• Title/Summary/Keyword: Particle diameter

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Effect of NCO Index on the Particle Size of Polycarbonate Diol-based Polyurethane Dispersion

  • Kim, Dong-Eun;Kang, Seung-Oh;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.20-25
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    • 2020
  • The effect of the isocyanate index (NCO index) on the particle size and particle size distribution of a waterborne polyurethane dispersion (WPUD) with polycarbonate-diol was determined. The WPUDs were prepared using a conventional acetone process with polycarbonate-polyol (Mn = 2028), 4,4'-methylenebis(cyclohexyl isocyanate) (H12MDI), 2,2-bis(hydroxymethyl) propionic acid (DMPA), and dibutyltin dilaurate catalyst. At NCO index values below 1.5, the number average particle diameter of the WPUDs significantly increased with the NCO index, whereas the particle diameter slightly varied at higher NCO indexes. The dependency of the WPUD viscosity on the NCO index exhibited similar behavior to that of the particle size. The relative values of the full width at half maximum of the WPUD particle distribution curves at various NCO indexes were not influenced by the NCO index.

A Study on the Particle Behavior in Turbulent Pulverized Coal Flame (난류 미분탄화염 내 입자거동에 관한 연구)

  • Hwang, Seung-Min
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.12
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    • pp.1111-1118
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    • 2010
  • Combustion measurements based on optical techniques have recently become of major interest as tools not only for clarifying the combustion mechanism but also for validating the computational results for the combustion fields. In this study, the particle behavior in turbulent pulverized coal flame are investigated using advanced optical diagnostics. A laboratory-scale pulverized coal combustion burner is specially fabricated as open type in order to apply various optical measurement techniques. The detailed particle behavior is performed by LDV (laser Doppler velocimetry) and SDPA (shadow Doppler particle analyzer). It is observed that the particle mean diameter increase as the distance from burner increases, and this is found to be caused by the decrease of small particles' diameter and increase of large particles' diameter. This is because of result in the char reaction and the particle swelling due to devolatilization, respectively. The size-classified streamwise velocities of pulverized coal particles in the central region of the jet show the same magnitude, whereas those in the outer region are different depending on the particle size. The results show that the velocity and size-classified diameter of the pulverized coal particles in the flame can be measured well by SDPA.

Preparations and Magnetic Properties of Aluminum Anodic Oxidized Films Electrodeposited Cobalt-Iron Alloys (코발트-철을 전해석출한 양극산화피막의 제작과 자기특성)

  • 강희우
    • Journal of the Korean Magnetics Society
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    • v.4 no.1
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    • pp.25-31
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    • 1994
  • The magnetic properties of aluminum anodized film in which Co-Fe alloy electrodeposited are investigated with regard to the alloy composition of magnetic films. The electrodeposited Co-Fe particles are confirmed to be single phase Co-Fe alloys by X-ray diffractions. At 34 at% Co, the sample with small pore diameter(particle diameter $150\;{\AA}$) has a large magnetic energy product($B_{max}$) of about 1.44 MGOe due to the large saturation magnetization, the high coercive force and good squareness of the M-H curve. However, for the samples with particle diameter larger than $450\;{\AA}$, the bottom of each particle forms abnormal particle claaed branch-shaped unlike the sample of the particle diameter $150\;{\AA}$. In this case, the magnetic anisotropy energy was about zero at the compositions of 45 and 75 at% Co. Moreover, at the compositions from 50 to 70 at% Co, the anisotropy became negative value. This means that an easy axis of magnetization of the film is in plane in plane in spite of the perpendicular shape anisotropy of the particle. It was found that the bottom extremity of the particle contains FeC from the X-ray diffraction. Thus the effect of the bottom extremity, that is, an unusal magnetic property was removed by electrodepositing Cu at the bottom extremity of the particle. Itis clear that the magnetic properties of the ilms are influenced by he branch-shaped bottom extremity filled with FeC.

