• Title/Summary/Keyword: Particle deposition

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Preparation and C-V characteristics of $Y_2O_3-StabilzedZrO_2$ Thin Films by PE MO CVD (플라즈마 화학 증착법에 의한 $Y_2O_3-StabilzedZrO_2$박막의 제조와 Capacitance-Voltage특성)

  • Choe, Hu-Rak;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.4 no.5
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    • pp.510-515
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    • 1994
  • Yttria-stabilized zirconia(YSZ) films were prepared onto p-type (100) silicon wafer by a plasma-enhanced metallorganic chemical vapor deposition(PE MO CVD) processing involving the application of vapor mixture of tri(2.2.6.6-tetramethyl-3, 5-heptanate) yttrium$[Y(DPM)_3]$, zirconiumtriflouracethyla cetonate$(Zr(tfacac)_4$ and oxygen gas. The x-ray diffraction(XRD) and fourier transform infrared spectra(FT1R) results showed that the deposited YSZ films had a single cubic phase. $Y_2O_3$ content of YSZ film was analyzed by PIXE(partic1e induced x-ray emission). The experimental results by PIXE revealed that 12.lmol%, 20.4mol% and 31.6mol% $Y_2O_3$ could be obtained as the $Y(DPM)_3$ bubbling temperature varied at $160^{\circ}C, 165^{\circ}C$ and $170^{\circ}C$ respectively. The increase of $Y(DPM)_3$ bubbling temperature caused shifting flat band voltage to have a negative value.

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A Study on the Preferred Orientation Characteristics of AlN Thin Films by Reactive Evaporation Method using NH3 (NH3를 이용한 반응성 증착법에 의한 AlN 박막의 우선배향특성에 관한 연구)

  • Oh, Chang-Sup;Han, Chang-Suk
    • Korean Journal of Metals and Materials
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    • v.50 no.1
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    • pp.78-85
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    • 2012
  • Aluminum nitride(AlN) is a compound (III-V group) of hexagonal system with a crystal structure. Its Wurzite phase is a very wide band gap semiconductor material. It has not only a high thermal conductivity, a high electrical resistance, a high electrical insulating constant, a high breakdown voltage and an excellent mechanical strength but also stable thermal and chemical characteristics. This study is on the preferred orientation characteristics of AlN thin films by reactive evaporation using $NH_3$. We have manufactured an AlN thin film and then have checked the crystal structure and the preferred orientation by using an X-ray diffractometer and have also observed the microstructure with TEM and AlN chemical structure with FT-IR. We can manufacture an excellent AlN thin film by reactive evaporation using $NH_3$ under 873 K of substrate temperature. The AlN thin film growth is dependent on Al supplying and $NH_3$ has been found to be effective as a source of $N_2$. However, the nuclear structure of AlN did not occur randomly around the substrate a particle of the a-axis orientation in fast growth speed becomes an earlier crystal structure and is shown to have an a-axis preferred orientation. Therefore, reactive evaporation using $NH_3$ is not affected by provided $H_2$ amount and this can be an easy a-axis orientation method.

Bragg-curve simulation of carbon-ion beams for particle-therapy applications: A study with the GEANT4 toolkit

