPs showed good electrocatalytic activity in alkaline media. Cyclic voltammetry (CV) and chronoamperometry (CA) were used to study the electrochemical performance of CoNPsMCPE. The number of monolayers on the surface of electrode was calculated as 1.08×10⁹ mol cm⁻² that is equal to that of metal Cobalt electrode. Diffusion coefficient of AA was determined using CA analysis which was equal to 1.5×10⁻⁶cm² s⁻¹.

• Proceedings of the Korean Vacuum Society Conference
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• 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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• pp.243.1-243.1
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• 2014

For two-dimensional grid electrodes immersed in plasmas, sheath expansion due to negative high-voltage pulse applied to the electrode generates high-energy pseudowave. The high-energy pseudowave can be used as ion beam for ion implantation. To estimate ion dose due to high-energy pseudowave, investigation on sheath expansion of grid electroes is necessary. To investigate sheath expansion, an analytic model was developed by Vlasov equation and applying the 1-D sheath expansion model to 2-D. Because of lack of generalized 2-D Child-Langmuir current, model cannot give solvable equation. Instead, for a given grid electrode geometry, the model found the relations between ion distribution functions, Child-Langmuir currents, and sheath expansions. With these relations and particle-in-cell (PIC) simulations, for given grid electrode geometry, computation time was greatly reduced for various conditions such as electrode voltages, plasma densities, and ion species. The model was examined by PIC simulations and experiments, and they well agreed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• 제28권1호
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• pp.21-27
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• 2015

We propose a fabrication process of a 3-electrode type reflective display and ascertain the realized color panel. The first design is proceeded with basis on Ti electrode for fast panel fabrication, easy align process, and high reflection of a white image. To observe the particle movement at the lower electrodes and optimize the space between electrodes, we design the second patterns, from which we establish a fabrication process with the mixing of electronic ink, loading of this ink, electronic ink assembly, driving, and packaging. After aging process, we ascertain a normally driving panel with black, white, and blue color.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• 제13권10호
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• pp.939-946
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• 2001

This study investigates the electrical and collection characteristics of a wide plate spacing electrostatic precipitator (ESP), using a pilot-scale one. Electrical operating characteristics and collection efficiency were measured for various shapes of discharge electrodes. The collection plate spacing ranged from 300 to 550 mm. Results of electrical characteristic and collection efficiency tests as a function of collection plate spacing, discharge electrode type, applied voltage, and particle diameter were obtained. Increasing the collection plate pitch and altering the corona electrode geometry was found to increase the collection efficiencies without increasing input power requirement. The best efficiency is achieved for the discharge electrode of twisted pin type.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• 제14권1호
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• pp.67-74
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• 2000

This paper presents the analysis of partial discharge signals according to the particle states in GIS, for preventing the insulation failure and recognizing the particle states. In this paper, four states of particle (particle on electrode, particle on enclosure, particle on spacer and crossing particle) were simulated. And $\Phi$-Q-N distribution of partial discharge signals was analyzed and the statistical operator of the $\Phi$-Q distribution was analyzed. As a result, it was found that the states of particle were distinguished by analysis of the $\Phi$-Q-N distribution and the statistical operator of the $\Phi$-Q distribution.

• Particle and aerosol research
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• 제5권3호
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• pp.123-131
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• 2009

This paper presents simulation results of particle transport in low-pressure, low-temperature plasma environment. The size dependent transport of particles in the plasma is investigated with a two-dimensional simulation tool developed in-house for plasma chamber analysis and design. The plasma model consists of the first two and three moments of the Boltzmann equation for ion and electron fluids respectively, coupled to Poisson's equation for the self-consistent electric field. The particle transport model takes into account all important factors, such as gravitational, electrostatic, ion drag, neutral drag and Brownian forces, affecting the motion of particles in the plasma environment. The particle transport model coupled with both neutral fluid and plasma models is simulated through a Lagrangian approach tracking the individual trajectory of each particle by taking a force balance on the particle. The size dependant trap locations of particles ranging from a few nm to a few ${\mu}m$ are identified in both electropositive and electronegative plasmas. The simulation results show that particles are trapped at locations where the forces acting on them balance. While fine particles tend to be trapped in the bulk, large particles accumulate near bottom sheath boundaries and around material interfaces, such as wafer and electrode edges where a sudden change in electric field occurs. Overall, small particles form a "dome" shape around the center of the plasma reactor and are also trapped in a "ring" near the radial sheath boundaries, while larger particles accumulate only in the "ring". These simulation results are qualitatively in good agreement with experimental observation.