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Simulation of Aggregate Slump Test Using Equivalent Sphere Particle in DEM (등가 구형입자를 이용한 DEM에서의 골재 슬럼프 실험 모사)

  • Yun, Tae Young;Ahn, Sang Hyeok;Nam, Jueong Hee;Yoo, Pyeong Jun
    • International Journal of Highway Engineering
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    • v.15 no.5
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    • pp.21-29
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    • 2013
  • PURPOSES: Simulation of aggregate slump test using equivalent sphere particle in DEM and its validity evaluation against lab aggregate slump test METHODS : In this research, aggregate slump tests are performed and compared with DEM simulation. To utilize spheric particles in YADE, equivalent sphere diameter concept is applied. As verification measures, the volume in slump cone filled with aggregate is used and it is compared with volume in slump cone filled with equivalent sphere particle. Slump height and diameter are also used to evaluate the suggested numerical method with equivalent concept RESULTS : Simulation test results show good agrement with lab test results in terms of loose packing volume, height and diameter of slumped particle clump. CONCLUSIONS : It is concluded that numerical simulation using DEM is applicable to evaluate the effect of aggregate morphological property in loose packing and optimum gradation determination based on the aggregate slump test simulation result.

Size Distribution Characteristics of Particulate Matter Emitted from Cooking (조리과정에서 생성된 미세먼지의 크기분포 특성)

  • Joo, Sang-Woo;Ji, Jun-Ho
    • Particle and aerosol research
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    • v.16 no.1
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    • pp.9-17
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    • 2020
  • The characteristics of particulate matter made from daily cooking at a Korean residential apartment house with three dwellers had been investigated for about 3 months. All data were recorded by an optical particle counter every minute at the kitchen. Types of cooking such as boiling, frying, and grilling that performed in the house were listed. Boiling only was used in 32% cases among total 234 meals. Frying and grilling were 14% and 11%, respectively. From an initial indoor particulate matter smaller than 10 ㎛ in diameter, the increases due to cooking are reported by size. In case of boiling, PM at 1-10 ㎛ size and under 1 ㎛ size little increased. Normally, particles from oil or combustion in a process of frying or grilling increased indoor PM. In a case of grilling, particle mass concentration in a region of 1-10 ㎛ in diameter increased as much as 295 ㎍/㎥. Mass concentration of particles smaller than 1 ㎛ increased as much as 33 ㎍/㎥.

A Study on Improvement of Valuable Metals Leaching and Distribution Characteristics on Waste PCBs(Printed Circuit Boards) by Using Pulverization Process (폐 PCBs의 미분쇄 공정 적용에 따른 유가금속 분포 특성 및 금속 침출 향상에 관한 연구)

  • Han, Young-Rip;Choi, Young-Ik
    • Journal of Environmental Science International
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    • v.24 no.2
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    • pp.245-251
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    • 2015
  • The main objective of this study is to recovery valuable metals with metal particle size distributions in waste cell phone PCBs(Printed Circuit Boards) by means of pulverization and nitric acid process. The particle size classifier also was evaluated by specific metal contents. The PCBs were pulverized by a fine pulverizer. The particle sizes were classified by 5 different sizes which were PcS1(0.2 mm below), PcS2(0.20~0.51 mm), PcS3(0.51~1.09 mm), PcS4(1.09~2.00 mm) and PcS5(2.00 mm above). Non-magnetic metals in the grinding particles were separated by a hand magnetic. And then, Cu, Co and Ni were separated by 3M nitric acid. Particle diameter of PCBs were 0.388~0.402 mm after the fine pulverizer. The sorting coefficient were 0.403~0.481. The highest metal content in PcS1. And the bigger particle diameter, the lower the valuable metals exist. The recovery rate of the valuable metals increases in smaller particle diameter with same leaching conditions. For further work, it could improve to recovery of the valuable metals effectively by means of individual treatment, multistage leaching and different leaching solvents.