  • Hamad, Morad Kh.
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2767-2773
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    • 2021
  • We used the GEANT4 Monte Carlo MC Toolkit to simulate carbon ion beams incident on water, tissue, and bone, taking into account nuclear fragmentation reactions. Upon increasing the energy of the primary beam, the position of the Bragg-Peak transfers to a location deeper inside the phantom. For different materials, the peak is located at a shallower depth along the beam direction and becomes sharper with increasing electron density NZ. Subsequently, the generated depth dose of the Bragg curve is then benchmarked with experimental data from GSI in Germany. The results exhibit a reasonable correlation with GSI experimental data with an accuracy of between 0.02 and 0.08 cm, thus establishing the basis to adopt MC in heavy-ion treatment planning. The Kolmogorov-Smirnov K-S test further ascertained from a statistical point of view that the simulation data matched the experimentally measured data very well. The two-dimensional isodose contours at the entrance were compared to those around the peak position and in the tail region beyond the peak, showing that bone produces more dose, in comparison to both water and tissue, due to secondary doses. In the water, the results show that the maximum energy deposited per fragment is mainly attributed to secondary carbon ions, followed by secondary boron and beryllium. Furthermore, the number of protons produced is the highest, thus making the maximum contribution to the total dose deposition in the tail region. Finally, the associated spectra of neutrons and photons were analyzed. The mean neutron energy value was found to be 16.29 MeV, and 1.03 MeV for the secondary gamma. However, the neutron dose was found to be negligible as compared to the total dose due to their longer range.

Uniformity Analysis of Unmanned Aerial Application with Variable Rate Spray System (무인항공 변량방제 시스템의 살포 균일도 분석)

  • Koo, Young Mo;Bae, Yeonghwan
    • Journal of agriculture & life science
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    • v.52 no.6
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    • pp.111-125
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    • 2018
  • In this study, we evaluated the uniformity of deposition rate and particle size distributions of the variable rate application technique using the unmanned rotorcraft by measuring the spray pattern according to path location in the range of spraying flight. The coefficient of variation (CV) of the lateral coverage rate for the overlapped distribution with the spray swath of 3.6 m in both guidance and auto-pilot flight modes maintaining constant flight speed was about 30% and the CV of the coverage rate by the flight path location was extremely small. Therefore, it was assessed that the variable rate application technology compensating for the variation of ground speed was superior in terms of spray uniformity. In addition, the droplet size distributions in both volume median diameter(VMD) and number median diameter(NMD) were adequate for aerial application and uniform in terms of lateral distribution. Thereafter, we intend to contribute to a precise application on small-scaled fields using the unmanned agricultural rotorcraft by the variable rate application.

Refinement of Gd2O3 inclusions in the GdBa2Cu3O7-δ films fabricated by the RCE-DR process

  • Park, I.;Oh, W.J.;Lee, J.H.;Moon, S.H.;Yoo, S.I.
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.4
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    • pp.46-49
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    • 2018
  • To improve in-field critical current densities ($J_c$) of $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) coated conductors(CCs) fabricated by the reactive co-evaporation by deposition and reaction (RCE-DR) process, employing the nominal composition of Gd:Ba:Cu=1:1:2.5, we tried to refine the $Gd_2O_3$ particles trapped in the GdBCO superconducting matrix. For this purpose, we carefully selected the processing conditions on the stability phase diagram of GdBCO for this composition. By lowering the growth temperature of $Gd_2O_3$ in the liquid, we could refine the average particle size of $Gd_2O_3$ particles trapped in the GdBCO matrix and also achieve the zero-resistive transition temperatures ($T_{c,zero}$) of 92.3~94.2 K. Unfortunately, however, it was unsuccessful to achieve enhanced in-field $J_c$ values from these samples because of an air-contamination of the amorphous precursor film before its conversion into crystalline GdBCO film, suggesting that any exposure of the amorphous precursor film to air is fatal in obtaining high performance GdBCO CCs via the RCE-DR process.

Enhancement of Respiratory Protective and Therapeutic Effect of Salvia plebeia R. Br. Extracts in Combination with Korean Red Ginseng (배암차즈기와 홍삼 복합물의 호흡기 보호 및 질환 치료 상승 효과)

