• Bulletin of the Korean Chemical Society
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• 제30권4호
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• pp.837-845
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• 2009

We have performed DFT calculations to investigate the conformational characteristics and hydrogen bonds of the calix[6]arene (1) and p-tert-butylcalix[6]arene (2). The structures of various conformers of 1 were optimized by using the B3LYP/6-31G(d,p) and /6-31+G(d,p) methods followed by single point calculation of MPW1PW91/ 6-31G(d,p). The relative stability of the conformers of 1 is in the following order: cone (pinched: most stable) > partial-cone > cone (winged) $\sim$ 1,2-alternate $\sim$ 1,2,3-alternate > 1,4-alternate > 1,3-alternate > 1,3,5-alternate. The structures of different conformers of 2 were optimized by using the B3LYP/6-31G(d,p) method followed by single point calculation of MPW1PW91/6-31G(d,p). The relative stability of the conformers of 2 is in the following order: cone (pinched) > 1,2-alternate > cone (winged) > 1,4-alternate $\sim$ partial-cone > 1,2,3-alternate > 1,3,5alternate > 1,3-alternate. One of the important factors affecting the relative stabilities of the various conformers of the 1 and 2 is the number and strength of the intramolecular hydrogen bonds.

• 한국전자파학회논문지
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• 제26권12호
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• pp.1050-1057
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• 2015

본 논문에서는 주상변압기 내부에서 부분 방전이 발생할 때 주상변압기의 1차측 또는 2차측 전극의 부싱부분에서 방사되는 방사 전자파(2~5 GHz)를 측정하는데 사용하기 위한 광대역 안테나로 이중 원추형의 광대역 안테나를 검토하였다. 이론 해석에는 FDTD 법을 이용한 상용툴을 사용하였으며, 이중 원추형 광대역 안테나의 반경, 높이 변화에 따른 반사손실 특성을 계산하여 이중 원추형 광대역 안테나의 구조 변화가 반사손실 특성에 미치는 영향을 고찰하였다. 그 결과, 이중 원추형 광대역 안테나의 반사손실 특성에 대한 최적 구조가 있음을 확인할 수 있었다. 또한, 이중 원추형 광대역 안테나는 다이폴 안테나와 유사한 방사지향성 패턴을 나타내고 있으며, 주상변압기에서 방사되는 방사 전자파를 측정하는데 매우 적합하다. 실험을 통하여 이론해석의 타당성도 검증하였다.

• 충청수학회지
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• 제26권3호
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• pp.601-603
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• 2013

We show that a compact embedded hypersurface with constant ratio of mean curvature functions in a convex cone $C{\subset}\mathbb{R}^{n+1}$ is part of a hypersphere if it has a point where all the principal curvatures are positive and if it is perpendicular to ${\partial}C$.

• 대한한의학회지
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• 제29권3호
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• pp.11-20
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• 2008

Objectives: Warm-needling is a method combining the effects of acupuncture with the effects of moxibustion. We need to standardize the characteristics of warm-needling in order to achieve consistency in its operational mechanisms and effects, which will improve clinical ability in the field of Eastern medicine. Methods: In this study, using the LabVIEW system on the warm-needling technique, we measured and compared partial temperature changes which varied according to the density of the moxa cone and the moxa cone's core peak temperature. Results& Conclusions: Examination of the warm-needle's partial temperature in relation to the cone density of the 0.8g moxa specimen suggests that a lower density of the moxa cone corresponds to a higher peak temperature and but with a shorter duration. During the effective stimulus time, the lower the density of the moxa cone, the shorter the duration of the effective stimulus time and the higher the mean temperature. Conversely, the higher the density of the moxa cone, the longer the effective stimulus time and lower the mean temperature.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.58-59
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• 2006

In Spray Forming, specific enthalpy is a key parameter in the deposition process as it influences the thermal condition of the impinging droplets as well as that of the deposit surface. An empirical model for the distribution of specific enthalpy in the spray cone was developed as an easy to handle alternative to numerical models with which the descriptive partial differential equations are solved numerically. The model results were compared with the experimental data to validate its applicability.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3247-3251
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• 2010

Molecular structures of the various conformers for the four stereoisomers of tetra-t-butyl-tetra-O-methylsulfinylcalix[4]arene (1) were optimized using DFT BLYP and mPW1PW91/6-31G(d,p) (hybrid HF-DF) calculation methods. We have analyzed the total electronic and Gibbs free energies and normal vibrational frequencies of 16 different structures from four major conformations (cone (CONE), partial cone (PC), 1,2-alternate (1,2-A), 1,3-alternate (1,3-A)) of the four stereoisomers [1(rccc), 1(rcct), 1(rctt), 1(rtct)]. The mPW1PW91/6-31G(d,p) calculations suggested that the $1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, and $1(rtct)_{1,3-A}$ were the most stable conformations of the respective stereoisomers. These outcomes are in accordance with the experimental structures obtained from X-ray crystallography. The electrostatic repulsion between the sulfinyl and methoxy groups is a primary factor for the relative stabilities of the four different conformations. The IR spectra of the most stable conformers [$1(rccc)_{CONE}$, $1(rcct)_{PC}$, $1(rctt)_{PC}$, $1(rtct)_{1,3-A}$] of each stereoisomer were compared to each other.

