• Title/Summary/Keyword: Particle assembly

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Double Convective Assembly Coatings of FePt Nanoparticles to Prevent Particle Coalescence during Annealing

  • Hwang, Yeon
    • Korean Journal of Materials Research
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    • v.21 no.3
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    • pp.156-160
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    • 2011
  • FePt nanoparticles suspension was synthesized by reduction of platinum acetylacetonate and decomposition of iron pentacarbonyl in the presence of oleic acid and oleyl amine. FePt nanoparticles were coated on a substrate by convective assembly from the suspension. To prevent the coalescence during the annealing of FePt nanoparticles double convective coatings were tried. First convective coating was for silica particle assembly on a silicon substrate and second one was for FePt nanoparticles on the previously coated silica layers. It was observed by scanning electron microscopy (SEM) that FePt nanoparticles were dispersed on the silica particle surface. After annealing at $700^{\circ}C$ for 30 minutes under nitrogen atmosphere, FePt nanoparticles on silica particles were maintained in a dispersed state with slight increase of particle size. On the contrary, FePt nanoparticles that were directly coated on silicon substrate showed severe particle growth after annealing due to the close-packing of nanoparticles during assembly. The size variation during annealing was also verified by X-ray diffractometer (XRD). It was suggested that pre-coating, which offered solvent flux oppose to the capillary force between FePt nanoparticles, was an effective method to prevent coalescence of nano-sized particles under high temperature annealing.

Two scale modeling of behaviors of granular structure: size effects and displacement fluctuations of discrete particle assembly

  • Chu, Xihua;Yu, Cun;Xiu, Chenxi;Xu, Yuanjie
    • Structural Engineering and Mechanics
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    • v.55 no.2
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    • pp.315-334
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    • 2015
  • This study's primary aim is to check the existence of a representative volume element for granular materials and determine the link between the properties (responses) of macro structures and the size of the discrete particle assembly used to represent a constitutive relation in a two-scale model. In our two-scale method the boundary value problem on the macro level was solved using finite element method, based on the Cosserat continuum; the macro stresses and modulus were obtained using a solution of discrete particle assemblies at certain element integration points. Meanwhile, discrete particle assemblies were solved using discrete element method under boundary conditions provided by the macro deformation. Our investigations focused largely on the size effects of the discrete particle assembly and the radius of the particle on macro properties, such as deformation stiffness, bearing capacity and the residual strength of the granular structure. According to the numerical results, we suggest fitting formulas linking the values of different macro properties (responses) and size of discrete particle assemblies. In addition, this study also concerns the configuration and displacement fluctuation of discrete particle assemblies on the micro level, accompanied with the evolution of bearing capacity and deformation on the macro level.

Development of New Biochip using Magnetic Interaction and Random Fluidic Self-assembly (자기력과 Random Fluidic Self-assembly에 의한 신규 바이오칩의 개발)

  • Choi, Yong-Sung;Kwon, Young-Soo;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.615-621
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    • 2004
  • This paper describes a new constructing method of multifunctional biosensor using many kinds of biomaterials. A metal particle and an array was fabricated by photolithographic. Biomaterials were immobilized on the metal particle. The array and the particles were mixed in a buffer solution, and were arranged by magnetic force interaction and random fluidic self-assembly. A quarter of total Ni dots were covered by the particles. The binding direction of the particles was controllable, and condition of particles was almost with Au surface on top. The particles were successfully arranged on the array. The biomaterial activities were detected by chemiluminescence and electrochemical methods.

Thermal Conductivity and Adhesion Properties of Thermally Conductive Pressure-Sensitive Adhesives

  • Kim, Jin-Kon;Kim, Jong-Won;Kim, Myung-Im;Song, Min-Seok
    • Macromolecular Research
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    • v.14 no.5
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    • pp.517-523
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    • 2006
  • The effects of particle content, size and shape on the thermal conductivity (k) and adhesion properties of thermally conductive, pressure-sensitive adhesives (PSAs) were investigated. The matrix resins were thermally crosslinkable, 2-ethylhexyl acrylic polyol and ultraviolet (UV)-curable, random copolymer consisting of acrylic oligomer and various acrylates. We found that k increased with increasing diameter and particle aspect ratio, and was further enhanced due to the reduction of the interfacial thermal barrier when the coupling agent, which increases the adhesion between particles and the matrix resin, was used. On the other hand, adhesion properties such as peel strength and tack of the thermally crosslinkable resin decreased sharply with increasing particle content. However, for UV curable resin, increased particle addition inhibited the decrease in adhesion properties.

Development of Biochip by Magnetic Force Interaction (자기력에 의한 바이오칩의 개발)

  • Choi, Yong-Sung;Park, Dae-Hee;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.196-199
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    • 2003
  • In this paper, we have been described a new constructing method of multichannel biosensor using self-assembly by magnetic force interaction. A metal particle and an array was fabricated by photolithographic. Biomaterials were immobilized on the metal particle. The array and the particles were mixed in a buffer solution, and were arranged by magnetic force interaction and self-assembly. A quarter of total Ni dots were covered by the particles. The binding direction of the particles was controllable, and condition of particles was almost with Au surface on top. The particles were successfully arranged on the array. The biomaterial activities were detected by chemiluminescence.