  • Shin, Han Jae;Gwak, Hyo Min;Lee, Moon Yong;Kyung, Jong Su;Jang, Kyoung Hwa;Han, Chang Kyun;Yang, Won Kyung;Kim, Seung Hyung
    • Korean Journal of Medicinal Crop Science
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    • v.27 no.3
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    • pp.218-231
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    • 2019
  • Background: We recently reported that Salvia plebeia R. Br. extracts suppress leukotriene production and effectively inhibit the airway inflammatory response by modulating inflammatory chemokine and cytokine expression. Here, we investigated the synergistic airway anti-inflammation effect of Salvia plebeia and Panax ginseng (Korean red ginseng, KRG) that has been used to treat various immune diseases such as asthma. Methods and Results: To evaluate the synergistic airway anti-inflammatory effect of Salvia plebeia and KRG, we measured the inhibitory effect of monotheraphy with either or co-theraphy with both on leukotriene and reactive oxygen species (ROS) production. Using coal a combustion, fly ash, and diesel exhaust particle (CFD)-induced respiratory disease mouse model, we found that co-theraphy synergistically suppressed airway inflammatory signs such as alveolar wall thickness and collagen fibers deposition, and decreased the number of total cell, $CD11b^+Gr-1^+$ cells, and inflammatory cytokines (IL17A, TNF, MIP-2 and CXCL-1) in bronchoalveolar lavage (BAL) fluid. Conclusions: We confirmed respiratory protection as a therapeutic effect of the Salbia plebeia-KRG 3 : 1 complex (KGC-03-PS) via anti-tracheal muscle contraction and expectorant animal studies using a CFD-induced respiratory disease mouse model.

A Study on Characteristics and Burial Ages of Sand Deposits at Hasari, Baeksoo, Yeonggwang (영광군 백수읍 하사리 일대의 사질 퇴적층 특성과 매몰 연대에 대한 연구)

  • Shin, Won Jeong;Yang, Dong Yoon;Kim, Jong Yeon
    • Journal of The Geomorphological Association of Korea
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    • v.24 no.1
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    • pp.25-38
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    • 2017
  • To investigate the characteristics of sand sediment topography in the Yeonggwang coastal area of Chonnam and to collect evidence of the past extreme events causing coastal flooding, three sites were surveyed among the sediments of Baeksoo-eup Hassari. In this study, the changes of particle characteristics, chemical composition, and the age of deposition of sediments were investigated. The sediments near Baeksoonam Elementary School at the elevation of 10m near the paleo-coastline are estimated to have been deposited at about 3,400 years ago and the grain size of the upper part of the sandy layer is in the range of $2.47-2.11{\varphi}$. The burial age of the sediment layer at Sadeung junction(BSN-B) was about 100 years. Considering the distance from the current coastline, the sands forming the dune are estimated to have been moved or deposited from the nearby area or the other dune on the front side. The mean grain size is observed to be fining upward. Especially, the mean of the upper part is about $2.3{\varphi}$, which is similar to other survey points. The averaged grain size of the lower part of the BSNC (Hasari-1 Gu) was $2.196{\varphi}$ and the upper part was $2.16{\varphi}$. The sorting showed that the upper part was slightly poorer than the lower, and it was difficult to specify the change of the environment. The burial age of the lower layer, which contains shells, was about 300 years. Considering previous studies, this shell layer is presumed to have formed by coastal flooding, such as a storm surge.

Electrodeposition of Ni-W/Al2O3 Nano-Composites and the Influence of Al2O3 Incorporation on Mechanical and Corrosion Resistance Behaviours

  • M. Ramaprakash;R. Nivethida;A. Muthukrishnan;A. Jerom Samraj;M. G. Neelavannan;N. Rajasekaran
    • Journal of Electrochemical Science and Technology
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    • v.14 no.4
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    • pp.377-387
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    • 2023
  • Ni-W/Al2O3 nano-composites were electrodeposited on mild steel substrate for mechanical and corrosion resistance applications. This study focused on the preparation of Ni-W/Al2O3 nano-composite coating with various quantity of Al2O3 incorporations. The addition of Al2O3 in the electrolytes were varied from 1-10 g/L in electrolytes and the Al2O3 incorporation in Ni-W/Al2O3 nano-composite coatings were obtained from 1.82 to 13.86 wt.%. The incorporation of Al2O3 in Ni-W alloy matrix influenced the grain size, surface morphology and structural properties were observed. The distributions of Al2O3 particle in alloy matrix were confirmed using electron microscopy (FESEM and TEM) and EDAX mapping analysis. The crystal structure informations were studied using X-ray diffraction method and it confirms that the deposits having cubic crystal structure. The better corrosion rate (0.87 mpy) and microhardness (965 HV) properties were obtained for the Ni-W/Al2O3 nano-composite coating with 13.86 wt.% of Al2O3 incorporations.

