• Journal of the Korea institute for structural maintenance and inspection
• /
• v.23 no.3
• /
• pp.25-31
• /
• 2019

This study was conducted to evaluate the penetration performance of the Silane Surface Protection Material (SSPM) penetrating the micro pore of concrete surface. The results was indicated microstructure, porosity and penetration depth of applied SSPM. Silica sand and conventional sand were used as fine aggregate in mortar. And liquid and cream types SSPM were used. The amounts of SPM were applied the 127, 255, 382, 510 g/m2 on the surface of mortar. The penetration depth specimens were made with $100{\times}30mm$ in according with KS F 4930. Penetration depth was evaluated according to KS F 4930, divide specimen and then spraying with water in cross section of specimens, and measure the depth of the non-wetted area. The microstructure result of mortar applied SSPM, it was obtained liquid and cream SSPM in mortar. The porosity results of SSPM application specimens were improved with than that of plain specimens. Test results indicated that the penetration depth of SPM were improved with increasing in amounts of SSPM. As a result of test, application of SSPM to concrete surface, it will improve durability.

• Clean Technology
• /
• v.25 no.3
• /
• pp.189-197
• /
• 2019

In this study an optimization of the preparation conditions of activated carbon with a ternary metal ion material to treat $H_2S$, which is classified as a representative odor substance, was carried out. For a metal ion material for enhancing the adsorption performance of hydrogen sulfide, performance enhancement was confirmed by combining Li and Fe or a ternary combination (K, Li, Fe) based on KI, which is a substance promoting hydrogen sulfide adsorption performance. Also, it was determined by XRD analysis that the reaction of each active substance with $H_2S$ was because of binding. The adsorption performance increased more than 3 times with heat treatment of the adsorbent with nitrogen compared with heat treatment with air. The maximum adsorption constant ($q_m$) value of the optimum adsorbent was 97.07, which is 6 times higher than that of the existing K-based impregnated activated carbon. It was confirmed that the objective adsorption amount ($0.3g\;g^{-1}$) was secured by an equilibrium between the mass transfer rate and adsorption rate. From the results, it was confirmed that the performance improvement was noticeable even when activated carbon with a reagent grade activated carbon particle size was modified. It was confirmed that the adsorption performance exists at high relative humidity levels of 60 and 100%, and the optimized preparation can be applied to a wet process such as a scrubber downstream.

• Journal of the Korean Electrochemical Society
• /
• v.22 no.3
• /
• pp.87-103
• /
• 2019

Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.

• Journal of the Mineralogical Society of Korea
• /
• v.32 no.2
• /
• pp.79-86
• /
• 2019

The white aluminum phases in acid mine drainage usually precipitates when mixed with stream waters with relatively high pH. The minerals in white precipitates play important roles in controlling the behavior of heavy metals by adsorbing and coprecipitation. By the phase transition of these minerals in white precipitates, dissolution and readsorption of heavy metals may occur. This study was conducted to obtain preliminary information on the phase transition of the mineral phases in white precipitates. In this study, the mineral phase changes in the white precipitates collected from the stream around Dogye Mining Site over time were investigated with different pH values and temperatures. White precipitates consist mainly of basaluminite, amorphous $Al(OH)_3$ and a small amount of $Al_{13}$-tridecamer. During aging, the incongruent dissolution of the basaluminite occurs first, increasing the content of the amorphous $Al(OH)_3$. After that, pseudoboehmite is finally precipitated following the precursor phase of pseudoboehmite. At $80^{\circ}C$, this series of processes was clearly observed, but at relatively low temperatures, no noticeable changes were observed from the initial condition with coexisting basaluminite and amorphous $Al(OH)_3$. At high pH, the desorption of $SO{_4}^{2-}$ group in basaluminite was initiated to promote phase transition to the pseudoboehmite precursor. Over time, the solution pH decreases due to the dissolution and phase transition of the minerals, and even after the precipitation of pseudoboehmite, only the particle size slightly increased but no clear cystal form was observed.