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Verification and application of beam-particle model for simulating progressive failure in particulate composites

  • Xing, Jibo;Yu, Liangqun;Jiang, Jianjing
    • Structural Engineering and Mechanics
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    • v.8 no.3
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    • pp.273-283
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    • 1999
  • Two physical experiments are performed to verify the effectiveness of beam-particle model for simulating the progressive failure of particulate composites such as sandstone and concrete. In the numerical model, the material is schematized at the meso-level as an assembly of discrete, interacting particles which are linked through a network of brittle breaking beams. The uniaxial compressive tests of cubic and parallelepipedal specimens made of carbon steel rod assembly which are glued together by a mixture are represented. The crack patterns and load-displacement response observed in the experiments are in good agreement with the numerical results. In the application respect of beam-particle model to the particulate composites, the influence of defects, particle arrangement and boundary conditions on crack propagation is approached, and the correlation existing between the cracking evolution and the level of loads imposed on the specimen is characterized by fractal dimensions.

Investigation of the Change of Soil Arch Structure in Model Particle Assembly Subjected to Displacing Trapdoor via Photoelastic Measurement Technique (트랩도어 하강이 일어나는 모형 입자 입상체에서 광탄성 측정 기법을 이용한 흙 아치 구조의 변화 조사)

  • Shin, Sang-Young;Jung, Young-Hoon;Kim, Taesik
    • Journal of the Korean Geotechnical Society
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    • v.32 no.10
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    • pp.31-40
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    • 2016
  • In order to investigate the change in soil arch structure developed within the soil subjected to trapdoor movement, various responses in the deformed particle assembly were observed via photoelastic measurement technique. The particle assembly was composed of the regularly stacked model particles coated by thin photoelastic material. Variation of the internal structure transmitting contact forces were observed by taking images showing the photoelastic responses and compared with the change in slip lines and pressures measured by load cells placed beneath the assembly. Initial soil arch structure established immediately after the trapdoor movement collapsed progressively and meanwhile a new extended structure was developed against further movement of the trapdoor. For the sufficient movement of the trapdoor, initially identical regions bounded by the soil arch structure and slip lines were separated and the region enclosed by slip lines became a part of the region loosing the transmitting contact forces identified by photoelastic measurement.

The unique role of domain 2A of the hepatitis A virus precursor polypeptide P1-2A in viral morphogenesis

  • Morace, Graziella;Kusov, Yuri;Dzagurov, Georgy;Beneduce, Francesca;Gauss-Muller, Verena
    • BMB Reports
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    • v.41 no.9
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    • pp.678-683
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    • 2008
  • The initial step during assembly of the hepatitis A virus particle is driven by domain 2A of P1-2A, which is the precursor of the structural proteins. The proteolytic removal of 2A from particulate VP1-2A by an as yet unknown host enzyme presumably terminates viral morphogenesis. Using a genetic approach, we show that a basic amino acid residue at the C-terminus of VP1 is required for efficient particle assembly and that host proteases trypsin and cathepsin L remove 2A from hepatitis A virus particles in vitro. Analyses of insertion mutants in the C-terminus of 2A reveal that this part of 2A is important for liberation of P1-2A from the polyprotein. The data provide the first evidence that the VP1/2A junction is involved in both viral particle assembly and maturation and, therefore, seems to coordinate the first and last steps in viral morphogenesis.

Optimum distribution of steel frame assembly for seismic retrofit of framed structures

  • Michael Adane;Seungho Chun;Jinkoo Kim
    • Steel and Composite Structures
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    • v.50 no.3
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    • pp.337-345
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    • 2024
  • This research proposed a particle swarm optimization (PSO) based seismic retrofit design of moment frame structures using a steel frame assembly. Two full scale specimens of the steel frame assembly with different corner details were attached to one-story RC frames for seismic retrofit, and the lateral load resisting capacities of the retrofitted frames subjected to cyclic loads were compared with those of a bare RC frame. The open source software framework Opensees was used to develop an analytical model for validating the experimental results. The developed analytical model and the optimization scheme were applied to a case study structure for economic seismic retrofit design, and its seismic performance was assessed before and after the retrofit. The results show that the developed steel frame assembly was effective in increasing seismic load resisting capability of the structure, and the PSO algorithm could be applied as convenient optimization tool for seismic retrofit design of structures.

Measurement of Stress and Displacement Fields in Particle Assembly subjected to Shallow Foundation Loading via Photoelasticity Technique (광탄성 기법을 이용한 얕은 기초 하중을 받는 입상체의 응력 및 변위장 측정)

  • Byeon, Bo-Hyeon;Jung, Young-Hoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.5
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    • pp.1947-1955
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    • 2013
  • The purpose of this paper is to present an photoelasticity technique for measuring the displacement and stress distribution in particle assembly subjected to shallow foundation loading. Photoelastic measurement technique was employed to visualize the force transmission of a particle assembly. A model assembly bounded by a steel frame was built by stacking bi-dimensional circular particles made of polycarbonate elastomer. Each particle was coated by a thin photoelastic sheet so that the force transmission represented by bright light stripes can be visualized. In a contacted particle, both magnitude and orientation of principal stress difference can also be measured via the photoelasticity technique. The different distributions of the contact stresses at the initial loading and near the failure were quantitatively compared. The photoelastic patterns and displacement fields observed in the pre-failure state disappears immediately after the buckling of confined force chains.