Comparison of Characteristics of Electrodeposited Lithium Electrodes Under Various Electroplating Conditions (다양한 전착조건에서 제작된 리튬 전극의 특성 연구)

  • Lim, Rana;Lee, Minhee;Kim, Jeom-Soo
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.128-137
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    • 2019
  • A lithium is the lightest metal on the earth. It has some attractive characteristics as a negative electrode material such as a low reduction potential (-3.04 V vs. SHE) and a high theoretical capacity ($3,860mAh\;g^{-1}$). Therefore, it has been studied as a next generation anode material for high energy lithium batteries. The thin lithium electrode is required to maximize the efficiency and energy density of the battery, but the physical roll-press method has a limitation in manufacturing thin lithium. In this study, thin lithium electrode was fabricated by electrodeposition under various conditions such as compositions of electrolytes and the current density. Deposited lithium showed strong relationship between process condition and its characteristics. The concentration of electrolyte affects to the shape of deposited lithium particle. As the concentration increases, the shape of particle changes from a sharp edged long one to a rounded lump. The former shape is favorable for suppressing dendrite formation and the elec-trode shows good stripping efficiency of 92.68% (3M LiFSI in DME, $0.4mA\;cm^{-2}$). The shape of deposited particle also affected by the applied current density. When the amount of current applied gets larger the shape changes to the sharp edged long one like the case of the low concentration electrolyte. The combination of salts and solvents, 1.5M LiFSI + 1.5M LiTFSI in DME : DOL [1 : 1 vol%] (Du-Co), was applied to the electrolyte for the lithium deposition. The lithium electrode obtained from this electrolyte composition shows the best stripping efficiency (97.26%) and the stable reversibility. This is presumed to be due to the stability of the surface film induced by the Li-F component and the DOL effect of providing film flexibility.

Estimating Critical Stream Power by the Distribution of Gravel-bed Materials in the Meandering River (만곡하천의 자갈하상재료 분포에 따른 한계수류력 평가)

  • Shin, Seung-Sook;Park, Sang-Deok;Lee, Seung-Kyu;Ji, Min-Gyu
    • Journal of Korea Water Resources Association
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    • v.45 no.2
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    • pp.151-163
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    • 2012
  • The distribution of gravel-bed materials in mountainous river is formed by the process of deposition and transportation of sediment responding to stream power of the latest flood that is over the certain scale. The particle size of bed material was surveyed in the longitudinal points of river and detail points of a specific meandering section and used to estimate the critical velocity and stream power. Yang's critical unit stream power and Bagnold's critical stream power for gravel-bed materials increased with the distance from downstream to upstream. Dimensionless shear stress based on the designed flood discharge in Shields diagram was evaluated that the gravel-bed materials in most survey points may be transported as form of bedload. The mean diameter in the meandering section was the biggest size in first water impingement point of inflow water from upstream and the second big size in second water impingement point by reflection flow. The mean diameters were relatively the small sizes in points right after water impingement. The range of mean critical velocity was 0.77~2.60 m/s and critical unit stream power was big greatly in first water impingement point. The distribution of critical stream power, range of 7~171 $W/m^2$, was shown that variation in longitudinal section was more obvious than that of cross section and estimated that critical stream power may be affected greatly in first and second water impingement point.