• Korean Journal of Food Science and Technology
• /
• v.51 no.4
• /
• pp.369-378
• /
• 2019

This study aimed to compare the quality characteristics of carrot juice based on different extraction methods such as centrifugation, single gear, and twin gear methods. Juice quality was evaluated based on extraction yield, nutritional components, and cloud stability. Twin gear extraction resulted in the highest extraction yield, and the highest mineral content. In addtion, ${\beta}$-carotene level higher than the recommended daily intake was obtained only in the carrot juice prepared using twin gear extraction of 100 g carrots. The minimum particle size was observed in twin gear extraction, followed by single gear extraction and centrifugation method. Therefore, twin gear extraction was selected as the optimal method, and changes in the antioxidant and metabolic activity of carrot juice were investigated using this method. Consequently, the carrot juice showed a higher lipid peroxidation inhibition rate than ${\alpha}$-tocopherol (1 mg/mL), and angiotensin I-converting enzyme (ACE) inhibitory activity was increased upon digestion.

• Clean Technology
• /
• v.25 no.3
• /
• pp.206-222
• /
• 2019

Recently, various multiphase flows have been developed, and among them some models have been commercialized. However, most of them have been developed based on a pressure-based approach; therefore, various numerical difficulties were involved inherently. Accordingly, in order to overcome these numerical difficulties, a multiphase flow model, MultiPhaSe flow (MPS), following a fractional-flow based approach was developed. In this study, by combining a contaminant transport module describing an enhanced dissolution effect of a surfactant with MPS, a MultiPhaSe flow and TranSport (MPSTS) model was developed. The developed model was verified using the analytical solution of Clement. The MPSTS model can simulate the process of surfactant enhanced aquifer remediation including interphase mass transfer and contaminant transport in multiphase flow by using the coupled particle tracking method and Lagrangian-Eulerian method. In this study, a surfactant was used in a non aqueous phase liquid (NAPL) contaminated area, and the effect of hydro-geological heterogeneity in the layered media on remediation efficiency was studied using the developed model. According to the numerical simulation, when hydraulic conductivity in a lower layer is 10 times, 20 times, and 50 times larger than that in an upper layer, the concentration of dissolved diesel in the lower layer is much higher than that in the upper layer because the surfactant moves faster along the lower layer owing to preferential flow; thus, the surfactant enhances dissolution of residual non aqueous phase liquid in the lower layer.

• Korean Journal of Heritage: History & Science
• /
• v.38
• /
• pp.359-385
• /
• 2005

Red ocher, red lead or cinnabar has been as red colorant for ages. Cinnabar of the red pigments has been highly regarded as a valuable ingredient because it represent a symbol of exorcising and a haute image. It was used as a pigment of painting and mural painting, bowl, clothes, rock writing, gravestone, etc. It is powder which dissolves in perilla oil or glue before using. Because it is high-priced, the use of cinnabar may be limited to the privileged class. Therefore, red ocher or red lead was used instead of cinnabar. "Gongsagyunmunrok" demonstrated that government official's gravestonea has been painted red by two colorants in the period of the Goryeo dynasty. However, cinnabar may be used to paint gravestones for the first time in the period of the Three States because it has been transmitted since the times. This study discuss the results obtained from an analysis of the pigments used on the red pigments of the Stone Monuments. The results can be briefly summarized as below; First, the microcrystalline structures seen on the surface section of analyzed pigments, samples of which were taken from various parts of red pigments show that different sizes and shapes of pigment particle. Second, a result of the analysis on the composition and structure of the pigments shows that the main components in their composition are : Red pigments - Red lead($Pb_3O_4$), Cinnabar(HgS) and Hematite($Fe_2O_3$) White pigments - Calcite($CaCO_3$) Especially, we knew that red Stone Monuments were found to be natural mineral pigments, which were used as a singular or a mixture.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2015.05a
• /
• pp.217-217
• /
• 2015