• 한국가스학회지
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• 제24권1호
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• pp.49-55
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• 2020

산업용 혹은 발전용 가스터빈에 사용되는 이중 콘형 예혼합 연소기의 다단 연소 특성을 이해하기 위하여 실험적연구를 수행하였다. 이를 위하여 기존에 모두 경사면에 공급되는 연료를 콘부분으로 일부 할애하는 방식으로 다단연소 방식을 구성하였으며 콘에서 분사되는 연료공급은 축방향과 콘 경사면 방향으로 하였다. 다단연소 연소특성을 이해하기 위하여 콘에서의 연료 분사 방향과 연료 분배율 변화에 대한 NOx와 CO의 배출 농도 그리고 벽면 온도분포를 측정하였다. 그 결과 총 연료에 대한 콘으로의 분배율이 3%인 경우 콘에서의 연료 분사방향에 관계없이 노즐내의 예혼합 영역에서 연료가 공기와 균일하게 혼합됨으로서 연소영역의 고온점 감소에 의하여 NOx 배출 농도가 감소된다. 그러나 콘에서 축방향으로 분사되는 연료분배율이 8%로 증가하는 경우 노즐 내부 예혼합 영역으로의 화염 역화로 인하여 NOx의 배출농도가 오히려 증가하게 된다.

• 암석학회지
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• 제1권2호
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• pp.91-103
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• 1992

Eruptive mechanisms and processes at Udo tuff cone can be inferred from indicative characters of products, bedforms and lithofacies, and ring faults. In terms of bedforms and lithofa-cies in particular, massive lapilli tuff beds and chaotic lapilli tuff beds are derived from subaerial falls of aggregated tephra of wet tephra finger jets, occurring dominantly at the lower sequences of proximal part at the tuff cone. Crudely stratified lapilli tuff are derived from subaerial falls of slightly aggregated tephra of less wet tephra finger jets, whereas reversely graded lapilli tuff beds are from slightly disaggregated subaerial falls of continuous uprush. Both beds frequently occur in the middle sequences at proximal and near medial part of the tuff cone. Block and lapilli tephra lenses, ash-coated lapilli tephra beds(lenses) and thin-bedded tuff beds are derived from extremely disaggregated subaerial falls of dry tephra in the continuous uprush, frequently occurring at the upper sequences of medial part at the tuff cone. Udo tuff cone is a basaltic volcano emergent through the sea water surface while water could flood across or into the vent area. Emergence of the tuff cone was from the type-Surtseyan eruption characterized by earlier tephra finger jets and later continuous uprush columns of tephra with copious volumes of steam. Explosions began when boiling of wter produced a bubble column reducing the hydrostatic pres-sure, allowing exsolution of gases from the magma. This expansion of magma into a vesiculating froth fragmented the magma and permitted mixing of magma and water so that a more vigorous generation of steam could proceed. Tephra finger jetting explosions continued to build the crater rims, then remove water from the vent that their deposits flowed like slsurries until the continuous uprush explosion ensued. Continuous uprush explosions were associated with most rapid accumula-tion of tephra. The increasing volume rate led to partial removal of water from the vent area by the newly tephra ring so that more vigorous activity could be attended by a reducing water supply. This might restrain surplus of cold water entering the vent and thus enhance the vigour of the eruption by allowing optimal heat exchange. Eventually the crater became so deep and unsuported that piecemeal sliding, or massive subsidence on indipping ring faults, filled and closed the vent, and the cycle of explosions and collapse began anew.

• 한국경영과학회지
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• 제23권3호
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• pp.27-36
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• 1998

This work has improved the method of Kim and Gal's (6) in that of requiring less response of the DM(decision maker) and ease of reply. The underlying notion is the MCDC(maximally changeable dominance cone) for describing all efficient solutions under the particular preference structure. According to the DM's partial preference expression, enlarging the MCDC is achieved, which results in reducing the solutions needed to take into consideration. The cone generators corresponding to the DM's response are added to the MCDC, which results the MCDC is enlarged. Adopting the scheme of pairwise comparison as a means of acquiring preference attitude, an improved interactive method is proposed. And also, a scheme of choosing a reference point is suggested to achieve the computational efficiency.

• 천문학회보
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• 제36권2호
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• pp.95.1-95.1
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• 2011

Halo Coronal Mass Ejections (HCMEs) are crucial for space weather, since they can produce severe geomagnetic storms when they interact with the Earth's magnetosphere. It is thus very important to infer their directions, radial velocities, and their three-dimensional structures. In this study, we apply two different models to HCMEs since 2008 : (1) an ice cream cone model by Xue et al (2005) using SOHO/LASCO data, (2) a flux rope model by Thernisien et al. (2009) using STEREO/SECCHI data. In addition, we use the flux rope model with zero separation angle of flux rope, which is morphologically similar to the ice cream cone model. The comparison shows that the CME radial velocities from three models have very good correlations (R>0.9) one another. We are extending this comparison to other partial halo CMEs observed by STEREO and SOHO.