Particle deposition on a semiconductor wafer larger than 100 mm with electrostatic effect (정전효과가 있는 100mm보다 큰 반도체 웨이퍼로의 입자침착)

  • Song, Gen-Soo;Yoo, Kyung-Hoon;Lee, Kun-Hyung
    • Particle and aerosol research
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    • v.5 no.1
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    • pp.17-27
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    • 2009
  • Particle deposition on a semiconductor wafer larger than 100 mm was studied experimentally and numerically. Particularly the electrostatic effect on particle deposition velocity was investigated. The experimental apparatus consisted of a particle generation system, a particle deposition chamber and a wafer surface scanner. Experimental data of particle deposition velocity were obtained for a semiconductor wafer of 200 mm diameter with the applied voltage of 5,000 V and PSL particles of the sizes between 83 and 495 nm. The experimental data of particle deposition velocity were compared with the present numerical results and the existing experimental data for a 100 mm wafer by Ye et al. (1991) and Opiolka et al. (1994). The present numerical method took into consideration the particle transport mechanisms of convection, Brownian diffusion, gravitational settling and electrostatic attraction in an Eulerian frame of reference. Based on the comparison of the present experimental and numerical results with the existing experimental results the present experimental method for a 200 mm semiconductor wafer was found to be able to present reasonable data.

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A Study of Particle Motion for Nozzle Geometry and Particle Diameter in Turbulent Jet Flow (노즐 형상 및 입경에 따른 난류 분류중의 미립자 유동 특성에 관한 연구)

  • 김종철;황승식;전운학
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.6
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    • pp.17-31
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    • 1999
  • This paper is a review of the results of examining the flow characteristics of gas and particles with regards to pipe-type nozzle and converging nozzles depending on nozzle geometry. The nozzles used in this experiment are the pipe-type nozzle which can sufficiently mix the gas and particles, and the converging nozzle which can rapidly accelerate fluid . The particles used at the time of this experiment each measured 0.8, 30, 60 and 80${\mu}{\textrm}{m}$ in the diameter. The Phase Doppler Particle Analyzer was used to measure the velocity of each particle, and the Hot-wire probe was used to measure the spectrum in order to analyze the flow near the nozzle exit of the 0.8${\mu}{\textrm}{m}$ particle.

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Heat Transfer Characteristics of Plastic Particle Slurry in a Circular tube Flow (관내 유동 플라스틱 슬러리의 열전달 특성)

  • 김명환;김명준
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.451-456
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    • 2004
  • This present experimental study has dealt with the heat transfer characteristics of plastic particle slurry which flows in a circular tube. This type of slurry is suggested for heat transfer enhancement effect cause by random and vortex effect of plastic particle dispersed in water. As a result, the thermal boundary layer becomes thin so the heat transfer coefficient on the tube wall more increase compare to pure water flow. This experimental test section was composed with stainless pipe which has the length of 2000mm, inner pipe diameter of 14mm and outer pipe diameter of 60mm. The most effective and important parameter of this experiment is plastic packing factor(PPF). The focuses of these results are pressure drop and heat transfer coefficient. As results, the friction factor of plastic particle slurry becomes higher at laminar flow region than pure water because of buoyancy effect of plastic particle but the local heat transfer coefficient becomes higher.

Generation of Janus particles smaller than 10-${\mu}$m in diameter (직경 10-${\mu}$m 이하의 야누스 입자 생성)

  • Ahn, Sang-Hoon;Yoo, Jung-Yul
    • 한국전산유체공학회:학술대회논문집
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    • 2008.03b
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    • pp.679-682
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    • 2008
  • The particle which has two different characteristics on both sides is called Janus particle which is emerging as a key material in microscale transport systems. For example, if one hemisphere has polarity and the other does not, then nonpolar sides would attract each other so that a complex cluster is formed. Thus, this fascinating material can be used as an element of twisting ball panel display, complex micro-scale clusters, drug delivery unit, and active detecting beads. The keywords in developing Janus particle are size and uniformity. Former researches solved uniformity but downsizing still remains a problem. There are three methods to generate small size particles in microchannels: co-flowing, cross-flowing, and elongational flows. In this research, we generate Janus particles smaller than 10-${\mu}$m in diameter using elongational flow in microchannels. And we use UV initiator with Hydrogen UV source to solidify micro size particles. One hemisphere of the particle is coated with rhodamin for visualization.

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