• Journal of the Korean Vacuum Society
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• 제15권6호
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• pp.576-580
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• 2006

Mercury-free lamp, external electrode fluorescent lamp (EEFL) which includes the xenon gas, is now going on the research for the replacement of mercury lamp. The densities of excited xenon atom in the $1s_4$ resonance state and the $1s_5$ metastable state are investigated in the EEFL by a laser absorption spectroscopy under various gas pressures. We have measured the absorption signals for both $1s_4$ resonance and the $1s_5$ metastable state in the EEFL by varying the discharge currents for a given pressure. This basic absorption characteristic is very important for improvement of the VUV luminous efficiency of the EEFL as well as plasma display panel.

• Particle and aerosol research
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• 제12권4호
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• pp.127-134
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• 2016

A multiwall carbon nanotube (MWCNT)/graphene (GR) composite was synthesized for an enhanced supercapacitor. Aerosol spray pyrolysis (ASP) was employed to synthesize the MWCNT/GR composites using a colloidal mixture of MWCNT and graphene oxide (GO). The effect of the weight ratio of the MWCNT/GO on the particle properties including the morphology and layered structure were investigated. The morphology of MWCNT/GR composites was generally the shape of a crumpled paper ball, and the average composite size was about $5{\mu}m$. MWCNT were uniformly dispersed in GR sheets and the MWCNT not only increase the basal spacing but also bridge the defects for electron transfer between GR sheets. Thus, it was increasing electrolyte/electrode contact area and facilitating transportation of electrolyte ion and electron in the electrode. Electrochemical data demonstrate that the MWCNT/GR (weight ratio=0.1) composite possesses a specific capacitance of 192 F/g at 0.1 A/g and good rate capability (88% capacity retention at 4 A/g) using two-electrode testing system.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• 제20권6호
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• pp.69-74
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• 2006

The effects of mechanical grinding(MG) treatment on the hydrogen storage of $Mg_2Ni$ alloy and $Mg_2Ni$ composite alloy($Mg_2Ni+graphite$) were investigated by pressure-composition-temperature(PCT) measurement, the micro-electrode technique of electrochemistry and etc, in which PCT was measured at high temperature(around $300[^{\circ}C]$) of gas phase and a carbon-filament micro-electrode for electrochemical evaluation was manipulated to make electrical contact with the particle in 1M KOH aqueous solution. It was found that the hydrogenation properties of $Mg_2Ni$ and graphite composite particle were greatly improved by the mechanical grinding treatment by which the $Mg_2Ni$ and graphite composite alloys could be changed into microstructure and nano-level particles. namely; the hydrogen dissociation pressure of PCT measurement was decreased from 0.55[MPa] to 0.42[MPa] and hydrogenation peaks by micro-electrode were also observed more clearly on the same sample.

• Journal of Electrochemical Science and Technology
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• 제9권3호
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• pp.220-228
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• 2018

This study introduced a carbon-free electrode for $Li-O_2$ cells with the aim of suppressing the side reactions activated by carbon material. Micro-particles of poly(3,4-ethylenedioxythiophene) (PEDOT), a conducting polymer, were used as the base material for the air electrode of $Li-O_2$cells. The PEDOT micro-particles were treated with $H_2SO_4$ to improve their electronic conductivity, and LiBr and CsBr were used as the redox mediators to facilitate the dissociation of there action products in the electrode and reduce the over-potential of the $Li-O_2$ cells. The capacity of the electrode employing PEDOT micro-particles was significantly enhanced via $H_2SO_4$ treatment, which is attributed to the increased electronic conductivity. The considerable capacity enhancement and relatively low over-potential of the electrode employing $H_2SO_4$-treated PEDOT micro-particles indicate that the treated PEDOT micro-particles can act as reaction sites and provide storage space for the reaction products. The cyclic performance of the electrode employing $H_2SO_4$-treated PEDOT micro-particles was superior to that of a carbon electrode. The results of the Fourier-transform infrared spectroscopic analysis showed that the accumulation of residual reaction products during cycling was significantly reduced by introducing the carbon-free electrode based on $H_2SO_4$-treated PEDOT micro-particles, compared with that of the carbon electrode. The cycle life was improved owing to the effect of the redox mediators. The refore, the use of the carbon -free electrode combined with redox mediators could realize excellent cyclic performance and low over-potential simultaneously.