The objective of this study was mainly to evaluate the water resources potential of Lake Tana Basin (LTB) by using Soil and Water Assessment Tool (SWAT). From SWAT simulation of LTB, about 5236 km2 area of LTB is gauged watershed and the remaining 9878 km2 area is ungauged watershed. For calibration of model parameters, four gauged stations were considered namely: Gilgel Abay, Gummera, Rib, and Megech. The SWAT-CUP built-in techniques, particle swarm optimization (PSO) and generalized likelihood uncertainty estimation (GLUE) method was used for calibration of model parameters and PSO method were selected for the study based on its performance results in four gauging stations. However the level of sensitivity of flow parameters differ from catchment to catchment, the curve number (CN2) has been found the most sensitive parameters in all gauged catchments. To facilitate the transfer of data from gauged catchments to ungauged catchments, clustering of hydrologic response units (HRUs) were done based on physical similarity measured between gauged and ungauged catchment attributes. From SWAT land use/ soil use/slope reclassification of LTB, a total of 142 HRUs were identified and these HRUs are clustered in to 39 similar hydrologic groups. In order to transfer the optimized model parameters from gauged to ungauged catchments based on these clustered hydrologic groups, this study evaluates three parameter transfer schemes: parameters transfer based on homogeneous regions (PT-I), parameter transfer based on global averaging (PT-II), and parameter transfer by considering Gilgel Abay catchment as a representative catchment (PT-III) since its model performance values are better than the other three gauged catchments. The performance of these parameter transfer approach was evaluated based on values of Nash-Sutcliffe efficiency (NSE) and coefficient of determination (R2). The computed NSE values was found to be 0.71, 0.58, and 0.31 for PT-I, PT-II and PT-III respectively and the computed R2 values was found to be 0.93, 0.82, and 0.95 for PT-I, PT-II, and PT-III respectively. Based on the performance evaluation criteria, PT-I were selected for modelling ungauged catchments by transferring optimized model parameters from gauged catchment. From the model result, yearly average stream flow for all homogeneous regions was found 29.54 m3/s, 112.92 m3/s, and 130.10 m3/s for time period (1989 - 2005) for region-I, region-II, and region-III respectively.

• The Journal of Engineering Geology
• /
• v.29 no.1
• /
• pp.23-35
• /
• 2019

Landslides occur due to heavy rainfall in the summer season. Some of water may infiltrate into the ground; it causes a high saturation condition capable of causing a landslide. Soil properties are crucial in estimating slope stability and debris flow occurrence. The main study areas are Gwanaksan, Suraksan and Bukhansan (Mountain) in Seoul. A total of 44 soil samples were taken from the study area; and a series of geotechnical tests were performed. Physical and mechanical properties were obtained and compared based on region. As a result, among well-graded soils, they are classified as a clayey sand. Coarse-grained and fine-grained contents are approximately 95% and 5%, respectively, with very low amount of clay content. Density, liquid limit and dry unit weight are ranged in $2.62{\sim}2.67g/cm^3$, 27.93~38.15% and $1.092{\sim}1.814g/cm^3$. Cohesion and internal friction angle are 4 kPa and $35^{\circ}$ regardless of mountain area. Coefficient of permeability is varied between $3.07{\times}10^{-3}{\sim}4.61{\times}10^{-2}cm/sec$; it means that it results in great seepage. Permeability is inversely proportional to the uniformity coefficient and is proportional to the effective particle size. In the formal case, there was a difference by mountain area, while in the latter, the tendency was almost similar.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.7 no.1
• /
• pp.37-43
• /
• 2019

This research studied production of lightweight filling production for sink hole restoration utilizing various industrial by-products(2kinds of fly ash, petro-cokes CFBC ash, blast furnace slag fine particle). For this purpose, the mixed raw material properties(compressive strength) behaviors according to the blending ratio of industrial by-products were examined by applying the experimental design method and statistical analysis was performed using the commercial program MINITAB. Compressive strengths of industrial by-products were strongly dependent on blast furnace slag powder. Compressive strength(3days aging) was 3~11MPa depending on the amount of blast furnace slag powder used. The use of CFBC fly ash was evaluated to have the least effect on compressive strength. In addition, the compressive strength and the coefficient of permeability were measured by preparing foamed concrete for the experimental batch 1 condition in the mixture experimental design. In this case, the bulk density is 0.9 to 1.0, the apparent porosity is 30 to 50%, the compressive strength(3days old) is 1 to 2MPa, and the permeability coefficient is $10^{-2}$ to $10^{-3}cm/sec$.